XXZ Chain
The spin- XXZ chain is an axially anisotropic nearest-neighbor Heisenberg chain whose single parameter connects a polarized ferromagnet, a gapless Luttinger liquid, the isotropic antiferromagnet, and a gapped Néel phase while retaining Bethe-ansatz integrability.
The phase diagram below is at zero temperature and zero longitudinal field, with positive transverse exchange. The same parameter changes the interaction between Jordan–Wigner fermions, so only one point is a free-fermion model.
Helpful background. Heisenberg Chain explains the isotropic spin normalization and multiplets; XXZ Spin Chain develops the Bethe and Luttinger descriptions.
Axial Anisotropy and the XXZ Hamiltonian
Section titled “Axial Anisotropy and the XXZ Hamiltonian”The reference chain has these physical choices.
| Field | Baseline choice |
|---|---|
| sites | spin- degrees of freedom |
| local space | |
| operators | dimensionless |
| geometry | uniform one-dimensional nearest-neighbor chain |
| transverse exchange | |
| longitudinal exchange | with real dimensionless |
| field | |
| boundaries | open or periodic, stated explicitly |
| energy offset | none |
| disorder, dimerization, and longer range | absent |
| thermodynamic reference | even periodic rings followed by |
The zero-field phase labels below assume . A longitudinal field is a useful integrable deformation, but its value must be stated because it changes magnetization, filling, and parts of the phase diagram. Negative , transverse fields, bond alternation, and frustrated exchange are not silently absorbed into the baseline.
Degrees of Freedom and Basis
Section titled “Degrees of Freedom and Basis”The Hilbert space is
Dimensionless spin operators satisfy
and
The product basis uses
Writing
gives the bond identity
The longitudinal term is diagonal in the product basis. The transverse term exchanges an adjacent up-down pair and conserves the total number of down spins.
Hamiltonian and Conventions
Section titled “Hamiltonian and Conventions”For an open chain,
For a periodic chain,
with
The open chain has undirected bonds; an ordinary ring has . As in other nearest-neighbor models, the periodic shorthand can count the same undirected pair twice. A two-site check therefore uses one explicitly open bond.
A longitudinal field measured in energy units adds
Pauli-matrix form
Section titled “Pauli-matrix form”In terms of Pauli matrices,
A result four times too large in the exchange spectrum or twice too large in the field response indicates that Pauli and spin conventions were mixed.
Anisotropy tensor
Section titled “Anisotropy tensor”The exchange constants are
is dimensionless. The labels easy plane and easy axis refer to this tensor, not to a classical orientation already chosen by a finite quantum ground state.
Symmetries
Section titled “Symmetries”Axial spin rotations
Section titled “Axial spin rotations”For every and longitudinal field ,
is conserved:
The internal continuous symmetry is generically . If sites are down relative to the all-up state,
This is both a physical charge decomposition and the natural exact-diagonalization basis.
Symmetry enhancement
Section titled “Symmetry enhancement”At
the Hamiltonian becomes isotropic:
All three components of total spin commute with , enhancing to . Heisenberg Chain describes the resulting multiplets and exact finite spectra.
Spin reversal and time reversal
Section titled “Spin reversal and time reversal”At , a global rotation about maps
and exchanges magnetization sectors . It leaves the XXZ exchange invariant.
Physical time reversal sends every spin component to its negative and also preserves the zero-field Hamiltonian. A nonzero longitudinal field breaks both magnetization reversal and time reversal, while retaining the axial symmetry.
Lattice symmetries
Section titled “Lattice symmetries”The uniform periodic chain has one-site translation and reflection symmetry. The open chain retains reflection about its midpoint but not translation. Bond alternation, disorder, twists, and boundary fields can change the spatial symmetry without necessarily breaking magnetization conservation.
Zero-Field Phase Map
Section titled “Zero-Field Phase Map”For , , and the thermodynamic ground state:
| Anisotropy | Ground-state regime | Bulk gap | Long-distance character |
|---|---|---|---|
| -polarized ferromagnet | nonzero away from | saturated magnetization | |
| first-order endpoint | quadratic soft mode | enlarged ground space on an even bipartite chain | |
| easy-plane Luttinger liquid | zero | algebraic correlations and | |
| isotropic antiferromagnet | zero | with logarithmic corrections | |
| easy-axis antiferromagnet | nonzero | thermodynamic Néel order |
The critical interval is an entire line of fixed points, not one isolated critical point. Its correlation exponents vary continuously with . The endpoint at is first order and has a vanishing linear-mode velocity; the transition at is Berezinskii–Kosterlitz–Thouless and opens a gap through an essential singularity.
A finite chain does not literally display all thermodynamic order parameters. Phase assignments require size sequences, long-distance correlations, sector information, or a symmetry-breaking source taken to zero after the thermodynamic limit.
Important Limits
Section titled “Important Limits”XX point
Section titled “XX point”At
Jordan–Wigner maps the chain to free spinless fermions. At zero field and half filling,
The fermions are free, but transverse spin operators contain nonlocal strings. Their correlations are not reduced to a one-body spin observable.
Isotropic point
Section titled “Isotropic point”At
the model is the antiferromagnetic spin- Heisenberg chain. Exact bulk fingerprints include
and
The point remains gapless, but marginally irrelevant interactions produce slow logarithmic corrections.
Ferromagnetic endpoint
Section titled “Ferromagnetic endpoint”On an even bipartite chain, a staggered rotation about maps the Hamiltonian to an isotropic ferromagnetic Heisenberg chain. Its ground-space dimension is therefore
for spin . The low-energy dispersion is quadratic, so the endpoint is not an ordinary finite-velocity conformal point.
Easy-axis limits
Section titled “Easy-axis limits”For , the longitudinal exchange dominates and the two alternating configurations organize the low-energy antiferromagnetic sector. Transverse exchange dresses them with quantum fluctuations. For , the two fully polarized product states are exact zero-field ground states.
Integrability and Its Scope
Section titled “Integrability and Its Scope”The uniform nearest-neighbor spin- chain is Bethe-ansatz integrable for the standard anisotropies and a longitudinal field. Exactness remains quantity and boundary dependent.
| Quantity or regime | Status |
|---|---|
| finite-volume spectrum | encoded by Bethe roots after sector and boundary conventions are fixed |
| exactly quadratic after Jordan–Wigner | |
| one-magnon sector | exact plane-wave result |
| zero-field phase boundaries | exact |
| bulk energy and dressed thermodynamics | exact integral-equation framework |
| zero-field and in the critical interval | exact |
| finite-size conformal spectrum | universal leading form with model-specific corrections |
| correlation exponents in the critical interval | exact once the bosonization convention is fixed |
| correlation amplitudes and dynamical functions | substantially harder; exact representations need further evaluation |
| generic next-neighbor, disordered, or transversely driven chain | not generically integrable |
Bethe solvability does not make the model free. For , quasiparticle momenta or rapidities are coupled by nontrivial scattering phases, and spin correlations require matrix elements as well as energies.
Fermions, Magnons, and Luttinger Parameters
Section titled “Fermions, Magnons, and Luttinger Parameters”Jordan–Wigner form
Section titled “Jordan–Wigner form”With
the open chain maps to
Thus the spinless-fermion hopping and nearest-neighbor interaction are
up to a removable sign of from a staggered phase convention on this open chain. On a periodic odd ring, the same transformation changes the boundary twist and cannot silently remove the sign. is free; retains a density interaction.
One-magnon and saturation check
Section titled “One-magnon and saturation check”For a periodic chain in a longitudinal field, the all-up energy is
One down spin with physical wave number has excitation energy
For an even periodic ring, or in the thermodynamic limit, the minimum lies at . For the saturation field is
This is both a necessary one-magnon condition and a sufficient ground-state condition in that regime. To see sufficiency, write each bond with half of the field on each end. Its four energies are
For , the all-up state minimizes every bond, hence their sum. At equality other states can become degenerate. A finite odd ring need not contain and has a different finite-size threshold.
For , the thermodynamic equilibrium positive saturation threshold is instead : any selects all-up over all-down. The negative value is merely a one-magnon stability bound for the all-up branch, not its global ground-state boundary. At zero field in that regime, the magnon gap is
It closes at .
Luttinger parameters
Section titled “Luttinger parameters”In the critical interval, write
At zero magnetization, one common bosonization convention gives
and
The limiting checks are
and
throughout , with endpoint and logarithmic qualifications as stated above.
Correlation exponents
Section titled “Correlation exponents”With the same convention, leading zero-magnetization correlations behave schematically as
Here is an integer site separation. The amplitudes are nonuniversal. At , multiplicative logarithms modify the pure powers. At finite magnetization, both and the oscillation wavevectors change.
Boundary Conditions and Finite-Size Effects
Section titled “Boundary Conditions and Finite-Size Effects”Three boundary statements must be kept distinct:
- open and periodic spin chains have different bond counts;
- periodic Jordan–Wigner fermions acquire a boundary sign fixed by total fermion parity;
- Bethe equations depend on periodicity, twists, magnetization sector, and rapidity convention.
These effects are subextensive in a bulk energy density but decisive for exact finite spectra, momenta, and gaps.
An even ring is the clean zero-field thermodynamic sequence. In the easy-axis antiferromagnet, an odd periodic ring frustrates the alternating order. Near the BKT point, very large correlation lengths and logarithmic corrections make modest system sizes especially deceptive.
A twist can be imposed through
The curvature of the ground energy with probes spin stiffness, but conventions differ by factors of , , and .
Typical Observables
Section titled “Typical Observables”Magnetization and order
Section titled “Magnetization and order”The uniform magnetization per site is
For an even chain, a staggered operator is
In a finite spin-reversal eigenstate, can vanish even in the easy-axis regime. Useful diagnostics include , the staggered structure factor, long-distance correlations, and a controlled symmetry-breaking source.
Correlations and structure factors
Section titled “Correlations and structure factors”The anisotropy makes longitudinal and transverse correlators inequivalent:
and
Their Fourier transforms distinguish -ferromagnetic, critical easy-plane, and Néel regimes. Structure Factors explains normalization and scattering conventions.
Energy gaps and entanglement
Section titled “Energy gaps and entanglement”The finite gap
must identify magnetization, momentum, parity, and boundary sectors. In the critical phase, low gaps scale as with corrections. In either gapped phase they approach nonzero bulk scales, aside from symmetry-partner or boundary splittings.
At criticality, interval entanglement has the leading logarithm. In the gapped phases it saturates beyond the correlation length, with possible finite-cat or boundary contributions.
Spin current
Section titled “Spin current”The continuity equation for defines one current convention:
Transport claims require temperature, magnetization, frequency, system-size, and order-of-limits conventions. Integrability can protect ballistic contributions in selected regimes but does not make every transport coefficient trivial.
Physical Phenomena
Section titled “Physical Phenomena”Interacting criticality
Section titled “Interacting criticality”For away from the free point , the chain is both interacting and exactly integrable. Its low-energy physics is collective: the Luttinger parameter continuously changes correlation exponents even though the central charge remains .
Fractionalization and variable descriptions
Section titled “Fractionalization and variable descriptions”The same microscopic system can be described as local spins, interacting spinless fermions, Bethe quasiparticles, or a compact boson at low energy. These descriptions are complementary rather than interchangeable. A local spin operator may be nonlocal in fermions, and the continuum theory omits lattice-scale observables.
Distinct endpoints
Section titled “Distinct endpoints”At , a quadratic soft mode and enlarged ground space accompany a first-order boundary. At , a marginal interaction drives a BKT transition whose gap opens essentially rather than through a simple power. Treating both as ordinary critical endpoints loses the central physics.
Finite versus thermodynamic order
Section titled “Finite versus thermodynamic order”The easy-axis phase has two symmetry-related Néel states in the thermodynamic description, while a finite ring can retain translation or spin-reversal symmetry. Conversely, large finite staggered correlations inside the critical phase do not imply a nonzero order parameter.
No nonzero-temperature order
Section titled “No nonzero-temperature order”A short-range one-dimensional XXZ chain has no nonzero-temperature transition into true ferromagnetic or Néel long-range order. Low-temperature quantum-critical windows and long correlation lengths are crossovers, not additional equilibrium phase transitions.
Minimal Worked Example: One Anisotropic Bond
Section titled “Minimal Worked Example: One Anisotropic Bond”For one open bond at zero field,
The parallel states have
In the zero-magnetization sector, define
Their energies are
At , the three triplet states become degenerate at and the singlet lies at . At , the singlet crosses the two parallel states. The trace is zero for every :
The normalized second moment is
The dimer catches normalization and the crossing, but it does not reproduce the thermodynamic Luttinger phase or BKT transition.
Numerical Benchmark
Section titled “Numerical Benchmark”Interacting four-site ring
Section titled “Interacting four-site ring”Use , periodic boundaries, four distinct undirected bonds,
and no constant offset. The anisotropy is interacting after Jordan–Wigner and is not an point.
The complete spectrum is
| degeneracy | |
|---|---|
| 1 | |
| 2 | |
| 1 | |
| 7 | |
| 2 | |
| 2 | |
| 1 |
The ground energy is
The degeneracies sum to , and the fixed- block dimensions are
Useful independent comparisons are
At , spin reversal also maps the block to the block with the same spectrum.
General trace-moment identity
Section titled “General trace-moment identity”For a simple graph with distinct XXZ bonds,
at zero field. Distinct Pauli strings are orthogonal under the full trace, so cross-bond terms vanish even for adjacent bonds. With and , this gives .
Bulk endpoint checks
Section titled “Bulk endpoint checks”After the finite matrix passes, separate thermodynamic calculations can test
and
These values use the unshifted spin-operator Hamiltonian. Adding per bond changes energy densities but not eigenstates or gaps.
Other Anisotropic Chains
Section titled “Other Anisotropic Chains”| Variant | What changes | Further calculation |
|---|---|---|
| isotropic point | set and recover | Heisenberg Chain dossier |
| XX model | set and obtain free fermions | Spinless Fermion Chains |
| longitudinal field | change magnetization and fermion filling | XXZ Spin Chain |
| twist | probe stiffness through boundary phase | Boundary Conditions on Lattices |
| dimerized chain | alternate bond strengths | translation and phase structure change |
| – chain | add frustrating next-neighbor exchange | generic Bethe integrability is lost |
| random-field chain | break translation and study disorder dynamics | Many-Body Localization Preview |
| higher-spin XXZ chain | enlarge the onsite representation | phase and integrability claims must be re-established |
For the isotropic limit, the Heisenberg Chain Hamiltonian card gives a compact operator formula.
Exercises
Section titled “Exercises”1. Verify magnetization conservation
Section titled “1. Verify magnetization conservation”Show directly that the exchange Hamiltonian commutes with .
Solution
The longitudinal term is built from operators and therefore commutes with . For one transverse term,
The Hermitian-conjugate term also commutes, so
Each transverse exchange moves a down spin but does not create or destroy one.
2. Recover the dimer spectrum
Section titled “2. Recover the dimer spectrum”Diagonalize the zero-magnetization block of the one-bond Hamiltonian in the basis .
Solution
The block is
Its symmetric and antisymmetric eigenvectors are and , with eigenvalues
and
The parallel states are separate one-dimensional magnetization sectors with energy .
3. Check the Pauli normalization
Section titled “3. Check the Pauli normalization”Write the one-bond Hamiltonian entirely in Pauli matrices. If a code omits the factor , how do the dimer energies and the trace moment change?
Solution
The correct Pauli form is
Omitting multiplies the Hamiltonian and every energy by four. Since the second trace moment is quadratic in , it becomes sixteen times too large:
4. Derive the saturation field
Section titled “4. Derive the saturation field”Use the one-magnon dispersion to derive the positive saturation field for and .
Solution
The excitation energy above the all-up state is
For , its minimum occurs at , where . Stability requires
Therefore
For an even periodic chain, the bond-energy argument above also proves sufficiency. On a finite odd ring, minimize over the actually allowed wave numbers. The result depends on the spin-operator normalization and the field term being .
5. Prove the trace-moment identity
Section titled “5. Prove the trace-moment identity”Derive the zero-field normalized second moment for a simple graph of XXZ bonds.
Solution
Each bond contributes three Pauli strings with coefficients
Every string is traceless, and distinct full-system Pauli strings are orthogonal. Therefore only identical-string squares survive:
6. Check the Luttinger limits
Section titled “6. Check the Luttinger limits”Evaluate and at , and take their limits as and .
Solution
With ,
At , , so
As , and , giving
As , , so
The last limit signals the singular ferromagnetic endpoint rather than an ordinary finite-velocity conformal point.
References
Section titled “References”- H. Bethe, “Zur Theorie der Metalle. I. Eigenwerte und Eigenfunktionen der linearen Atomkette,” Zeitschrift für Physik 71, 205–226 (1931), doi:10.1007/BF01341708.
- F. Franchini, An Introduction to Integrable Techniques for One-Dimensional Quantum Systems, Springer (2017), doi:10.1007/978-3-319-48487-7.
- M. Gaudin, The Bethe Wavefunction, translated by J.-S. Caux, Cambridge University Press (2014), doi:10.1017/CBO9781107053885.
- T. Giamarchi, Quantum Physics in One Dimension, Oxford University Press (2004), doi:10.1093/acprof:oso/9780198525004.001.0001.
- F. D. M. Haldane, “‘Luttinger liquid theory’ of one-dimensional quantum fluids. I,” Journal of Physics C 14, 2585–2609 (1981), doi:10.1088/0022-3719/14/19/010.
- A. Luther and I. Peschel, “Calculation of critical exponents in two dimensions from quantum field theory in one dimension,” Physical Review B 12, 3908–3917 (1975), doi:10.1103/PhysRevB.12.3908.
- R. Orbach, “Linear antiferromagnetic chain with anisotropic coupling,” Physical Review 112, 309–316 (1958), doi:10.1103/PhysRev.112.309.
- M. Takahashi, Thermodynamics of One-Dimensional Solvable Models, Cambridge University Press (1999), doi:10.1017/CBO9780511524332.
- C. N. Yang and C. P. Yang, “One-dimensional chain of anisotropic spin-spin interactions. I. Proof of Bethe’s hypothesis for ground state in a finite system,” Physical Review 150, 321–327 (1966), doi:10.1103/PhysRev.150.321.
- C. N. Yang and C. P. Yang, “One-dimensional chain of anisotropic spin-spin interactions. II. Properties of the ground-state energy per lattice site for an infinite system,” Physical Review 150, 327–339 (1966), doi:10.1103/PhysRev.150.327.
- C. N. Yang and C. P. Yang, “One-dimensional chain of anisotropic spin-spin interactions. III. Applications,” Physical Review 151, 258–264 (1966), doi:10.1103/PhysRev.151.258.