Cavity QED
Cavity quantum electrodynamics studies the coherent and dissipative dynamics of quantum emitters coupled to selected electromagnetic resonances. A cavity does more than store light. It concentrates the electric field into a small mode volume, repeatedly brings that field past the emitter, and routes part of the emitted radiation into identifiable output channels. These three effects can make the interaction of one emitter with one photon measurable, controllable, and sometimes faster than every relevant loss process.
The smallest useful model contains one cavity mode, one optical transition, and several reservoirs. Its behavior is governed not by the coupling alone but by the comparison
Here is the cavity energy-decay rate, is the emitter population-decay rate into noncavity channels, is pure dephasing, and is the atom-cavity detuning. Throughout this page, is the full width at half maximum of the empty-cavity power resonance and the intracavity field amplitude decays as . This convention matters: factors of two in cavity-QED figures of merit often come from comparing rates defined in different ways.
The Jaynes–Cummings Model derives the closed-system dressed ladder and excitation exchange. Here the focus is physical coupling, loss, and measurable spectra. Cavity QED Platforms compares implementations; conditional cavity dynamics connects them to measurement records.
Required background. Quantized Modes defines the vacuum field, Input–Output Theory supplies port relations, the Two-Level Atom supplies the emitter basis, and Spontaneous Emission explains environmental decay.
One Emitter in a Lossy Cavity
Section titled “One Emitter in a Lossy Cavity”A cavity concentrates the vacuum field at an emitter, while its ports and parasitic losses set the total rate . The emitter also radiates into noncavity modes at rate . In the ideal one-excitation spectrum, the bare atom and cavity resonances hybridize and open a gap at zero detuning. The lower panel plots the exact lossless frequencies versus ; the lower branch stays below both bare frequencies and the upper above both. Loss broadens these resonances and can hide the gap in a measured spectrum.
The mirrors in the figure are only one realization. Fabry–Pérot cavities, whispering-gallery resonators, photonic-crystal defects, microwave resonators, and nanophotonic cavities differ greatly in geometry but share the same local ingredients: a normalized mode field, an emitter transition, and specified decay channels.
Cavity Modes and the Vacuum Field
Section titled “Cavity Modes and the Vacuum Field”Resonance, linewidth, and quality factor
Section titled “Resonance, linewidth, and quality factor”Let the selected cavity mode have angular frequency and annihilation operator . Its total energy-decay rate is a sum over useful ports and unmonitored loss,
For an isolated Lorentzian resonance,
A large gives a long storage time; a small effective mode volume gives a large field per photon. Neither quantity by itself establishes strong coupling. A very high- cavity can have poor spatial overlap with the emitter, and a tiny mode can be so lossy that coherent exchange is overdamped.
Normalized mode function
Section titled “Normalized mode function”For a lossless, scalar, positive, nondispersive dielectric, use a normalizable closed-cavity mode as an approximation to an isolated, weakly leaking resonance. Write its positive-frequency field as
with normalization
At a field antinode , an effective volume may be defined by
For a dipole aligned with the local polarization, the corresponding maximum root-mean-square vacuum field is
This expression is a useful design estimate, not a universal definition for absorbing or strongly dispersive media. Quasinormal-mode normalization and the electromagnetic Green tensor are then safer tools. The conservative mode quantization is developed in Quantized Electromagnetic Modes.
What actually sets the overlap
Section titled “What actually sets the overlap”The emitter samples the vector field at its position. The relevant overlap contains
- the standing-wave or traveling-wave amplitude at ;
- alignment between the transition dipole and local polarization;
- angular-momentum and Clebsch–Gordan factors;
- the coherent superposition of Zeeman or hyperfine sublevels;
- averaging over motion, spectral diffusion, and technical drift.
Consequently, the maximum coupling quoted for a cavity geometry can be much larger than the time-averaged coupling in an experiment.
Atom–Field Coupling
Section titled “Atom–Field Coupling”In the electric-dipole approximation,
For transition dipole , the rotating-wave single-photon coupling is
An overall phase of can be absorbed into or the atomic states for one emitter and one mode. Its magnitude is physical. At optimal position and orientation,
The factor is the matrix element connecting and . Even when the cavity begins in the vacuum, the matrix element remains : the vacuum has zero mean electric field but nonzero field fluctuations.
After the rotating-wave approximation, the closed part of the minimal model is
This Hamiltonian is reliable when one transition and one mode are spectrally isolated, the coupling is weak compared with optical frequencies, and the mode function is not materially altered by the emitter. Ultrastrong coupling, dense multilevel structure, or overlapping resonances require a larger model.
Open-System Model and Rate Dictionary
Section titled “Open-System Model and Rate Dictionary”A driven, lossy single-emitter model is
where
These independent Markovian reservoirs have negligible thermal occupation in their lowering channels. With this normalization, pure dephasing contributes to the optical coherence decay. The total transverse rate is
The model separates physically different quantities:
| Symbol | Meaning | Decay or linewidth convention |
|---|---|---|
| total cavity energy decay | cavity amplitude decays at | |
| coupling to port | contributes to both damping and an output field | |
| absorption, scattering, or other uncollected cavity loss | damps the mode without a useful port | |
| emitter population decay outside the modeled cavity channel | excited population decays at | |
| pure dephasing | adds directly to coherence decay | |
| total emitter coherence decay | optical amplitude decays at |
When the emitter is weakly excited, set and , approximate , and drive port 1 with coherent amplitude . In a frame rotating at the probe frequency,
where and . These are the equations of two damped coupled oscillators. They accurately describe weak-probe spectra, but they discard saturation and therefore cannot reproduce all single-photon nonlinearities or higher excitation manifolds.
Weak and Strong Coupling
Section titled “Weak and Strong Coupling”Cooperativity
Section titled “Cooperativity”If pure dephasing is negligible, a standard single-emitter cooperativity is
Equivalently, C is the ratio of the broad-cavity resonant emission rate to the noncavity population-decay rate . With pure dephasing present, the weak-probe response is more directly organized by
Since when , the two definitions then agree. A paper that instead calls the cavity field-amplitude decay rate or calls the atomic half width will display different factors of two or four. The invariant procedure is to reconstruct the equations of motion and identify which amplitudes or populations each rate damps.
High cooperativity means that the selected cavity channel competes successfully with unwanted emitter decoherence. It does not by itself mean that a photon oscillates coherently between atom and cavity. For example, a bad cavity can have
It efficiently funnels emission into the cavity output while eliminating the intracavity field too quickly for several resolved swaps.
A practical regime map
Section titled “A practical regime map”- Perturbative weak coupling, . The cavity weakly modifies an emitter, or the emitter weakly perturbs the cavity.
- Bad-cavity or Purcell regime, . Eliminating the cavity gives enhanced irreversible emission into its output.
- High-cooperativity bad cavity, but . Channeling and extinction can be strong without many coherent swaps.
- Strong coupling, above the relevant linewidth scales. Atom and cavity form resolvable hybrid modes and can exchange excitation coherently.
- Dispersive coupling, . State-dependent frequency shifts dominate real exchange.
- Saturated response. Once the probe appreciably changes , the linear coupled-oscillator formulas fail and nonlinear quantum dynamics matters.
These boundaries are crossovers, not phase transitions. A device can be strongly coupled for a stationary atom at an antinode but appear inhomogeneously broadened after averaging over motion. Conversely, a device without resolved normal-mode peaks may still have excellent cooperativity and single-emitter readout.
Vacuum Rabi Splitting
Section titled “Vacuum Rabi Splitting”Ideal avoided crossing
Section titled “Ideal avoided crossing”In the one-excitation manifold of the lossless model, the two eigenfrequencies are
Far from resonance, one branch is atom-like and the other cavity-like. Near , they hybridize into upper and lower polaritons. Their minimum frequency separation is
After choosing phases so is real, an initial exactly on resonance and with no loss evolves as
The first complete transfer occurs at , and the population oscillation has angular frequency . This time-domain exchange and the frequency-domain avoided crossing are two views of the same coupling.
Complex poles in a lossy system
Section titled “Complex poles in a lossy system”In the weak-excitation sector, define the uncoupled complex frequencies
The coupled poles are
On exact resonance and with , this reduces to
The real parts separate once . That algebraic condition is not a universal criterion for observing two peaks. If the common linewidth is broader than the separation, the peaks merge. Interference with a prompt reflected field can create a dip or asymmetry, and transmission, reflection, fluorescence, and intracavity spectra weight the poles differently.
Thus three statements should be kept distinct:
- The closed Hamiltonian has an avoided crossing for every nonzero .
- The open response generically has two complex poles, coalescing at an exceptional point; on resonance their real parts split only above the threshold stated in the chosen rate convention.
- A particular experiment resolves two spectral features only when their separation, widths, port geometry, signal-to-noise ratio, and background permit it.
The conservative statement identifies an unambiguous strong-coupling limit, but many useful experiments operate near its boundary.
What makes the splitting quantum?
Section titled “What makes the splitting quantum?”Two classical damped oscillators also exhibit normal-mode splitting. A spectral doublet alone therefore demonstrates coherent mode hybridization, not by itself the quantization of the electromagnetic field. The vacuum Rabi interpretation additionally relies on calibrated coupling to a single or known small number of emitters, operation near the zero-photon limit, and consistency with the one-quantum matrix element . More distinctively quantum signatures include excitation-number-dependent splittings, photon blockade, sub-Poissonian output, and conditional single-quantum dynamics.
Purcell Effect and Emission Channeling
Section titled “Purcell Effect and Emission Channeling”Eliminating a broad cavity
Section titled “Eliminating a broad cavity”Suppose the cavity is broader than the coherent coupling and changes much faster than the emitter. Adiabatic elimination gives an additional emitter-population decay rate into the cavity channel,
On resonance,
If is the background radiative rate and nonradiative decay is negligible, then
This is the weak-coupling meaning of cooperativity. The cavity has converted reversible coupling into an effectively irreversible decay channel because a cavity photon escapes on the short time scale .
For a narrow emitter with optimal polarization and position in a weak-coupling cavity, relative to its radiative rate in a homogeneous host of refractive index , the same result is often expressed as
where is the vacuum wavelength and microscopic local-field factors are assumed consistent between the reference and cavity. It is multiplied in practice by spatial, polarization, and spectral-overlap factors. The Spontaneous Emission page develops the more general environmental and Green-tensor viewpoint.
Branching ratio is not collection efficiency
Section titled “Branching ratio is not collection efficiency”Let denote residual radiative decay outside the selected cavity mode and nonradiative loss. In the eliminated-cavity, exponential-decay limit, the probability that one initially prepared excitation leaves through the cavity channel is
This branching expression is not the general strong-coupling result. For resonant undriven exchange from , no pure dephasing, and , exact integration gives
The extra factor approaches one in the bad-cavity limit. At very strong coupling the excitation spends comparable times in atom and cavity, so escape competes with emitter decay and . Driven Raman generation has different dynamics and must not be assigned this initial-excitation formula.
Only a fraction of those cavity photons leave by the desired port. Including propagation and detector efficiencies,
A large Purcell factor can therefore coexist with poor detected efficiency if absorption dominates the cavity linewidth, the output is split among several ports, or the external optics have poor mode matching. Conversely, improving outcoupling can lower and hence change the Purcell rate. Cavity design is an optimization over both emission and extraction.
Limits of the simple Purcell formula
Section titled “Limits of the simple Purcell formula”The Lorentzian expression assumes weak excitation, one broad cavity mode, Markovian reservoirs, and an emitter whose population and coherence vary slowly compared with the cavity response. In particular, dephasing broadening cannot simply be ignored in the spectral overlap. It must be reconsidered when
- coherent exchange is resolved;
- pure dephasing or spectral diffusion broadens the emitter;
- several cavity modes or transitions overlap;
- the cavity line is non-Lorentzian;
- nonradiative decay or blinking changes the emitter quantum yield;
- the electromagnetic environment is absorptive or strongly dispersive.
Purcell enhancement is thus a regime of cavity QED, not a synonym for strong coupling.
Cavity-Enhanced Measurement
Section titled “Cavity-Enhanced Measurement”Resonant extinction and transmission
Section titled “Resonant extinction and transmission”The steady weak-probe cavity amplitude follows directly from the linear equations:
Together with the port relation
this predicts the coherent reflection or transmission signal in the sign convention used on the Input–Output Theory Overview. On double resonance, the emitter adds to the cavity response denominator. Relative to an empty cavity, the intracavity field is reduced by a factor
for the same input and port convention. Even when individual fluorescence photons are hard to collect, this coherent perturbation can make one emitter visible in a bright transmitted or reflected probe.
The observed contrast is not a direct measurement of without a port model. Internal loss, mode mismatch, polarization leakage, prompt reflection, and detector normalization all affect the trace.
Dispersive readout
Section titled “Dispersive readout”For a detuning large compared with the coupling across all occupied manifolds,
real excitation exchange is suppressed. For the stated two-level JC Hamiltonian, to second order and after discarding a constant,
The emitter state shifts the cavity resonance by opposite amounts, so a probe acquires a state-dependent amplitude or phase. Conversely, cavity photons shift the emitter and fluctuate in number, producing AC Stark shifts and measurement-induced dephasing. The scale
marks where the simplest dispersive expansion loses uniform validity; the exact threshold depends on the required accuracy and multilevel structure.
Dispersive does not mean backaction-free. Off-resonant photons can still scatter, and any record that distinguishes atomic states dephases their superposition when the record is ignored. A measurement is quantum nondemolition only with respect to a specified observable and effective Hamiltonian, over a specified time scale.
What the detector actually sees
Section titled “What the detector actually sees”Cavity-enhanced readout may use
- direct counting of cavity fluorescence or transmitted photons;
- extinction or transmission contrast of a coherent probe;
- homodyne phase shifts from a dispersive interaction;
- heterodyne records when both quadratures or an offset band are useful;
- correlations such as to reveal nonlinear dynamics.
The receiver physics remains in Photon Counting and Homodyne and Heterodyne Detection. Conditional jumps, innovations, and trajectory backaction remain in the open-system cavity-QED map.
Several Emitters
Section titled “Several Emitters”For emitters near their collective ground state, the coupling vector selects one bright superposition in the single-excitation space. A closed two-mode description also requires degenerate emitter frequencies and compatible damping; otherwise free evolution mixes bright and dark modes. Its coupling is
For identical couplings, . This enhancement follows from coherent addition of excitation amplitudes, not from independent emission rates. Dark collective states, inhomogeneous detunings, motion, and dipole-dipole interactions can invalidate the simple two-oscillator description. A measured splitting therefore requires control or calibration of the participating ensemble.
Computational Notebook
Section titled “Computational Notebook”The Cavity QED Simulation Notebook provides reproducible dressed-spectrum, vacuum-Rabi, collapse–revival, photon-cutoff, and small Lindblad-loss benchmarks. Use this page for the physical rate dictionary and experiment-facing interpretation; use the notebook for finite-basis construction and numerical validation.
Exercises
Section titled “Exercises”Exercise 1: Vacuum field and maximum coupling
Section titled “Exercise 1: Vacuum field and maximum coupling”An empty-space cavity mode has wavelength and effective volume
An optimally oriented transition has dipole magnitude . Estimate and . Use , , and .
Solution
The angular frequency and mode volume in SI units are
For vacuum refractive index ,
The dipole magnitude is
Therefore
This is an ideal spatial and polarization value. The measured coupling will be smaller if the emitter is not at the antinode or if the transition dipole does not align with the local mode.
Exercise 2: Spatial, polarization, and internal-state overlap
Section titled “Exercise 2: Spatial, polarization, and internal-state overlap”An emitter in a standing-wave cavity has
where is the angle between the dipole and local polarization and is an angular-momentum amplitude. Take measured from an antinode, , and .
- Find .
- Find if all decay rates are unchanged.
Solution
Since ,
The full amplitude ratio is
Cooperativity scales as , so
Three moderate amplitude-overlap reductions have lowered the cooperativity by a factor of twelve. This is why quoting only the geometric can be misleading.
Exercise 3: High cooperativity without strong coupling
Section titled “Exercise 3: High cooperativity without strong coupling”A cavity and emitter are resonant, with
and negligible pure dephasing.
- Calculate the cooperativity.
- Calculate the resonant bad-cavity emission rate .
- Classify the system.
Solution
All three quoted numbers use the same angular-frequency conversion, so the factors of cancel in ratios:
The eliminated-cavity rate is
Thus cavity-mediated emission is forty times faster than background emission. Nevertheless,
so a cavity excitation escapes much faster than one coherent atom-cavity swap. This is a high-cooperativity bad-cavity system, not an unambiguous resolved-strong-coupling system.
Exercise 4: Dissipative polariton poles
Section titled “Exercise 4: Dissipative polariton poles”On exact resonance, a system with negligible pure dephasing has
Find the real-frequency separation of the two weak-excitation poles and the power linewidth associated with their common imaginary part. Would a doublet be expected in a clean spectrum?
Solution
Writing every rate after division by in megahertz, the real offset of each pole is
The pole separation is therefore
The common imaginary part has magnitude
An amplitude pole with imaginary part produces a Lorentzian power full width of approximately . The separation is nearly four times that width, so a clean, well-coupled measurement channel should resolve two features. Interference backgrounds or inhomogeneous broadening could still obscure them.
Exercise 5: Purcell channeling and click probability
Section titled “Exercise 5: Purcell channeling and click probability”A weakly coupled emitter has
Its noncavity rates are and . The useful port has , while and .
- Find and .
- Find the probability that one initial emitter excitation produces a detector click through the selected path.
Solution
Using the common megahertz units,
The cavity branching ratio is
The total click probability is
About of excitations enter the cavity channel, but only about produce a registered click. Conflating those two numbers would overstate the system efficiency by almost a factor of three.
Exercise 6: Adiabatic elimination
Section titled “Exercise 6: Adiabatic elimination”In a frame rotating at the emitter frequency, let the no-jump single-excitation amplitudes obey
Assume , negligible background decay on the cavity response time, and times after any fast transient, so . Eliminate and identify the cavity-induced population-decay rate and frequency shift.
Solution
Setting the fast derivative to zero gives
Substitution into the emitter equation yields
Writing
we identify
The same eliminated susceptibility produces a dissipative rate from its real part and a reactive frequency shift from its imaginary part. Reversing the definition of detuning reverses the sign of but not the decay rate.
Exercise 7: Dispersive scale and critical photon number
Section titled “Exercise 7: Dispersive scale and critical photon number”An atom-cavity system has
- Estimate and .
- For , evaluate .
- Compare the separation between the two state-dependent cavity frequencies with the empty-cavity linewidth.
Solution
The dispersive shift is
The conventional critical scale is
At ,
The leading dispersive expansion is plausible, with corrections controlled by a parameter of order in quantities that begin at second order, though precision work should retain higher orders.
The two atomic states shift the cavity by , so their resonance separation is
This is smaller than the cavity full width. The states need not produce two resolved peaks: a phase-sensitive measurement can still distinguish their different complex transmission amplitudes after sufficient integration.
Exercise 8: Collective bright-state coupling
Section titled “Exercise 8: Collective bright-state coupling”Twenty-five identical emitters couple with equal phase and to one cavity mode. Take
with no pure dephasing or inhomogeneous broadening.
- Find and the collective cooperativity.
- Estimate the resonant separation of the two collective weak-excitation poles.
- Explain why the result need not survive arbitrary emitter detunings.
Solution
For equal couplings,
The collective cooperativity is
The pole separation follows from the single-bright-mode formula:
Identical resonance frequencies make one collective superposition bright and leave orthogonal superpositions dark. Inhomogeneous detunings mix those collective states and dephase their amplitudes. If the detuning spread is comparable with or the polariton linewidths, the simple doublet broadens or fragments.
Exercise 9: Integrated escape in strong coupling
Section titled “Exercise 9: Integrated escape in strong coupling”For resonant exchange from with real g and positive rates, define , , and . Derive the exact cavity escape probability from the one-excitation master equation.
Solution
The population and coherence equations are
Both excited populations vanish at long time. Integration gives , , and . Eliminating E and Y yields
For and , the limiting probability is only one half even though C is large. The complementary emitter escape probability is .
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