Fermi Momentum and Fermi Energy
The Fermi momentum is the momentum at the boundary of the filled zero-temperature states of a uniform ideal Fermi gas. The Fermi energy is the one-particle energy at that boundary:
For a nonrelativistic particle of mass ,
These quantities are not independent thermodynamic parameters. Once the spatial dimension, number density, internal degeneracy, and dispersion are specified, state counting fixes and hence every other Fermi scale.
The most common source of wrong factors is a silent change between:
- total density, summed over all internal components;
- density per spin or hyperfine component;
- spinless or fully polarized conventions;
- continuum momentum and crystal momentum;
- kinetic energy and total relativistic energy.
The formulas below keep those conventions explicit. The ideal Fermi gas develops the thermodynamic model; degenerate Fermi gases explains the low-temperature physics.
Helpful background. Pauli exclusion explains the filling rule; plane-wave normalization explains the reciprocal-space state density.
The Fermi boundary and energy convention
Section titled “The Fermi boundary and energy convention”Unless stated otherwise, assume:
- a uniform continuum system in spatial dimensions;
- a large periodic box of -dimensional measure ;
- particles and total density ;
- degenerate internal modes at every wave vector;
- an isotropic, monotonically increasing dispersion ;
- zero temperature when defining the occupied Fermi region;
- one fermion at most in each complete one-particle mode.
Internal modes may be spin, hyperfine, or flavor states sharing the same dispersion and Fermi boundary. Equivalent valleys can also supply a multiplicity when each identical pocket is counted once using momentum relative to its own minimum; they are generally centered at different crystal momenta. Unequal populations or inequivalent dispersions require separate counts.
This page writes the Fermi energy as . Many texts and neighboring pages write for the same quantity. The notation does not imply a different physical definition:
For the nonrelativistic formulas, the energy zero is the bottom of the band or free-particle spectrum. The physical degeneracy scale is the energy above that bottom. If an offset is retained in , use for the Fermi temperature and the corresponding energy difference for a microscopic Fermi time. At finite temperature, this scale remains defined from zero-temperature filling. It is generally not equal to the temperature-dependent chemical potential .
Formula sheet
Section titled “Formula sheet”For a quadratic dispersion,
the standard formulas are:
| Dimension | Total density | Fermi wave number |
|---|---|---|
| 1D | ||
| 2D | ||
| 3D |
The corresponding Fermi energies are:
| Dimension | Fermi energy |
|---|---|
| 1D | |
| 2D | |
| 3D |
For a balanced spin- gas, and is the total density:
For a spinless or fully polarized gas, set .
The 1D Fermi boundary consists of the two points ; in 2D it is a circle; in 3D it is a sphere. These formulas require monotone isotropic filling from the minimum. The corresponding densities have units of inverse length, inverse area, and inverse volume, respectively. The geometric derivation below explains all three coefficients at once.
Geometric origin of the formulas
Section titled “Geometric origin of the formulas”Periodic boundary conditions quantize each wave-vector component in steps of . One allowed point per internal mode therefore occupies -dimensional wave-vector volume
Equivalently, the number of wave-vector states per internal mode in an element is
Let denote the volume of the unit ball in Euclidean dimensions:
The ball of radius has volume . Including internal modes, the continuum approximation to the integrated state count is
At , the ground state fills the lowest one-particle modes. For a monotone isotropic dispersion, this occupied region is the ball , so
Dividing by gives the master relation
Solving for the Fermi wave number,
The numerical coefficients in 1D, 2D, and 3D are therefore geometric coefficients, not additional dynamical assumptions.
For an isotropic monotone dispersion, the zero-temperature occupied region is the -ball . Its geometric measure is in 1D, in 2D, and in 3D. Multiplication by converts that measure into a state count.
Internal degeneracy conventions
Section titled “Internal degeneracy conventions”The degeneracy factor counts independent one-particle modes at the same . It is part of the state count, not a correction applied after the count.
Spin degeneracy
Section titled “Spin degeneracy”If spin is conserved and all spin projections are degenerate and equally populated, then
Examples include:
- spinless fermions or a fully polarized sample: ;
- balanced spin- fermions: ;
- an idealized balanced spin- multiplet: .
This formula does not say that every spin multiplet is physically populated. Zeeman splitting, spin–orbit coupling, preparation constraints, interactions, or selection rules may remove the degeneracy.
Several independent degeneracies
Section titled “Several independent degeneracies”If spin, valley, and another internal label are all independent and exactly degenerate, their multiplicities multiply:
One must not multiply by a label that is already counted as a separate band or included explicitly in the sum over states.
Total density and component density
Section titled “Total density and component density”Suppose components are balanced, each with density . Then
The per-component state count contains no additional degeneracy factor:
Substituting recovers the total-density formula.
Imbalanced components
Section titled “Imbalanced components”If components have unequal densities, there is generally no single common Fermi wave number. Each component has
For two spin components in three dimensions,
Writing one formula for an imbalanced gas hides the two distinct Fermi surfaces.
Fixed-density polarization effect
Section titled “Fixed-density polarization effect”At fixed total density,
and, for a quadratic dispersion,
Reducing the number of available internal components forces particles to occupy a larger region of momentum space. In three dimensions, fully polarizing a previously balanced spin- ideal gas changes the scales by
and
Derived Fermi scales
Section titled “Derived Fermi scales”Once is known, several useful scales follow.
Fermi momentum
Section titled “Fermi momentum”Wave number and momentum differ by :
Thus has units of inverse length, while has units of momentum. The phrase Fermi momentum is often used informally for either quantity; a careful formula should display which one is meant.
Fermi velocity
Section titled “Fermi velocity”For a general isotropic dispersion, the group velocity at the Fermi boundary is
For a quadratic dispersion,
Fermi temperature
Section titled “Fermi temperature”The Fermi temperature is the energy scale expressed in kelvin:
It is not the temperature of the zero-temperature gas. It defines the reduced temperature
which distinguishes the degenerate regime from the classical regime under the appropriate density conditions.
Fermi wavelength and inverse Fermi scale
Section titled “Fermi wavelength and inverse Fermi scale”The de Broglie wavelength associated with is
Many-body estimates also use the shorter length . These differ by and should not be interchanged silently.
Fermi time
Section titled “Fermi time”A natural microscopic time is
For a quadratic dispersion,
This is a scale, not automatically a collision time or equilibration time.
Inverse formulas
Section titled “Inverse formulas”If the nonrelativistic Fermi energy is known, then
The corresponding density in dimensions is
Explicitly,
The densities have different dimensions: inverse length in 1D, inverse area in 2D, and inverse volume in 3D.
Density-of-states checks
Section titled “Density-of-states checks”The integrated number of states below energy for a quadratic dispersion is
Differentiation gives the density of states per -dimensional measure:
At the Fermi energy,
This identity is a fast consistency check. It uses a density of states that includes the same internal factor as the density .
The energy dependence is
Thus the free-particle density of states diverges as in 1D, is constant in 2D, and grows as in 3D. The general density-of-states normalization is explained in Density of States: First Encounter.
Zero-temperature consistency identities
Section titled “Zero-temperature consistency identities”For a quadratic dispersion, integrating all occupied energies gives
Scale invariance of the nonrelativistic kinetic energy gives
In one dimension, is a force; in two dimensions, it is force per length; in three dimensions, it is the usual force per area. These identities are useful checks, but the full equation-of-state derivation belongs to the Ideal Fermi Gas page.
Worked example: a three-dimensional electron density
Section titled “Worked example: a three-dimensional electron density”Consider nonrelativistic electrons with total density
and spin degeneracy . Then
The momentum scale is
Using the electron mass,
Consequently,
and
An ordinary laboratory temperature can therefore be much smaller than even when it is hundreds of kelvin. This is why conduction electrons are often strongly degenerate. A real metal may require band-dependent effective masses and a nonspherical Fermi surface, so the numerical calculation is an ideal free-electron estimate rather than a complete material model.
Worked example: a two-dimensional electron gas
Section titled “Worked example: a two-dimensional electron gas”Take a two-dimensional spin-degenerate gas with sheet density
, and effective mass . The Fermi wave number is
The quadratic-band Fermi energy is
Equivalently,
The use of rather than the bare electron mass is part of the model specification. Valley degeneracy, spin splitting, or nonparabolicity would modify the count or the dispersion.
What survives for another dispersion
Section titled “What survives for another dispersion”The state-counting relation for depends on the occupied -space volume, not on the detailed energy dispersion. For a continuum dispersion, or an isotropic pocket counted within its domain of validity, the same density relation holds:
Only the map from to energy and velocity changes:
and
For a power-law dispersion
one obtains
and
The familiar factor is the special case .
Relativistic convention
Section titled “Relativistic convention”Relativistic state counting gives the same for a specified density and degeneracy. What changes is the energy relation. With
the total one-particle energy at the Fermi boundary is
If Fermi energy means kinetic energy measured from the rest energy, then
At zero temperature, a relativistic chemical potential that includes rest energy is
whereas a convention that subtracts rest energy gives
Both conventions are legitimate; mixing them in one calculation is not. The nonrelativistic approximation requires
Bands, lattices, and anisotropy
Section titled “Bands, lattices, and anisotropy”The scalar is exact for a spherical Fermi boundary. In a crystal band, the occupied region is determined by
inside the Brillouin zone. The boundary can be warped, disconnected, open across a zone boundary, or split among bands. Then one should speak of:
- the Fermi surface ;
- direction-dependent Fermi wave vectors;
- extremal radii or orbit areas;
- an effective spherical only when explicitly defined.
For an anisotropic quadratic band,
constant-energy surfaces are ellipsoids with semiaxes . Their volume gives
The density-of-states mass reproduces this total count in the spherical formula. It does not reproduce the directional Fermi radii or velocities; those still need the individual masses.
Fermi Surface develops the general many-body concept and low-energy excitations near nonspherical boundaries. The linked band-structure discussions explain Bloch-band topology and material-specific surfaces.
Traps and inhomogeneous gases
Section titled “Traps and inhomogeneous gases”A finite trap does not have translational invariance, so momentum states are not labeled by a uniform continuum density. Exact state counting uses trap eigenlevels.
In a slowly varying potential, a local-density approximation may define
with a local Fermi energy
These are local scales. They need not equal the global Fermi energy defined by the highest occupied trap level. Quantum gases in traps derives the trap conventions and local-density approximation.
Finite systems and shell filling
Section titled “Finite systems and shell filling”In a finite box, allowed momenta are discrete. The continuum formula replaces a lattice-point count by a geometric volume, so it becomes accurate when many modes are occupied and boundary corrections are small.
For a finite noninteracting system, several quantities may be called the Fermi energy:
- the highest occupied one-particle energy;
- the lowest unoccupied one-particle energy;
- the midpoint between them;
- an addition or removal chemical potential;
- the continuum estimate from the mean density.
For the gapless continuum gas, these differences vanish in the ordinary thermodynamic limit, but can be a shell spacing in a small system. A band insulator with a persistent gap does not have the same coincidence. A partially filled degenerate shell also makes the zero-temperature boundary less sharp than the continuum picture suggests.
Exercises
Section titled “Exercises”Translate between total and component density
Section titled “Translate between total and component density”A balanced two-component gas in two dimensions has total sheet density . Compute first from the total-density formula with , then from the density of one component. Verify agreement.
Solution
Using total density and ,
For one component, no extra degeneracy factor is included:
Since ,
Both expressions count each spin component once and therefore agree.
Derive the density-of-states check
Section titled “Derive the density-of-states check”Starting from for a quadratic dispersion, show that
Solution
Write
where contains the mass, degeneracy, and geometric factors. Differentiation gives
At ,
Eliminating yields
Obtain the mean ground-state energy
Section titled “Obtain the mean ground-state energy”Use to prove
Check the results in 1D, 2D, and 3D.
Solution
The particle number and energy are proportional to
and
Taking the ratio gives
Thus
Separate relativistic energy conventions
Section titled “Separate relativistic energy conventions”Show that the relativistic kinetic Fermi energy approaches when , and approaches when .
Solution
The kinetic Fermi energy is
For ,
so
For ,
and therefore
The leading density-dependent term is . The subtractive rest-energy constant remains because the kinetic-energy convention measures from .
An ellipsoidal Fermi sea
Section titled “An ellipsoidal Fermi sea”At fixed total density and degeneracy, compare the quadratic band with masses to the isotropic band with mass . Find the energy ratio, the three radius ratios, and the velocity ratios.
Solution
The density-of-states mass is , so . Since each radius is proportional to , the ratios are . Their product is one, as fixed occupied volume requires. The velocities are , so their ratios are . One scalar mass preserves the state count but not these directional properties.
References
Section titled “References”- N. W. Ashcroft and N. D. Mermin, Solid State Physics, Holt, Rinehart and Winston (1976) — free-electron and band-theory Fermi scales.
- A. L. Fetter and J. D. Walecka, Quantum Theory of Many-Particle Systems, Dover (2003) — Fermi momentum, density of states, and many-body conventions.
- S. Giorgini, L. P. Pitaevskii, and S. Stringari, “Theory of ultracold atomic Fermi gases,” Reviews of Modern Physics 80, 1215–1274 (2008) — balanced and imbalanced atomic-gas conventions.
- G. F. Giuliani and G. Vignale, Quantum Theory of the Electron Liquid, Cambridge University Press (2005) — electron-gas conventions in two and three dimensions.
- X.-W. Guan, M. T. Batchelor, and C. Lee, “Fermi gases in one dimension: From Bethe ansatz to experiments,” Reviews of Modern Physics 85, 1633–1691 (2013) — one-dimensional Fermi scales and component conventions.
- K. Huang, Statistical Mechanics, 2nd ed., Wiley (1987) — ideal Fermi-gas thermodynamics and dimensional state counting.
- M. Kardar, Statistical Physics of Particles, Cambridge University Press (2007) — phase-space counting and quantum statistics.
- R. K. Pathria and P. D. Beale, Statistical Mechanics, 3rd ed., Elsevier (2011) — continuum state counting and ideal quantum gases.