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Cavity quantum electrodynamics studies the coherent and dissipative dynamics of quantum emitters coupled to selected electromagnetic resonances. A cavity does more than store light. It concentrates the electric field into a small mode volume, repeatedly brings that field past the emitter, and routes part of the emitted radiation into identifiable output channels. These three effects can make the interaction of one emitter with one photon measurable, controllable, and sometimes faster than every relevant loss process.

The smallest useful model contains one cavity mode, one optical transition, and several reservoirs. Its behavior is governed not by the coupling gg alone but by the comparison

g,κ,γ,γϕ,Δ=ωa−ωc.\begin{gathered} g,\quad \kappa,\quad \gamma, \\ \gamma_\phi, \qquad \Delta=\omega_a-\omega_c. \end{gathered}

Here κ\kappa is the cavity energy-decay rate, γ\gamma is the emitter population-decay rate into noncavity channels, γϕ\gamma_\phi is pure dephasing, and Δ\Delta is the atom-cavity detuning. Throughout this page, κ/(2π)\kappa/(2\pi) is the full width at half maximum of the empty-cavity power resonance and the intracavity field amplitude decays as e−κt/2e^{-\kappa t/2}. This convention matters: factors of two in cavity-QED figures of merit often come from comparing rates defined in different ways.

The Jaynes–Cummings Model derives the closed-system dressed ladder and excitation exchange. Here the focus is physical coupling, loss, and measurable spectra. Cavity QED Platforms compares implementations; conditional cavity dynamics connects them to measurement records.

Required background. Quantized Modes defines the vacuum field, Input–Output Theory supplies port relations, the Two-Level Atom supplies the emitter basis, and Spontaneous Emission explains environmental decay.

A two-level emitter inside a two-sided cavity above an avoided-crossing diagram for the coupled polariton resonances

A cavity concentrates the vacuum field at an emitter, while its ports and parasitic losses set the total rate κ\kappa. The emitter also radiates into noncavity modes at rate γ\gamma. In the ideal one-excitation spectrum, the bare atom and cavity resonances hybridize and open a gap 2g2g at zero detuning. The lower panel plots the exact lossless frequencies (ω±−ωc)/∣g∣(\omega_\pm-\omega_c)/|g| versus Δ/∣g∣\Delta/|g|; the lower branch stays below both bare frequencies and the upper above both. Loss broadens these resonances and can hide the gap in a measured spectrum.

The mirrors in the figure are only one realization. Fabry–Pérot cavities, whispering-gallery resonators, photonic-crystal defects, microwave resonators, and nanophotonic cavities differ greatly in geometry but share the same local ingredients: a normalized mode field, an emitter transition, and specified decay channels.

Let the selected cavity mode have angular frequency ωc\omega_c and annihilation operator aa. Its total energy-decay rate is a sum over useful ports and unmonitored loss,

κ=∑jκj+κint.\kappa = \sum_j\kappa_j+\kappa_{\rm int}.

For an isolated Lorentzian resonance,

Q=ωcκ.Q = \frac{\omega_c}{\kappa}.

A large QQ gives a long storage time; a small effective mode volume gives a large field per photon. Neither quantity by itself establishes strong coupling. A very high-QQ cavity can have poor spatial overlap with the emitter, and a tiny mode can be so lossy that coherent exchange is overdamped.

For a lossless, scalar, positive, nondispersive dielectric, use a normalizable closed-cavity mode as an approximation to an isolated, weakly leaking resonance. Write its positive-frequency field as

E(+)(r)=iℏωc2ϵ0 f(r) a,\mathbf E^{(+)}(\mathbf r) = i \sqrt{\frac{\hbar\omega_c}{2\epsilon_0}}\, \mathbf f(\mathbf r)\,a,

with normalization

∫d3r ϵr(r)∣f(r)∣2=1.\int d^3r\, \epsilon_r(\mathbf r) \left|\mathbf f(\mathbf r)\right|^2 =1.

At a field antinode r0\mathbf r_0, an effective volume may be defined by

Veff=1ϵr(r0)∣f(r0)∣2.V_{\rm eff} = \frac{1}{ \epsilon_r(\mathbf r_0) \left|\mathbf f(\mathbf r_0)\right|^2 }.

For a dipole aligned with the local polarization, the corresponding maximum root-mean-square vacuum field is

Evac,max=ℏωc2ϵ0ϵr(r0)Veff.E_{\rm vac,max} = \sqrt{ \frac{\hbar\omega_c}{ 2\epsilon_0\epsilon_r(\mathbf r_0)V_{\rm eff} } }.

This expression is a useful design estimate, not a universal definition for absorbing or strongly dispersive media. Quasinormal-mode normalization and the electromagnetic Green tensor are then safer tools. The conservative mode quantization is developed in Quantized Electromagnetic Modes.

The emitter samples the vector field at its position. The relevant overlap contains

  • the standing-wave or traveling-wave amplitude at ra\mathbf r_a;
  • alignment between the transition dipole and local polarization;
  • angular-momentum and Clebsch–Gordan factors;
  • the coherent superposition of Zeeman or hyperfine sublevels;
  • averaging over motion, spectral diffusion, and technical drift.

Consequently, the maximum coupling quoted for a cavity geometry can be much larger than the time-averaged coupling in an experiment.

In the electric-dipole approximation,

Hint=−d⋅E(ra).H_{\rm int} = -\mathbf d\mathbin{\cdot}\mathbf E(\mathbf r_a).

For transition dipole deg=⟨e∣d∣g⟩\mathbf d_{eg}=\langle e|\mathbf d|g\rangle, the rotating-wave single-photon coupling is

g(ra)=−iωc2ℏϵ0 deg⋅f(ra).g(\mathbf r_a) = -i \sqrt{\frac{\omega_c}{2\hbar\epsilon_0}}\, \mathbf d_{eg}\mathbin{\cdot}\mathbf f(\mathbf r_a).

An overall phase of gg can be absorbed into aa or the atomic states for one emitter and one mode. Its magnitude is physical. At optimal position and orientation,

∣gmax∣=degEvac,maxℏ.|g_{\rm max}| = \frac{d_{eg}E_{\rm vac,max}}{\hbar}.

The factor gn+1g\sqrt{n+1} is the matrix element connecting ∣e,n⟩|e,n\rangle and ∣g,n+1⟩|g,n+1\rangle. Even when the cavity begins in the vacuum, the n=0n=0 matrix element remains gg: the vacuum has zero mean electric field but nonzero field fluctuations.

After the rotating-wave approximation, the closed part of the minimal model is

HJCℏ=ωca†a+ωaσ+σ−+g aσ++g∗a†σ−.\frac{H_{\rm JC}}{\hbar} ={} \omega_c a^\dagger a + \omega_a\sigma_+\sigma_- + g\,a\sigma_+ + g^*a^\dagger\sigma_-.

This Hamiltonian is reliable when one transition and one mode are spectrally isolated, the coupling is weak compared with optical frequencies, and the mode function is not materially altered by the emitter. Ultrastrong coupling, dense multilevel structure, or overlapping resonances require a larger model.

A driven, lossy single-emitter model is

ρ˙=−iℏ[HJC+Hdrv,ρ]+κD[a]ρ+γD[σ−]ρ+γϕ2D[σz]ρ,\dot\rho ={} -\frac{i}{\hbar} \left[ H_{\rm JC}+H_{\rm drv}, \rho \right] + \kappa\mathcal D[a]\rho + \gamma\mathcal D[\sigma_-]\rho + \frac{\gamma_\phi}{2} \mathcal D[\sigma_z]\rho,

where

D[L]ρ=LρL†−12{L†L,ρ}.\mathcal D[L]\rho = L\rho L^\dagger - \frac12 \left\{ L^\dagger L,\rho \right\}.

These independent Markovian reservoirs have negligible thermal occupation in their lowering channels. With this normalization, pure dephasing contributes γϕ\gamma_\phi to the optical coherence decay. The total transverse rate is

γ⊥=γ2+γϕ.\gamma_\perp = \frac{\gamma}{2}+\gamma_\phi.

The model separates physically different quantities:

Symbol Meaning Decay or linewidth convention
κ\kappa total cavity energy decay cavity amplitude decays at κ/2\kappa/2
κj\kappa_j coupling to port jj contributes to both damping and an output field
κint\kappa_{\rm int} absorption, scattering, or other uncollected cavity loss damps the mode without a useful port
γ\gamma emitter population decay outside the modeled cavity channel excited population decays at γ\gamma
γϕ\gamma_\phi pure dephasing adds directly to coherence decay
γ⊥\gamma_\perp total emitter coherence decay optical amplitude decays at γ⊥\gamma_\perp

When the emitter is weakly excited, set α=⟨a⟩\alpha=\langle a\rangle and s=⟨σ−⟩s=\langle\sigma_-\rangle, approximate ⟨σz⟩≃−1\langle\sigma_z\rangle\simeq-1, and drive port 1 with coherent amplitude βin\beta_{\rm in}. In a frame rotating at the probe frequency,

α˙=(iΔc−κ2)α−ig∗s−κ1 βin,s˙=(iΔa−γ⊥)s−igα,\begin{aligned} \dot\alpha ={}& \left( i\Delta_c-\frac{\kappa}{2} \right)\alpha -ig^*s -\sqrt{\kappa_1}\,\beta_{\rm in}, \\ \dot s ={}& \left( i\Delta_a-\gamma_\perp \right)s -ig\alpha, \end{aligned}

where Δc=ωp−ωc\Delta_c=\omega_{\rm p}-\omega_c and Δa=ωp−ωa\Delta_a=\omega_{\rm p}-\omega_a. These are the equations of two damped coupled oscillators. They accurately describe weak-probe spectra, but they discard saturation and therefore cannot reproduce all single-photon nonlinearities or higher excitation manifolds.

If pure dephasing is negligible, a standard single-emitter cooperativity is

C=4∣g∣2κγ.C = \frac{4|g|^2}{\kappa\gamma}.

Equivalently, C is the ratio of the broad-cavity resonant emission rate 4∣g∣2/κ4|g|^2/\kappa to the noncavity population-decay rate γ\gamma. With pure dephasing present, the weak-probe response is more directly organized by

C⊥=2∣g∣2κγ⊥.C_\perp = \frac{2|g|^2}{\kappa\gamma_\perp}.

Since γ⊥=γ/2\gamma_\perp=\gamma/2 when γϕ=0\gamma_\phi=0, the two definitions then agree. A paper that instead calls the cavity field-amplitude decay rate κ\kappa or calls the atomic half width γ\gamma will display different factors of two or four. The invariant procedure is to reconstruct the equations of motion and identify which amplitudes or populations each rate damps.

High cooperativity means that the selected cavity channel competes successfully with unwanted emitter decoherence. It does not by itself mean that a photon oscillates coherently between atom and cavity. For example, a bad cavity can have

κ≫∣g∣≫γandC≫1.\kappa\gg |g|\gg\gamma \qquad\text{and}\qquad C\gg1.

It efficiently funnels emission into the cavity output while eliminating the intracavity field too quickly for several resolved swaps.

  • Perturbative weak coupling, C⊥≪1C_\perp\ll1. The cavity weakly modifies an emitter, or the emitter weakly perturbs the cavity.
  • Bad-cavity or Purcell regime, κ≫∣g∣,γ⊥\kappa\gg |g|,\gamma_\perp. Eliminating the cavity gives enhanced irreversible emission into its output.
  • High-cooperativity bad cavity, C⊥≫1C_\perp\gg1 but κ≳∣g∣\kappa\gtrsim |g|. Channeling and extinction can be strong without many coherent swaps.
  • Strong coupling, ∣g∣|g| above the relevant linewidth scales. Atom and cavity form resolvable hybrid modes and can exchange excitation coherently.
  • Dispersive coupling, ∣Δ∣≫∣g∣n+1,κ,γ⊥|\Delta|\gg |g|\sqrt{n+1},\kappa,\gamma_\perp. State-dependent frequency shifts dominate real exchange.
  • Saturated response. Once the probe appreciably changes ⟨σz⟩\langle\sigma_z\rangle, the linear coupled-oscillator formulas fail and nonlinear quantum dynamics matters.

These boundaries are crossovers, not phase transitions. A device can be strongly coupled for a stationary atom at an antinode but appear inhomogeneously broadened after averaging over motion. Conversely, a device without resolved normal-mode peaks may still have excellent cooperativity and single-emitter readout.

In the one-excitation manifold of the lossless model, the two eigenfrequencies are

ω±=ωa+ωc2±12Δ2+4∣g∣2.\omega_\pm = \frac{\omega_a+\omega_c}{2} \pm \frac12 \sqrt{\Delta^2+4|g|^2}.

Far from resonance, one branch is atom-like and the other cavity-like. Near Δ=0\Delta=0, they hybridize into upper and lower polaritons. Their minimum frequency separation is

ω+−ω−=2∣g∣.\omega_+-\omega_-=2|g|.

After choosing phases so g=∣g∣g=|g| is real, an initial ∣e,0⟩|e,0\rangle exactly on resonance and with no loss evolves as

∣ψ(t)⟩=cos⁡(gt)∣e,0⟩−isin⁡(gt)∣g,1⟩,Pe(t)=cos⁡2(gt).\begin{aligned} |\psi(t)\rangle ={}& \cos(gt)|e,0\rangle - i\sin(gt)|g,1\rangle, \\ P_e(t) ={}& \cos^2(gt). \end{aligned}

The first complete transfer occurs at t=π/(2∣g∣)t=\pi/(2|g|), and the population oscillation has angular frequency 2∣g∣2|g|. This time-domain exchange and the frequency-domain avoided crossing are two views of the same coupling.

In the weak-excitation sector, define the uncoupled complex frequencies

ω~c=ωc−iκ2,ω~a=ωa−iγ⊥.\widetilde\omega_c = \omega_c-\frac{i\kappa}{2}, \qquad \widetilde\omega_a = \omega_a-i\gamma_\perp.

The coupled poles are

ω~±=ω~c+ω~a2±∣g∣2+(ω~c−ω~a)24.\widetilde\omega_\pm = \frac{ \widetilde\omega_c+\widetilde\omega_a }{2} \pm \sqrt{ |g|^2 + \frac{ \left( \widetilde\omega_c-\widetilde\omega_a \right)^2 }{4} }.

On exact resonance and with γϕ=0\gamma_\phi=0, this reduces to

ω~±=ω0−i(κ+γ)4±∣g∣2−(κ−γ)216.\widetilde\omega_\pm = \omega_0 - \frac{i(\kappa+\gamma)}{4} \pm \sqrt{ |g|^2 - \frac{(\kappa-\gamma)^2}{16} }.

The real parts separate once ∣g∣>∣κ−γ∣/4|g|>|\kappa-\gamma|/4. That algebraic condition is not a universal criterion for observing two peaks. If the common linewidth is broader than the separation, the peaks merge. Interference with a prompt reflected field can create a dip or asymmetry, and transmission, reflection, fluorescence, and intracavity spectra weight the poles differently.

Thus three statements should be kept distinct:

  1. The closed Hamiltonian has an avoided crossing for every nonzero gg.
  2. The open response generically has two complex poles, coalescing at an exceptional point; on resonance their real parts split only above the threshold stated in the chosen rate convention.
  3. A particular experiment resolves two spectral features only when their separation, widths, port geometry, signal-to-noise ratio, and background permit it.

The conservative statement ∣g∣≫κ,γ,γϕ|g|\gg\kappa,\gamma,\gamma_\phi identifies an unambiguous strong-coupling limit, but many useful experiments operate near its boundary.

Two classical damped oscillators also exhibit normal-mode splitting. A spectral doublet alone therefore demonstrates coherent mode hybridization, not by itself the quantization of the electromagnetic field. The vacuum Rabi interpretation additionally relies on calibrated coupling to a single or known small number of emitters, operation near the zero-photon limit, and consistency with the one-quantum matrix element gg. More distinctively quantum signatures include excitation-number-dependent n+1\sqrt{n+1} splittings, photon blockade, sub-Poissonian output, and conditional single-quantum dynamics.

Suppose the cavity is broader than the coherent coupling and changes much faster than the emitter. Adiabatic elimination gives an additional emitter-population decay rate into the cavity channel,

Γcav(Δ)=∣g∣2κΔ2+(κ/2)2.\Gamma_{\rm cav}(\Delta) = \frac{ |g|^2\kappa }{ \Delta^2+(\kappa/2)^2 }.

On resonance,

Γcav(0)=4∣g∣2κ.\Gamma_{\rm cav}(0) = \frac{4|g|^2}{\kappa}.

If γ\gamma is the background radiative rate and nonradiative decay is negligible, then

Γcav(0)γ=C.\frac{\Gamma_{\rm cav}(0)}{\gamma} = C.

This is the weak-coupling meaning of cooperativity. The cavity has converted reversible coupling gg into an effectively irreversible decay channel because a cavity photon escapes on the short time scale κ−1\kappa^{-1}.

For a narrow emitter with optimal polarization and position in a weak-coupling cavity, relative to its radiative rate in a homogeneous host of refractive index nn, the same result is often expressed as

FP=34π2(λn)3QVeff,F_P = \frac{3}{4\pi^2} \left( \frac{\lambda}{n} \right)^3 \frac{Q}{V_{\rm eff}},

where λ\lambda is the vacuum wavelength and microscopic local-field factors are assumed consistent between the reference and cavity. It is multiplied in practice by spatial, polarization, and spectral-overlap factors. The Spontaneous Emission page develops the more general environmental and Green-tensor viewpoint.

Branching ratio is not collection efficiency

Section titled “Branching ratio is not collection efficiency”

Let γbg\gamma_{\rm bg} denote residual radiative decay outside the selected cavity mode and γnr\gamma_{\rm nr} nonradiative loss. In the eliminated-cavity, exponential-decay limit, the probability that one initially prepared excitation leaves through the cavity channel is

βcav=ΓcavΓcav+γbg+γnr.\beta_{\rm cav} = \frac{ \Gamma_{\rm cav} }{ \Gamma_{\rm cav} + \gamma_{\rm bg} + \gamma_{\rm nr} }.

This branching expression is not the general strong-coupling result. For resonant undriven exchange from ∣e,0⟩|e,0\rangle, no pure dephasing, and γ=γbg+γnr\gamma=\gamma_{\rm bg}+\gamma_{\rm nr}, exact integration gives

βcavexact=κκ+γC1+C,C=4∣g∣2κγ.\beta_{\rm cav}^{\rm exact} =\frac{\kappa}{\kappa+\gamma}\frac{C}{1+C},\qquad C=\frac{4|g|^2}{\kappa\gamma}.

The extra factor approaches one in the bad-cavity limit. At very strong coupling the excitation spends comparable times in atom and cavity, so escape competes with emitter decay and βcav→κ/(κ+γ)\beta_{\rm cav}\to \kappa/(\kappa+\gamma). Driven Raman generation has different dynamics and must not be assigned this initial-excitation formula.

Only a fraction κcol/κ\kappa_{\rm col}/\kappa of those cavity photons leave by the desired port. Including propagation and detector efficiencies,

ηclick=βcavκcolκηpropηdet.\eta_{\rm click} = \beta_{\rm cav} \frac{\kappa_{\rm col}}{\kappa} \eta_{\rm prop} \eta_{\rm det}.

A large Purcell factor can therefore coexist with poor detected efficiency if absorption dominates the cavity linewidth, the output is split among several ports, or the external optics have poor mode matching. Conversely, improving outcoupling can lower QQ and hence change the Purcell rate. Cavity design is an optimization over both emission and extraction.

The Lorentzian expression assumes weak excitation, one broad cavity mode, Markovian reservoirs, and an emitter whose population and coherence vary slowly compared with the cavity response. In particular, dephasing broadening cannot simply be ignored in the spectral overlap. It must be reconsidered when

  • coherent exchange is resolved;
  • pure dephasing or spectral diffusion broadens the emitter;
  • several cavity modes or transitions overlap;
  • the cavity line is non-Lorentzian;
  • nonradiative decay or blinking changes the emitter quantum yield;
  • the electromagnetic environment is absorptive or strongly dispersive.

Purcell enhancement is thus a regime of cavity QED, not a synonym for strong coupling.

The steady weak-probe cavity amplitude follows directly from the linear equations:

αss=−κ1 βinκ2−iΔc+∣g∣2γ⊥−iΔa.\alpha_{\rm ss} = - \frac{ \sqrt{\kappa_1}\,\beta_{\rm in} }{ \displaystyle \frac{\kappa}{2} -i\Delta_c + \frac{|g|^2}{ \gamma_\perp-i\Delta_a } }.

Together with the port relation

βout,j=βin,j+κj αss,\beta_{{\rm out},j} = \beta_{{\rm in},j} + \sqrt{\kappa_j}\,\alpha_{\rm ss},

this predicts the coherent reflection or transmission signal in the sign convention used on the Input–Output Theory Overview. On double resonance, the emitter adds ∣g∣2/γ⊥|g|^2/\gamma_\perp to the cavity response denominator. Relative to an empty cavity, the intracavity field is reduced by a factor

11+C⊥\frac{1}{1+C_\perp}

for the same input and port convention. Even when individual fluorescence photons are hard to collect, this coherent perturbation can make one emitter visible in a bright transmitted or reflected probe.

The observed contrast is not a direct measurement of C⊥C_\perp without a port model. Internal loss, mode mismatch, polarization leakage, prompt reflection, and detector normalization all affect the trace.

For a detuning large compared with the coupling across all occupied manifolds,

∣Δ∣≫∣g∣n+1,κ,γ⊥,|\Delta| \gg |g|\sqrt{n+1}, \kappa, \gamma_\perp,

real excitation exchange is suppressed. For the stated two-level JC Hamiltonian, to second order and after discarding a constant,

Hdispℏ≃(ωc+χσz)a†a+ωa+χ2σz,χ=∣g∣2Δ.\begin{aligned} \frac{H_{\rm disp}}{\hbar} &\simeq \left( \omega_c+\chi\sigma_z \right)a^\dagger a + \frac{\omega_a+\chi}{2}\sigma_z, \\ \chi &= \frac{|g|^2}{\Delta}. \end{aligned}

The emitter state shifts the cavity resonance by opposite amounts, so a probe acquires a state-dependent amplitude or phase. Conversely, cavity photons shift the emitter and fluctuate in number, producing AC Stark shifts and measurement-induced dephasing. The scale

ncrit∼Δ24∣g∣2n_{\rm crit} \sim \frac{\Delta^2}{4|g|^2}

marks where the simplest dispersive expansion loses uniform validity; the exact threshold depends on the required accuracy and multilevel structure.

Dispersive does not mean backaction-free. Off-resonant photons can still scatter, and any record that distinguishes atomic states dephases their superposition when the record is ignored. A measurement is quantum nondemolition only with respect to a specified observable and effective Hamiltonian, over a specified time scale.

Cavity-enhanced readout may use

  • direct counting of cavity fluorescence or transmitted photons;
  • extinction or transmission contrast of a coherent probe;
  • homodyne phase shifts from a dispersive interaction;
  • heterodyne records when both quadratures or an offset band are useful;
  • correlations such as g(2)(τ)g^{(2)}(\tau) to reveal nonlinear dynamics.

The receiver physics remains in Photon Counting and Homodyne and Heterodyne Detection. Conditional jumps, innovations, and trajectory backaction remain in the open-system cavity-QED map.

For NN emitters near their collective ground state, the coupling vector selects one bright superposition in the single-excitation space. A closed two-mode description also requires degenerate emitter frequencies and compatible damping; otherwise free evolution mixes bright and dark modes. Its coupling is

G=∑i=1N∣gi∣2.G = \sqrt{ \sum_{i=1}^{N}|g_i|^2 }.

For identical couplings, G=N ∣g∣G=\sqrt N\,|g|. This enhancement follows from coherent addition of excitation amplitudes, not from NN independent emission rates. Dark collective states, inhomogeneous detunings, motion, and dipole-dipole interactions can invalidate the simple two-oscillator description. A measured N\sqrt N splitting therefore requires control or calibration of the participating ensemble.

The Cavity QED Simulation Notebook provides reproducible dressed-spectrum, vacuum-Rabi, collapse–revival, photon-cutoff, and small Lindblad-loss benchmarks. Use this page for the physical rate dictionary and experiment-facing interpretation; use the notebook for finite-basis construction and numerical validation.

Exercise 1: Vacuum field and maximum coupling

Section titled “Exercise 1: Vacuum field and maximum coupling”

An empty-space cavity mode has wavelength λ=780 nm\lambda=780\ \mathrm{nm} and effective volume

Veff=1000 μm3.V_{\rm eff} = 1000\ \mu\mathrm m^3.

An optimally oriented transition has dipole magnitude deg=3ea0d_{eg}=3ea_0. Estimate Evac,maxE_{\rm vac,max} and gmax/(2π)g_{\rm max}/(2\pi). Use e=1.602×10−19 Ce=1.602\times10^{-19}\ \mathrm C, a0=5.292×10−11 ma_0=5.292\times10^{-11}\ \mathrm m, and c=2.998×108 m s−1c=2.998\times10^8\ \mathrm{m\,s^{-1}}.

Solution

The angular frequency and mode volume in SI units are

ωc=2πcλ,ωc≃2.414×1015 s−1,Veff=1000×10−18 m3,Veff=1.00×10−15 m3.\begin{gathered} \omega_c = \frac{2\pi c}{\lambda} , \\ \omega_c \simeq 2.414\times10^{15}\ \mathrm{s^{-1}}, \\ V_{\rm eff} = 1000\times10^{-18}\ \mathrm m^3 , \\ V_{\rm eff} = 1.00\times10^{-15}\ \mathrm m^3. \end{gathered}

For vacuum refractive index n=1n=1,

Evac,max=ℏωc2ϵ0Veff≃3.79×103 V m−1.\begin{aligned} E_{\rm vac,max} &= \sqrt{ \frac{\hbar\omega_c}{2\epsilon_0V_{\rm eff}} } \\ &\simeq 3.79\times10^3\ \mathrm{V\,m^{-1}}. \end{aligned}

The dipole magnitude is

deg=3ea0≃2.54×10−29 C m.d_{eg} = 3ea_0 \simeq 2.54\times10^{-29}\ \mathrm{C\,m}.

Therefore

gmax=degEvac,maxℏ≃9.14×108 s−1,gmax2π≃145 MHz.\begin{aligned} g_{\rm max} &= \frac{d_{eg}E_{\rm vac,max}}{\hbar} \simeq 9.14\times10^8\ \mathrm{s^{-1}}, \\ \frac{g_{\rm max}}{2\pi} &\simeq 145\ \mathrm{MHz}. \end{aligned}

This is an ideal spatial and polarization value. The measured coupling will be smaller if the emitter is not at the antinode or if the transition dipole does not align with the local mode.

Exercise 2: Spatial, polarization, and internal-state overlap

Section titled “Exercise 2: Spatial, polarization, and internal-state overlap”

An emitter in a standing-wave cavity has

g=gmaxcos⁡(kz)cos⁡θCang,g = g_{\rm max} \cos(kz) \cos\theta C_{\rm ang},

where θ\theta is the angle between the dipole and local polarization and CangC_{\rm ang} is an angular-momentum amplitude. Take z=λ/8z=\lambda/8 measured from an antinode, θ=60∘\theta=60^\circ, and Cang=2/3C_{\rm ang}=\sqrt{2/3}.

  1. Find g/gmaxg/g_{\rm max}.
  2. Find C/CmaxC/C_{\rm max} if all decay rates are unchanged.
Solution

Since k=2π/λk=2\pi/\lambda,

cos⁡(kz)=cos⁡(π4)=12.\cos(kz) = \cos\left(\frac{\pi}{4}\right) = \frac{1}{\sqrt2}.

The full amplitude ratio is

ggmax=12(12)23=123≃0.289.\begin{aligned} \frac{g}{g_{\rm max}} &= \frac{1}{\sqrt2} \left(\frac12\right) \sqrt{\frac23} \\ &= \frac{1}{2\sqrt3} \simeq 0.289. \end{aligned}

Cooperativity scales as ∣g∣2|g|^2, so

CCmax=∣ggmax∣2=112≃0.0833.\frac{C}{C_{\rm max}} = \left| \frac{g}{g_{\rm max}} \right|^2 = \frac1{12} \simeq 0.0833.

Three moderate amplitude-overlap reductions have lowered the cooperativity by a factor of twelve. This is why quoting only the geometric gmaxg_{\rm max} can be misleading.

Exercise 3: High cooperativity without strong coupling

Section titled “Exercise 3: High cooperativity without strong coupling”

A cavity and emitter are resonant, with

g2π=40 MHz,κ2π=400 MHz,γ2π=0.40 MHz,\begin{gathered} \frac{g}{2\pi}=40\ \mathrm{MHz}, \\ \frac{\kappa}{2\pi}=400\ \mathrm{MHz}, \\ \frac{\gamma}{2\pi}=0.40\ \mathrm{MHz}, \end{gathered}

and negligible pure dephasing.

  1. Calculate the cooperativity.
  2. Calculate the resonant bad-cavity emission rate Γcav/(2π)\Gamma_{\rm cav}/(2\pi).
  3. Classify the system.
Solution

All three quoted numbers use the same angular-frequency conversion, so the factors of 2π2\pi cancel in ratios:

C=4(40)2(400)(0.40)=40.C = \frac{ 4(40)^2 }{ (400)(0.40) } = 40.

The eliminated-cavity rate is

Γcav2π=4(40 MHz)2400 MHz=16 MHz.\frac{\Gamma_{\rm cav}}{2\pi} = \frac{ 4(40\ \mathrm{MHz})^2 }{ 400\ \mathrm{MHz} } = 16\ \mathrm{MHz}.

Thus cavity-mediated emission is forty times faster than background emission. Nevertheless,

κ=10g,\kappa=10g,

so a cavity excitation escapes much faster than one coherent atom-cavity swap. This is a high-cooperativity bad-cavity system, not an unambiguous resolved-strong-coupling system.

On exact resonance, a system with negligible pure dephasing has

g2π=10 MHz,κ2π=8 MHz,γ2π=2 MHz.\begin{gathered} \frac{g}{2\pi}=10\ \mathrm{MHz}, \\ \frac{\kappa}{2\pi}=8\ \mathrm{MHz}, \\ \frac{\gamma}{2\pi}=2\ \mathrm{MHz}. \end{gathered}

Find the real-frequency separation of the two weak-excitation poles and the power linewidth associated with their common imaginary part. Would a doublet be expected in a clean spectrum?

Solution

Writing every rate after division by 2π2\pi in megahertz, the real offset of each pole is

Ωpole2π=(10)2−(8−2)216 MHz=97.75 MHz≃9.89 MHz.\begin{aligned} \frac{\Omega_{\rm pole}}{2\pi} &= \sqrt{ (10)^2 - \frac{(8-2)^2}{16} } \ \mathrm{MHz} \\ &= \sqrt{97.75}\ \mathrm{MHz} \simeq 9.89\ \mathrm{MHz}. \end{aligned}

The pole separation is therefore

Re⁡(ω~+−ω~−)2π≃19.8 MHz.\frac{ \operatorname{Re} \left( \widetilde\omega_+ - \widetilde\omega_- \right) }{2\pi} \simeq 19.8\ \mathrm{MHz}.

The common imaginary part has magnitude

κ+γ4(2π)=2.5 MHz.\frac{\kappa+\gamma}{4(2\pi)} = 2.5\ \mathrm{MHz}.

An amplitude pole with imaginary part −2π(2.5 MHz)-2\pi(2.5\ \mathrm{MHz}) produces a Lorentzian power full width of approximately 5.0 MHz5.0\ \mathrm{MHz}. The separation is nearly four times that width, so a clean, well-coupled measurement channel should resolve two features. Interference backgrounds or inhomogeneous broadening could still obscure them.

Exercise 5: Purcell channeling and click probability

Section titled “Exercise 5: Purcell channeling and click probability”

A weakly coupled emitter has

g2π=25 MHz,κ2π=250 MHz,Δ2π=125 MHz.\begin{gathered} \frac{g}{2\pi}=25\ \mathrm{MHz}, \\ \frac{\kappa}{2\pi}=250\ \mathrm{MHz}, \\ \frac{\Delta}{2\pi}=125\ \mathrm{MHz}. \end{gathered}

Its noncavity rates are γbg/(2π)=1.0 MHz\gamma_{\rm bg}/(2\pi)=1.0\ \mathrm{MHz} and γnr/(2π)=0.5 MHz\gamma_{\rm nr}/(2\pi)=0.5\ \mathrm{MHz}. The useful port has κcol/κ=0.70\kappa_{\rm col}/\kappa=0.70, while ηprop=0.80\eta_{\rm prop}=0.80 and ηdet=0.60\eta_{\rm det}=0.60.

  1. Find Γcav/(2π)\Gamma_{\rm cav}/(2\pi) and βcav\beta_{\rm cav}.
  2. Find the probability that one initial emitter excitation produces a detector click through the selected path.
Solution

Using the common megahertz units,

Γcav2π=(25)2(250)(125)2+(250/2)2 MHz=5.0 MHz.\begin{aligned} \frac{\Gamma_{\rm cav}}{2\pi} &= \frac{ (25)^2(250) }{ (125)^2+(250/2)^2 } \ \mathrm{MHz} \\ &= 5.0\ \mathrm{MHz}. \end{aligned}

The cavity branching ratio is

βcav=5.05.0+1.0+0.5≃0.769.\beta_{\rm cav} = \frac{5.0}{5.0+1.0+0.5} \simeq 0.769.

The total click probability is

ηclick=(0.769)(0.70)(0.80)(0.60)≃0.258.\begin{aligned} \eta_{\rm click} &= (0.769)(0.70)(0.80)(0.60) \\ &\simeq 0.258. \end{aligned}

About 77%77\% of excitations enter the cavity channel, but only about 26%26\% produce a registered click. Conflating those two numbers would overstate the system efficiency by almost a factor of three.

In a frame rotating at the emitter frequency, let the no-jump single-excitation amplitudes obey

c˙e=−igcc,c˙c=(iΔ−κ2)cc−ig∗ce.\begin{aligned} \dot c_e &= -igc_c, \\ \dot c_c &= \left( i\Delta-\frac{\kappa}{2} \right)c_c -ig^*c_e. \end{aligned}

Assume ∣g∣≪Δ2+(κ/2)2|g|\ll\sqrt{\Delta^2+(\kappa/2)^2}, negligible background decay on the cavity response time, and times after any fast transient, so c˙c≃0\dot c_c\simeq0. Eliminate ccc_c and identify the cavity-induced population-decay rate and frequency shift.

Solution

Setting the fast derivative to zero gives

cc≃−ig∗κ/2−iΔce.c_c \simeq - \frac{ig^*}{ \kappa/2-i\Delta } c_e.

Substitution into the emitter equation yields

c˙e=−∣g∣2κ/2−iΔce=−∣g∣2κ/2Δ2+(κ/2)2ce−i∣g∣2ΔΔ2+(κ/2)2ce.\begin{aligned} \dot c_e &= - \frac{|g|^2}{ \kappa/2-i\Delta } c_e \\ &= - \frac{ |g|^2\kappa/2 }{ \Delta^2+(\kappa/2)^2 } c_e -i \frac{ |g|^2\Delta }{ \Delta^2+(\kappa/2)^2 } c_e. \end{aligned}

Writing

c˙e=−(Γcav2+iδcav)ce,\dot c_e = - \left( \frac{\Gamma_{\rm cav}}{2} +i\delta_{\rm cav} \right)c_e,

we identify

Γcav=∣g∣2κΔ2+(κ/2)2,δcav=∣g∣2ΔΔ2+(κ/2)2.\begin{gathered} \Gamma_{\rm cav} = \frac{ |g|^2\kappa }{ \Delta^2+(\kappa/2)^2 }, \\ \delta_{\rm cav} = \frac{ |g|^2\Delta }{ \Delta^2+(\kappa/2)^2 }. \end{gathered}

The same eliminated susceptibility produces a dissipative rate from its real part and a reactive frequency shift from its imaginary part. Reversing the definition of detuning reverses the sign of δcav\delta_{\rm cav} but not the decay rate.

Exercise 7: Dispersive scale and critical photon number

Section titled “Exercise 7: Dispersive scale and critical photon number”

An atom-cavity system has

g2π=20 MHz,Δ2π=1.00 GHz,κ2π=2.0 MHz.\begin{gathered} \frac{g}{2\pi}=20\ \mathrm{MHz}, \\ \frac{\Delta}{2\pi}=1.00\ \mathrm{GHz}, \\ \frac{\kappa}{2\pi}=2.0\ \mathrm{MHz}. \end{gathered}
  1. Estimate χ/(2π)\chi/(2\pi) and ncritn_{\rm crit}.
  2. For nˉ=25\bar n=25, evaluate gnˉ+1/∣Δ∣g\sqrt{\bar n+1}/|\Delta|.
  3. Compare the separation between the two state-dependent cavity frequencies with the empty-cavity linewidth.
Solution

The dispersive shift is

χ2π=(20 MHz)21000 MHz=0.40 MHz.\frac{\chi}{2\pi} = \frac{ (20\ \mathrm{MHz})^2 }{ 1000\ \mathrm{MHz} } = 0.40\ \mathrm{MHz}.

The conventional critical scale is

ncrit∼(1000)24(20)2=625.n_{\rm crit} \sim \frac{(1000)^2}{4(20)^2} = 625.

At nˉ=25\bar n=25,

gnˉ+1∣Δ∣=20261000≃0.102.\frac{ g\sqrt{\bar n+1} }{ |\Delta| } = \frac{ 20\sqrt{26} }{ 1000 } \simeq 0.102.

The leading dispersive expansion is plausible, with corrections controlled by a parameter of order 10−210^{-2} in quantities that begin at second order, though precision work should retain higher orders.

The two atomic states shift the cavity by ±χ\pm\chi, so their resonance separation is

2χ2π=0.80 MHz.\frac{2\chi}{2\pi} = 0.80\ \mathrm{MHz}.

This is smaller than the 2.0 MHz2.0\ \mathrm{MHz} cavity full width. The states need not produce two resolved peaks: a phase-sensitive measurement can still distinguish their different complex transmission amplitudes after sufficient integration.

Exercise 8: Collective bright-state coupling

Section titled “Exercise 8: Collective bright-state coupling”

Twenty-five identical emitters couple with equal phase and g/(2π)=3.0 MHzg/(2\pi)=3.0\ \mathrm{MHz} to one cavity mode. Take

κ2π=20 MHz,γ2π=1.0 MHz,\frac{\kappa}{2\pi}=20\ \mathrm{MHz}, \qquad \frac{\gamma}{2\pi}=1.0\ \mathrm{MHz},

with no pure dephasing or inhomogeneous broadening.

  1. Find G/(2π)G/(2\pi) and the collective cooperativity.
  2. Estimate the resonant separation of the two collective weak-excitation poles.
  3. Explain why the result need not survive arbitrary emitter detunings.
Solution

For equal couplings,

G2π=25(3.0 MHz)=15 MHz.\frac{G}{2\pi} = \sqrt{25} \left( 3.0\ \mathrm{MHz} \right) = 15\ \mathrm{MHz}.

The collective cooperativity is

CN=4G2κγ=4(15)2(20)(1)=45.C_N = \frac{4G^2}{\kappa\gamma} = \frac{4(15)^2}{(20)(1)} = 45.

The pole separation follows from the single-bright-mode formula:

Δωpoles2π=2(15)2−(20−1)216 MHz≃28.5 MHz.\begin{aligned} \frac{\Delta\omega_{\rm poles}}{2\pi} &= 2 \sqrt{ (15)^2 - \frac{(20-1)^2}{16} } \ \mathrm{MHz} \\ &\simeq 28.5\ \mathrm{MHz}. \end{aligned}

Identical resonance frequencies make one collective superposition bright and leave orthogonal superpositions dark. Inhomogeneous detunings mix those collective states and dephase their amplitudes. If the detuning spread is comparable with GG or the polariton linewidths, the simple N\sqrt N doublet broadens or fragments.

Exercise 9: Integrated escape in strong coupling

Section titled “Exercise 9: Integrated escape in strong coupling”

For resonant exchange from ∣e,0⟩|e,0\rangle with real g and positive rates, define E=∫0∞ρee(t)dtE=\int_0^\infty\rho_{ee}(t)dt, K=∫0∞ρcc(t)dtK=\int_0^\infty\rho_{cc}(t)dt, and Y=∫0∞Im⁡ρec(t)dtY=\int_0^\infty\operatorname{Im}\rho_{ec}(t)dt. Derive the exact cavity escape probability from the one-excitation master equation.

Solution

The population and coherence equations are

ρ˙ee=−γρee−2gIm⁡ρec,ρ˙cc=−κρcc+2gIm⁡ρec,\dot\rho_{ee}=-\gamma\rho_{ee}-2g\operatorname{Im}\rho_{ec},\quad \dot\rho_{cc}=-\kappa\rho_{cc}+2g\operatorname{Im}\rho_{ec}, ddtIm⁡ρec=g(ρee−ρcc)−γ+κ2Im⁡ρec.\frac{d}{dt}\operatorname{Im}\rho_{ec} =g(\rho_{ee}-\rho_{cc})-\frac{\gamma+\kappa}{2} \operatorname{Im}\rho_{ec}.

Both excited populations vanish at long time. Integration gives 1=γE+κK1=\gamma E+\kappa K, 2gY=κK2gY=\kappa K, and g(E−K)=(γ+κ)Y/2g(E-K)=(\gamma+\kappa)Y/2. Eliminating E and Y yields

βcav=κK=κγ+κ4g24g2+γκ.\beta_{\rm cav}=\kappa K =\frac{\kappa}{\gamma+\kappa} \frac{4g^2}{4g^2+\gamma\kappa}.

For γ=κ\gamma=\kappa and g≫κg\gg\kappa, the limiting probability is only one half even though C is large. The complementary emitter escape probability is γE=1−βcav\gamma E=1-\beta_{\rm cav}.