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Prethermalization is a two-stage relaxation process in which a many-body system rapidly approaches a long-lived intermediate regime and only much later escapes toward its true asymptotic behavior. The intermediate regime is organized by a reference Hamiltonian, a dressed effective Hamiltonian, or one or more approximately conserved quantities.

Its defining structure is a separation of clocks:

τfast≪t≪τ∗,⟨O(t)⟩≃⟨O⟩pre,O∈Alocal,Q~(t)≃Q~(0)until t approaches τ∗.\begin{gathered} \tau_{\mathrm{fast}} \ll t \ll \tau_*, \\ \langle O(t)\rangle \simeq \langle O\rangle_{\mathrm{pre}}, \\ O\in\mathcal A_{\mathrm{local}}, \\ \widetilde Q(t) \simeq \widetilde Q(0) \quad \text{until }t\text{ approaches }\tau_*. \end{gathered}

Here τfast\tau_{\mathrm{fast}} is the initial dephasing or constrained-relaxation time, while τ∗\tau_* is the leakage, heating, or escape time. A flat curve alone is not enough. A defensible prethermal claim identifies the structure suppressing the slow process, shows that the two timescales separate as a control parameter is tuned, and states what is expected after the plateau.

Prethermalization is not one universal phase or one universal ensemble. Weak integrability breaking, a large static energy separation, high-frequency driving, dilute quasiparticle collisions, and metastable sectors can all produce intermediate regimes, but their lifetime laws and effective descriptions need not agree.

Helpful background. Thermalization distinguishes equilibration from a thermal prediction; conserved quantities supplies the commutator criterion used below. For periodically driven examples, high-frequency expansions explains the effective Hamiltonian and its truncation.

Prethermalization is normally a statement about local observables, correlation functions, reduced states, or coarse thermodynamic quantities. It is not convergence of the exact global wavefunction.

Let A\mathcal A be a declared set of probes and let ρpre\rho_{\mathrm{pre}} be a candidate intermediate description. Define

δA(t)=sup⁡O∈A∥O∥≤1∣Tr⁡ ⁣[ρ(t)O]−Tr⁡ ⁣[ρpreO]∣.\delta_{\mathcal A}(t) = \sup_{\substack{O\in\mathcal A\\ \|O\|\le 1}} \left| \operatorname{Tr}\!\left[\rho(t)O\right] - \operatorname{Tr}\!\left[\rho_{\mathrm{pre}}O\right] \right|.

A prethermal window [t1,t2][t_1,t_2] requires δA(t)\delta_{\mathcal A}(t) to remain small throughout that window, with

τfast≲t1<t2≲τ∗.\tau_{\mathrm{fast}} \lesssim t_1 < t_2 \lesssim \tau_*.

The choice of A\mathcal A matters. Local densities may look stationary while long-range correlations, rare operators, or the full state continue changing.

An observation time tobst_{\mathrm{obs}} can resolve a prethermal regime only if

tobs≫τfast,tobs≪τ∗.\begin{aligned} t_{\mathrm{obs}} &\gg \tau_{\mathrm{fast}}, \\ t_{\mathrm{obs}} &\ll \tau_*. \end{aligned}

The first inequality shows that the initial transient has ended. The second shows that the slow escape has not yet erased the approximate constraint. If an experiment covers only one side, it may reveal relaxation or longevity, but not the full two-stage structure.

A perfectly flat plateau is not required. Often the state moves slowly along a manifold of constrained equilibria. For an observable OO, define a local logarithmic drift rate

rO(t)=∣d⟨O(t)⟩dln⁡t∣.r_O(t) = \left| \frac{d\langle O(t)\rangle}{d\ln t} \right|.

One may call a window prethermal when rOr_O is parametrically smaller than its value during the initial transient and when the residual drift is explained by leakage of an approximate charge. The threshold must be reported; visual flatness is not a quantitative definition.

At fixed nonzero perturbation, a generic finite-range nonintegrable system is often expected eventually to leave the prethermal manifold. The endpoint might be:

  • a Gibbs state fixed only by exact conserved quantities;
  • a generalized state if exact integrability survives;
  • an infinite-temperature-like state within exact symmetry sectors under generic periodic driving;
  • a bath-controlled steady state in an open system;
  • another long-lived regime if several hierarchical scales are present.

Not observing escape establishes a lower bound on τ∗\tau_*, not an infinite lifetime.

Observation Possible interpretation What else must be tested
local observable becomes nearly constant dephasing, prethermalization, finite-size saturation, or exact stationarity a mechanism and an escape scale
approximate charge changes slowly prethermal constraint local-state relaxation within its sector
rapid approach to a GGE-like value near-integrable prethermalization later drift under integrability breaking
slow energy absorption under a drive Floquet prethermal protection equilibration under the effective Hamiltonian
persistent local memory localization, exact conservation, fragmentation, or a long plateau transport, perturbation, size, and time scaling
long-lived order metastability or a prethermal phase robustness, nucleation or heating mechanism, and lifetime scaling

The word prethermal is justified by a hierarchy, not by nonthermal appearance alone.

Write the exact Hamiltonian as

H=H0+gV,∣g∣≪g0,H = H_0 + gV, \qquad |g|\ll g_0,

where H0H_0 is a useful reference Hamiltonian with local energy scale g0g_0. Take gg to have energy units and the local terms of VV to be dimensionless and of order one. The reference need not be integrable. Suppose H0H_0 has one or more charges QaQ_a satisfying

[H0,Qa]=0,[H_0,Q_a]=0,

while the perturbation breaks them:

[V,Qa]≠0.[V,Q_a]\neq0.

Under the full Hamiltonian,

dQa(t)dt=igℏ[V(t),Qa(t)].\frac{dQ_a(t)}{dt} = \frac{i g}{\hbar} [V(t),Q_a(t)].

This equation identifies the small parameter, but it does not by itself determine the lifetime. The expectation of the commutator may oscillate and average to zero at first order; resonances or coherent secular terms may instead make it accumulate.

For a bounded operator,

∣⟨Qa(t)⟩−⟨Qa(0)⟩∣≤∣g∣ℏ∫0tds×∥[V(s),Qa(s)]∥.\left| \langle Q_a(t)\rangle - \langle Q_a(0)\rangle \right| \le \frac{|g|}{\hbar} \int_0^t ds \times \left\| [V(s),Q_a(s)] \right\|.

If the norm is of order one, this only guarantees a time of order ∣g∣−1|g|^{-1}. For extensive operators, the global norm grows with volume and is usually the wrong thermodynamic measure. Local densities, commutators per site, or local interaction norms are the relevant quantities.

The bare QaQ_a is often not the longest-lived object. A quasilocal change of basis can construct

Q~a=e−SQaeS,\widetilde Q_a = e^{-S}Q_a e^S,

with S†=−SS^\dagger=-S and

Q~a=Qa+gQa(1)+g2Qa(2)+⋯ .\widetilde Q_a = Q_a + gQ_a^{(1)} + g^2Q_a^{(2)} + \cdots.

Choosing SS order by order can cancel charge-changing terms through some order nn:

[H,Q~a(n)]=O ⁣(gn+1).[H,\widetilde Q_a^{(n)}] = O\!\left(g^{n+1}\right).

For a dimensionless charge density and a residual commutator bounded by Cg0(∣g∣/g0)n+1C g_0(|g|/g_0)^{n+1}, integration guarantees small drift at fixed tolerance for times of order

tguaranteed(n)∼ℏg0(g0∣g∣)n+1,t_{\mathrm{guaranteed}}^{(n)} \sim \frac{\hbar}{g_0} \left( \frac{g_0}{|g|} \right)^{n+1},

with a tolerance-dependent prefactor. This is a lower bound on protection, not a prediction that decay occurs at that time. Resonances may obstruct the construction itself. An asymptotic series has an optimal truncation order rather than a convergent infinite construction.

Approximate conservation does not itself create a plateau. The reference dynamics must also mix or dephase the chosen probes rapidly while the charges remain nearly fixed.

Let

qa(t)=1L⟨Qa(t)⟩.q_a(t) = \frac{1}{L} \langle Q_a(t)\rangle.

If H0H_0 equilibrates locally at fixed qaq_a, a moving constrained ensemble can be written

ρpre(q)=1Z(q)exp⁡ ⁣[Ξ(q)],Ξ(q)=−β(q)H0−∑aλa(q)Qa.\begin{aligned} \rho_{\mathrm{pre}}(q) &= \frac{1}{Z(q)} \exp\!\left[\Xi(q)\right], \\ \Xi(q) &= -\beta(q)H_0 -\sum_a\lambda_a(q)Q_a. \end{aligned}

The parameters are chosen to reproduce the instantaneous slowly varying densities. The exact state remains pure if it began pure; the ensemble compresses local information.

When first-order secular contributions vanish and the reference dynamics loses memory rapidly enough, second-order perturbation theory often gives

dqadt=g2Fa(q)+O(g3).\frac{dq_a}{dt} = g^2F_a(q) + O(g^3).

The resulting drift time is

τ∗∼1g2\tau_* \sim \frac{1}{g^2}

in suitable microscopic units. This is the logic behind many quantum Boltzmann equations and the general reference-dynamics framework.

The exponent 22 is not universal. It can change when:

  • a first-order resonance is allowed;
  • symmetry forbids the leading transition;
  • several particles must cooperate to change the charge;
  • the density of final states vanishes or diverges;
  • long-time correlations invalidate a Markov approximation;
  • the initial state lies near a singular point;
  • the perturbation is not small in the relevant local norm.

One should therefore report a measured or derived scaling, not insert g−2g^{-2} by reflex.

For

H=Hint+gV,H = H_{\mathrm{int}} + gV,

an integrable reference Hamiltonian carries charges QrQ_r with

[Hint,Qr]=0.[H_{\mathrm{int}},Q_r]=0.

Under the perturbed model,

dQrdt=igℏ[V,Qr].\frac{dQ_r}{dt} = \frac{i g}{\hbar} [V,Q_r].

The system can first dephase under HintH_{\mathrm{int}}, producing local values close to a GGE fixed by the initial charge densities. Weak integrability breaking then causes those densities to drift, eventually leaving the GGE manifold or moving along it toward an ordinary thermal state.

The appropriate schematic sequence is

ρ0⇓t∼τdephρGGE[qr(0)]⇓t∼τbreakρGibbsor another exact-constraint ensemble.\begin{gathered} \rho_0 \\ \Downarrow\quad t\sim\tau_{\mathrm{deph}} \\ \rho_{\mathrm{GGE}}[q_r(0)] \\ \Downarrow\quad t\sim\tau_{\mathrm{break}} \\ \rho_{\mathrm{Gibbs}} \\ \text{or another exact-constraint ensemble}. \end{gathered}

Integrability and Generalized Gibbs Ensembles Preview explains construction and completeness of the GGE. Here the key point is that its charges are only approximate under the full Hamiltonian.

A transparent example begins from

H0=∑kεknk,nk=ck†ck.H_0 = \sum_k \varepsilon_k n_k, \qquad n_k = c_k^\dagger c_k.

The mode occupations are exactly conserved by H0H_0. Add a weak two-body interaction gVgV. Coherent dephasing and dressing can occur on a relatively short time, while redistribution of occupations requires collisions.

A schematic fermionic collision integral is

n˙1=2πg2ℏ∑2,3,4∣M12;34∣2δkδεF12;34,δk=δk1+k2, k3+k4,δε=δ(ε1+ε2−ε3−ε4),F12;34=(1−n1)(1−n2)n3n4−n1n2(1−n3)(1−n4).\begin{aligned} \dot n_1 &= \frac{2\pi g^2}{\hbar} \sum_{2,3,4} |M_{12;34}|^2 \delta_{\mathbf k} \delta_\varepsilon \mathcal F_{12;34}, \\ \delta_{\mathbf k} &= \delta_{\mathbf k_1+\mathbf k_2,\, \mathbf k_3+\mathbf k_4}, \\ \delta_\varepsilon &= \delta( \varepsilon_1+\varepsilon_2 -\varepsilon_3-\varepsilon_4 ), \\ \mathcal F_{12;34} &= (1-n_1)(1-n_2)n_3n_4 - n_1n_2(1-n_3)(1-n_4). \end{aligned}

The two delta functions impose crystal momentum (modulo a reciprocal lattice vector) and reference-quasiparticle energy conservation. Matrix-element and pair-counting conventions are absorbed into this schematic collision kernel. The prefactor displays the common g2g^2 collision scale. On a finite lattice the energy delta function is resolved into discrete levels, so broadening, time windows, and system size must be handled consistently.

Exact integrability is not prethermalization

Section titled “Exact integrability is not prethermalization”

If g=0g=0 exactly and the GGE is stationary forever, the system is integrable rather than prethermal with respect to that charge hierarchy. Prethermalization describes the singular crossover as gg becomes small but nonzero.

The order of limits exposes the distinction:

lim⁡g→0lim⁡t→∞⟨O(t)⟩≠lim⁡t→∞lim⁡g→0⟨O(t)⟩\lim_{g\to0} \lim_{t\to\infty} \langle O(t)\rangle \neq \lim_{t\to\infty} \lim_{g\to0} \langle O(t)\rangle

whenever the perturbed and integrable endpoints differ.

Consider a local Hamiltonian

H=ΔN+D+V,H = \Delta N + D + V,

where:

[D,N]=0,∥D∥loc,∥V∥loc≲J,J≪Δ.\begin{gathered} [D,N]=0, \\ \|D\|_{\mathrm{loc}},\|V\|_{\mathrm{loc}} \lesssim J, \\ J \ll \Delta. \end{gathered}

Assume NN is a sum of bounded, mutually commuting local counting terms with an integer-spaced spectrum, together with the locality hypotheses of the chosen theorem. A single local change of NN then costs the large energy scale Δ\Delta before perturbative corrections. Merely spacing the spectrum of an arbitrary nonlocal operator is not enough. A quasilocal unitary YY can bring the Hamiltonian to a normal form

YHY†=ΔN+D∗+E∗,YHY^\dagger = \Delta N + D_* + E_*,

with

[D∗,N]=0,∥E∗∥loc≪J.[D_*,N]=0, \qquad \|E_*\|_{\mathrm{loc}} \ll J.

The dressed quantity

N~=Y†NY\widetilde N = Y^\dagger N Y

is then almost conserved by the original Hamiltonian. Under theorem-specific locality, boundedness, and spectral assumptions, E∗E_* can be nonperturbatively small and the lifetime nearly exponential or stretched exponential in Δ/J\Delta/J.

It is safer to write the generic message as

τ∗≫ℏJ\tau_* \gg \frac{\hbar}{J}

and then state the precise bound for the model at hand.

For the Fermi–Hubbard model,

H=UNd+T,Nd=∑ini↑ni↓,H = U N_d + T, \qquad N_d = \sum_i n_{i\uparrow}n_{i\downarrow},

where NdN_d counts doublons and TT is hopping. Decompose

T=T+1+T0+T−1,T = T_{+1} + T_0 + T_{-1},

so that

[Nd,Tm]=mTm.[N_d,T_m] = mT_m.

For ∣U∣≫J|U|\gg J, take the leading anti-Hermitian generator

S1=T+1−T−1U.S_1 = \frac{T_{+1}-T_{-1}}{U}.

Because

[S1,UNd]=−T+1−T−1,[S_1,UN_d] = -T_{+1} -T_{-1},

the transformed Hamiltonian has no doublon-changing term at first order:

eS1He−S1=UNd+T0+O ⁣(J2U).e^{S_1}He^{-S_1} = UN_d + T_0 + O\!\left(\frac{J^2}{U}\right).

The leading effective Hamiltonian conserves the transformed counting operator. In the original frame, the dressed operator N~d=e−S1NdeS1\widetilde N_d=e^{-S_1}N_de^{S_1} is better conserved; the bare NdN_d can have small rapid oscillations from virtual hopping even when the dressed value barely drifts. A quench can relax rapidly within a fixed-doublon sector and only later change the doublon density.

This derivation is a scale-separation statement. It does not say that every large-UU state is thermal within its sector, nor that doublons never decay.

Yin and Lucas (2023) extend the principle beyond an exactly integer counting operator. For a spatially local gapped Hamiltonian H0H_0 perturbed by local terms of strength ϵ≪Δ\epsilon\ll\Delta, local correlation functions for initial states in the protected low-energy subspace can remain close to its effective dynamics for stretched-exponential times under the theorem’s hypotheses.

This result is about local robustness over a long finite time. It is not a blanket claim that the perturbed Hamiltonian remains gapped or that every initial state is protected.

Let

H(t+T)=H(t),Ω=2πT,H(t+T) = H(t), \qquad \Omega = \frac{2\pi}{T},

with one-period propagator

UF=Texp⁡ ⁣[−iℏ∫0TH(t) dt].U_F = \mathcal T \exp\!\left[ -\frac{i}{\hbar} \int_0^T H(t)\,dt \right].

The exact Floquet operator always exists for a well-defined finite problem. The prethermal question is different: can local dynamics for many periods be approximated by a quasilocal static generator?

For an interacting lattice, the global norm ∥H∥\|H\| grows with volume. The thermodynamic control parameter uses a local interaction scale glocg_{\mathrm{loc}}:

η=glocℏΩ.\eta = \frac{g_{\mathrm{loc}}}{\hbar\Omega}.

When η≪1\eta\ll1 and appropriate locality and bounded-local-Hilbert-space assumptions hold, a periodic dressing P(t)P(t) and a quasilocal effective Hamiltonian H∗H_* give the effective evolution

U(t)≃P(t)exp⁡ ⁣(−iℏH∗t)P†(0)U(t) \simeq P(t) \exp\!\left( -\frac{i}{\hbar}H_*t \right) P^\dagger(0)

through a long interval when tested on fixed-support local observables, with a theorem-specific error bound. The notation does not assert a volume-independent global operator-norm approximation to U(t)U(t). At stroboscopic times, P(nT)=P(0)P(nT)=P(0).

The residual terms that absorb drive quanta are small after optimal truncation. A common schematic estimate is

Γheat≲glocℏexp⁡ ⁣[−cℏΩgloc],\Gamma_{\mathrm{heat}} \lesssim \frac{g_{\mathrm{loc}}}{\hbar} \exp\!\left[ -c \frac{\hbar\Omega}{g_{\mathrm{loc}}} \right],

leading to

τ∗≳ℏglocexp⁡ ⁣[cℏΩgloc].\tau_* \gtrsim \frac{\hbar}{g_{\mathrm{loc}}} \exp\!\left[ c \frac{\hbar\Omega}{g_{\mathrm{loc}}} \right].

Constants, powers, logarithmic corrections, interaction range, smoothness, and precise hypotheses depend on the theorem and model. One rigorous local-spin construction gives a quasi-exponential scale of the form

τ∗≳Ω0−1exp⁡ ⁣[cΩ/Ω0log⁡3(Ω/Ω0)]\tau_* \gtrsim \Omega_0^{-1}\exp\!\left[ c \frac{\Omega/\Omega_0} {\log^3(\Omega/\Omega_0)} \right]

at large Ω/Ω0\Omega/\Omega_0, with Ω0\Omega_0 a local microscopic frequency and theorem-dependent constants. Other finite-range bounds and physical estimates yield exponential-in-frequency behavior. These statements should not be merged into one universal formula.

High-Frequency Expansions derives the expansion and specifies its conventions.

There are two logically separate claims:

heating under the exact drive is slow,local dynamics under H∗ equilibrates.\begin{gathered} \text{heating under the exact drive is slow}, \\ \text{local dynamics under }H_*\text{ equilibrates}. \end{gathered}

If H∗H_* is nonintegrable and satisfies ETH in the relevant energy window, a prethermal Gibbs state is plausible:

ρpre=exp⁡(−β∗H∗)Tr⁡exp⁡(−β∗H∗).\rho_{\mathrm{pre}} = \frac{ \exp(-\beta_*H_*) }{ \operatorname{Tr}\exp(-\beta_*H_*) }.

The inverse temperature β∗\beta_* is fixed approximately by the expectation of H∗H_* in the dressed initial state ρ∗,0=P†(0)ρ0P(0)\rho_{*,0}=P^\dagger(0)\rho_0P(0), provided the effective energy distribution is sufficiently narrow for one local thermal prediction. If H∗H_* is integrable, constrained, fragmented, or localized over the tested window, its local endpoint need not be Gibbs.

For a fixed laboratory observable OO, its representative in the effective frame is

O∗(t)=P†(t)OP(t).O_*(t) = P^\dagger(t)OP(t).

The expectation is computed as Tr⁡[e−iH∗t/ℏρ∗,0eiH∗t/ℏO∗(t)]\operatorname{Tr}[e^{-iH_*t/\hbar}\rho_{*,0}e^{iH_*t/\hbar}O_*(t)] within the effective approximation. A stroboscopic plateau can coexist with substantial intracycle motion. Comparisons must specify whether data are sampled at fixed phase, cycle averaged, or measured continuously.

Some driven systems possess an additional approximate symmetry or charge even when the state is effectively at high temperature with respect to H∗H_*. Long-lived oscillations or constrained dynamics can then survive without a useful finite prethermal temperature.

This broadens the concept beyond Gibbs plateaus, but the physical test remains the same: identify the approximate conserved structure, show its parametric lifetime, and exclude trivial finite-size or calibration effects.

If only the effective energy and exact symmetries constrain a locally ergodic H∗H_*, use

ρpre=1Z∗exp⁡ ⁣(−β∗H∗−∑αμαCα),\rho_{\mathrm{pre}} = \frac{1}{Z_*} \exp\!\left( -\beta_*H_* -\sum_\alpha\mu_\alpha C_\alpha \right),

where CαC_\alpha are exact charges.

If several approximate charges remain fixed over the window,

ρpre=1Zpreexp⁡ ⁣(−∑aλaQ~a).\rho_{\mathrm{pre}} = \frac{1}{Z_{\mathrm{pre}}} \exp\!\left( -\sum_a\lambda_a\widetilde Q_a \right).

The charges should be local or quasilocal enough to control the declared probes. Adding arbitrary projectors until a fit succeeds is not a predictive ensemble.

When charges drift measurably,

ρpre(t)=ρpre ⁣[q1(t),q2(t),…].\rho_{\mathrm{pre}}(t) = \rho_{\mathrm{pre}}\!\left[q_1(t),q_2(t),\ldots\right].

The state can remain close to a moving manifold even though no single stationary density operator fits the entire window.

An effective Hamiltonian can govern dynamics accurately while the initial state continues oscillating or fails to equilibrate under it. In that case, H∗H_* is still useful, but calling exp⁡(−β∗H∗)/Z∗\exp(-\beta_*H_*)/Z_* the observed prethermal state would be premature.

Exact unitary evolution preserves the global von Neumann entropy:

SvN[ρ(t)]=SvN[ρ(0)].S_{\mathrm{vN}}[\rho(t)] = S_{\mathrm{vN}}[\rho(0)].

Any entropy change must specify a subsystem or a coarse graining. Relevant quantities include:

  • growth of subsystem entanglement entropy;
  • diagonal entropy in a reference basis whose populations can change under the perturbation (it is constant in the exact static Hamiltonian eigenbasis);
  • coarse-grained entropy of the prethermal ensemble;
  • kinetic entropy associated with slowly evolving occupations.

For a small region AA,

ρA(t)=Tr⁡Aˉρ(t)≃ρA,pre\rho_A(t) = \operatorname{Tr}_{\bar A}\rho(t) \simeq \rho_{A,\mathrm{pre}}

can hold while the global state remains far from any mixed ensemble. The plateau entropy may differ from the final thermal entropy because approximate constraints reduce the locally accessible state space.

Useful clocks include

Symbol Meaning
τmicro\tau_{\mathrm{micro}} inverse local bandwidth or interaction time
τdeph\tau_{\mathrm{deph}} decay of coherent transients under the reference dynamics
τloc\tau_{\mathrm{loc}} local constrained equilibration
τtr(L)\tau_{\mathrm{tr}}(L) transport across system size LL
τ∗\tau_* approximate-charge leakage or drive-heating time
τbath\tau_{\mathrm{bath}} environment-induced relaxation time
τrec(L)\tau_{\mathrm{rec}}(L) finite-size recurrence time

A clean isolated-system prethermal window needs

max⁡(τdeph,τloc)≪t≪min⁡(τ∗,τbath,τrec).\max( \tau_{\mathrm{deph}}, \tau_{\mathrm{loc}} ) \ll t \ll \min( \tau_*, \tau_{\mathrm{bath}}, \tau_{\mathrm{rec}} ).

Transport can be slower than local equilibration, so a spatially inhomogeneous system may require an additional hydrodynamic stage.

For weak breaking,

lim⁡g→0lim⁡t→∞≠lim⁡t→∞lim⁡g→0\lim_{g\to0} \lim_{t\to\infty} \neq \lim_{t\to\infty} \lim_{g\to0}

as operations on local observables whenever exact and approximate constraints select different ensembles.

For a driven system,

lim⁡Ω→∞lim⁡t→∞≠lim⁡t→∞lim⁡Ω→∞.\lim_{\Omega\to\infty} \lim_{t\to\infty} \neq \lim_{t\to\infty} \lim_{\Omega\to\infty}.

Taking Ω→∞\Omega\to\infty first can freeze heating; taking t→∞t\to\infty first at fixed frequency can reveal eventual absorption.

A finite spectrum has a smallest resolved spacing and eventual recurrences. Apparent plateaus can arise when the expected collision width is below that spacing.

For a golden-rule process with rate Γ\Gamma and spacing δL\delta_L among accessible final levels coupled by that process, a continuum kinetic description requires schematically

δL≪ℏΓ≪g0.\delta_L \ll \hbar\Gamma \ll g_0.

If ℏΓ≲δL\hbar\Gamma\lesssim\delta_L, increasing time at fixed size does not reproduce the thermodynamic collision integral.

Bosonic lattices and continuum gases do not have a finite maximal local transition energy. A high-frequency or large-gap claim must state:

  • the populated energy and occupation window;
  • how matrix elements to remote states decay;
  • whether losses or three-body processes matter;
  • how the Hilbert-space cutoff is varied;
  • which resonances remain in the retained window.

An apparent plateau created by truncating away the escape channel is numerical, not physical.

Power-law interactions can modify locality bounds and permit collective processes. The relevant norm, system-size dependence, and exponent range must be stated. Short-range exponential-lifetime formulas cannot be transferred unchanged to every dipolar or all-to-all model.

For an extensive candidate Q~\widetilde Q, define

DQ(t)=∣⟨Q~(t)⟩−⟨Q~(0)⟩∣Lqref.D_Q(t) = \frac{ \left| \langle\widetilde Q(t)\rangle - \langle\widetilde Q(0)\rangle \right| }{ Lq_{\mathrm{ref}} }.

The reference scale qrefq_{\mathrm{ref}} should be declared. A prethermal interpretation predicts a parametrically small DQD_Q over the plateau and a drift correlated with its breakdown.

For a local observable OO,

ϵO(t)=∣⟨O(t)⟩H−⟨O(t)⟩H∗∣.\epsilon_O(t) = \left| \langle O(t)\rangle_H - \langle O(t)\rangle_{H_*} \right|.

Check ϵO(t)\epsilon_O(t) for several support sizes and observables. Agreement for one specially protected operator is weaker than agreement for a local algebra.

Given a candidate ρpre\rho_{\mathrm{pre}},

RO(t)=⟨O(t)⟩−Tr⁡(ρpreO).R_O(t) = \langle O(t)\rangle - \operatorname{Tr} \left( \rho_{\mathrm{pre}}O \right).

Report the time average and variance:

RO‾=1t2−t1∫t1t2RO(t) dt,\overline{R_O} = \frac{1}{t_2-t_1} \int_{t_1}^{t_2} R_O(t)\,dt, σO2=1t2−t1∫t1t2[RO(t)−RO‾]2dt.\sigma_O^2 = \frac{1}{t_2-t_1} \int_{t_1}^{t_2} \left[ R_O(t)-\overline{R_O} \right]^2dt.

Small variance with a large bias means the plateau is stable but the proposed ensemble is wrong.

Choose a threshold ϵ\epsilon before fitting:

τ∗(ϵ)=inf⁡{t>t1:DQ(t)≥ϵ}.\tau_*(\epsilon) = \inf \left\{ t>t_1: D_Q(t)\ge\epsilon \right\}.

Vary ϵ\epsilon to test robustness. A lifetime extracted after inspecting the curve is vulnerable to selection bias.

Measure τ∗\tau_* as the small parameter is tuned:

τ∗(g)∝∣g∣−α,\tau_*(g) \propto |g|^{-\alpha},

or

ln⁡τ∗(Ω)∝ℏΩgloc,\ln\tau_*(\Omega) \propto \frac{\hbar\Omega}{g_{\mathrm{loc}}},

where justified. A fit over less than a decade rarely discriminates a power law from an exponential reliably. Report alternative fits, covariance, and the accessible asymptotic range.

For periodic driving, track the effective energy density

e∗(n)=1L⟨H∗⟩nTe_*(n) = \frac{1}{L} \left\langle H_* \right\rangle_{nT}

and a simple infinite-temperature benchmark

e∞=Tr⁡SH∗dim⁡S,e_{\infty} = \frac{ \operatorname{Tr}_{\mathcal S}H_* }{ \dim\mathcal S },

where S\mathcal S is the exact symmetry sector. Energy absorption, entanglement growth, and local-observable relaxation need not share one rate.

Experiments on a coherently split one-dimensional Bose gas observed rapid local emergence of thermal-like phase correlations and a light-cone-like spread of those correlations. The long-lived state retained memory associated with the near-integrable low-energy description. This is a canonical example of local prethermalization without global thermal equilibrium.

The interpretation depends on:

  • the Luttinger-liquid or related reference description;
  • approximate mode conservation;
  • the observable window;
  • residual integrability breaking from trapping, transverse modes, and nonlinear corrections.

Trapped-ion experiments observed long-lived quasistationary behavior in spin chains with tunable long-range interactions. Collective constraints and the competition of fluctuation and relaxation times can create a prethermal regime even when the mechanism is not a small perturbation of a conventional short-range integrable model.

Finite system size and interaction range are part of the result. An all-to-all or slowly decaying interaction can have scaling very different from a finite-range lattice theorem.

Driven optical-lattice experiments measured heating rates in an interacting Bose–Hubbard system and found strong, approximately exponential suppression as the drive frequency increased over the tested regime. The experiment linked the heating curve to the local many-body energy scales and resolved features associated with the equilibrium phase diagram.

The evidence is stronger than a single long-lived trace because frequency, interaction, and dimensionality were varied.

Nuclear-magnetic-resonance experiments in dipolar spin chains observed relaxation to a state described by a prethermal Hamiltonian and exponentially slow heating over an accessible high-frequency range. Tracking the autocorrelation of the effective Hamiltonian directly tested the proposed approximate conservation law.

Additional quasiconserved structures survived after the simplest effective-Hamiltonian picture began to fail, illustrating that several nested prethermal windows can occur.

When independent exponential decay channels are a good approximation, compare the intrinsic escape rate with the measured total:

Γobs=Γintrinsic+Γnoise+Γloss+Γbath+Γcontrol.\Gamma_{\mathrm{obs}} = \Gamma_{\mathrm{intrinsic}} + \Gamma_{\mathrm{noise}} + \Gamma_{\mathrm{loss}} + \Gamma_{\mathrm{bath}} + \Gamma_{\mathrm{control}}.

This additive approximation requires weak, approximately independent Markovian decay channels acting on the same measured quantity. Correlated noise, coherent errors, or different decay laws cannot generally be represented by a sum of constant rates. Calibration runs, particle-number monitoring, and independent coherence measurements help distinguish the mechanisms.

A system can equilibrate directly without a parametrically distinct plateau. Prethermalization requires at least two separated relaxation stages.

Exact charges produce stationary constrained behavior. Weakly broken charges can produce a prethermal GGE whose parameters drift. The same density operator can therefore describe an exact endpoint in one Hamiltonian and an intermediate state in a nearby Hamiltonian.

Idealized MBL retains quasilocal memory asymptotically in an isolated thermodynamic system. A prethermal regime retains memory only over a long finite window. Finite-time data can resemble both, so perturbation, disorder, transport, and lifetime scaling must be compared.

Metastability often refers to a particular state or phase protected by an energetic, entropic, or nucleation barrier. Prethermalization usually refers to local relaxation within an almost-invariant sector. The concepts overlap when a metastable sector rapidly develops internal local equilibrium before its rare decay.

Recent rigorous work connects metastable short-range-entangled states to eigenstates of nearby Hamiltonians and bounds local decay for nonperturbatively long times. This enlarges the mathematical setting but does not make every metastable plateau a Gibbs ensemble.

Quantum scars are atypical states or subspaces with unusual dynamics inside a broader spectrum. Fragmentation splits Hilbert space into disconnected components. Either can generate long-lived signals, but neither is automatically prethermal. A prethermal interpretation needs a tunable approximate constraint and an escape process.

A bath can create an attracting stationary state. That is not the same as an isolated prethermal plateau, although weak dissipation can stabilize, destroy, or reshape one. Compare τbath\tau_{\mathrm{bath}} with τ∗\tau_* explicitly.

Slow conserved-density transport can create intermediate spatial profiles. This can coexist with prethermalization, but ordinary diffusion alone does not imply an approximate extra charge.

Let a fast observable xx relax toward a value selected by a slow charge qq:

x˙=−γf[x−aq],q˙=−γs[q−qeq],\begin{aligned} \dot x &= -\gamma_f \left[ x-aq \right], \\ \dot q &= -\gamma_s \left[ q-q_{\mathrm{eq}} \right], \end{aligned}

with γs≪γf\gamma_s\ll\gamma_f. The slow variable is

q(t)=qeq+[q(0)−qeq]e−γst.q(t) = q_{\mathrm{eq}} + \left[ q(0)-q_{\mathrm{eq}} \right] e^{-\gamma_st}.

After the fast transient,

x(t)=aq(t)+O ⁣(γsγf).x(t) = aq(t) + O\!\left( \frac{\gamma_s}{\gamma_f} \right).

Thus

γf−1≪t≪γs−1\gamma_f^{-1} \ll t \ll \gamma_s^{-1}

gives

x(t)≃aq(0),x(t) \simeq aq(0),

while at late times x(t)→aqeqx(t)\to aq_{\mathrm{eq}}. Its drift has the slow scale γs\gamma_s. The relative tracking lag is controlled by γs/γf\gamma_s/\gamma_f, whereas the change from the initial plateau value accumulates as γst\gamma_st.

Exact two-rate relaxation curves show a rapid approach followed by slow escape; a second panel plots the small tracking lag

The two-rate model with a=1a=1, x(0)=0x(0)=0, q(0)=1q(0)=1, qeq=0q_{\mathrm{eq}}=0, and γs/γf=0.01\gamma_s/\gamma_f=0.01. After the fast transient, xx follows the slowly moving qq with a small lag. The plateau value nevertheless changes substantially by t∼γs−1t\sim\gamma_s^{-1}; a small tracking error is different from exact stationarity.

Why a first-order commutator need not imply a first-order rate

Section titled “Why a first-order commutator need not imply a first-order rate”

Suppose

H=H0+gV,[H0,Q]=0.H = H_0 + gV, \qquad [H_0,Q]=0.

In the interaction picture,

Δ⟨Q(t)⟩=igℏ∫0tds×⟨[VI(s),Q]⟩0+O(g2).\Delta\langle Q(t)\rangle = \frac{i g}{\hbar} \int_0^t ds \times \langle[V_I(s),Q]\rangle_0 + O(g^2).

For a finite set of off-resonant frequencies bounded away from zero, the oscillatory integral stays bounded rather than growing linearly. More generally one needs control of its low-frequency spectral weight; merely removing a zero-frequency delta peak is not sufficient in a gapless continuum. The leading secular drift can then arise at order g2tg^2t, giving τ∗∼g−2\tau_*\sim g^{-2}. If a resonance supplies a zero-frequency component, the order-gg term can grow and the lifetime is shorter.

Suppose a drive has heating rate

Γheat∼glocℏe−cℏΩ/gloc,\Gamma_{\mathrm{heat}} \sim \frac{g_{\mathrm{loc}}}{\hbar} e^{-c\hbar\Omega/g_{\mathrm{loc}}},

while H∗H_* locally equilibrates at rate Γloc∼gloc/ℏ\Gamma_{\mathrm{loc}}\sim g_{\mathrm{loc}}/\hbar. Then

τ∗τloc∼ecℏΩ/gloc.\frac{\tau_*}{\tau_{\mathrm{loc}}} \sim e^{c\hbar\Omega/g_{\mathrm{loc}}}.

The exponential controls the ratio of clocks, not the absolute quality of a low-order expansion. One still checks resonances, micromotion, and the first omitted term.

Work in dimensionless microscopic units and consider

Og(t)=Oth+(Opre−Oth)e−g2t.O_g(t) = O_{\mathrm{th}} + \left( O_{\mathrm{pre}}-O_{\mathrm{th}} \right) e^{-g^2t}.

Evaluate the two ordered limits g→0g\to0 and t→∞t\to\infty. Interpret the result.

Solution

At fixed g≠0g\neq0,

lim⁡t→∞Og(t)=Oth,\lim_{t\to\infty} O_g(t) = O_{\mathrm{th}},

so

lim⁡g→0lim⁡t→∞Og(t)=Oth.\lim_{g\to0} \lim_{t\to\infty} O_g(t) = O_{\mathrm{th}}.

At fixed tt,

lim⁡g→0Og(t)=Opre,\lim_{g\to0} O_g(t) = O_{\mathrm{pre}},

and therefore

lim⁡t→∞lim⁡g→0Og(t)=Opre.\lim_{t\to\infty} \lim_{g\to0} O_g(t) = O_{\mathrm{pre}}.

The exact integrable point has an indefinitely stable constrained value, whereas every fixed nonzero breaking eventually reaches the thermal value. The prethermal plateau occupies the singular intermediate window 1≪t≪g−21\ll t\ll g^{-2}.

Let [H0,Q]=0[H_0,Q]=0, H=H0+gVH=H_0+gV, and ∥[V,Q]∥≤C\|[V,Q]\|\le C. Show that

∣⟨Q(t)⟩−⟨Q(0)⟩∣≤∣g∣Ctℏ.\left| \langle Q(t)\rangle-\langle Q(0)\rangle \right| \le \frac{|g|Ct}{\hbar}.

What does this prove, and what does it fail to prove?

Solution

The Heisenberg equation gives

ddt⟨Q(t)⟩=igℏ⟨[V(t),Q(t)]⟩.\frac{d}{dt} \langle Q(t)\rangle = \frac{i g}{\hbar} \langle[V(t),Q(t)]\rangle.

Using ∣⟨A⟩∣≤∥A∥|\langle A\rangle|\le\|A\| and unitary invariance of the norm,

∣ddt⟨Q(t)⟩∣≤∣g∣Cℏ.\left| \frac{d}{dt} \langle Q(t)\rangle \right| \le \frac{|g|C}{\hbar}.

Integration yields the stated inequality. It guarantees small drift only up to a scale of order ∣g∣−1|g|^{-1} for fixed tolerance. It does not prove that this scale is sharp, that the system locally equilibrates, or that cancellations cannot extend the lifetime to g−2g^{-2} or a nonperturbative scale. For extensive QQ, one also needs a local or density-normalized version.

Suppose the effective dynamics conserves H∗H_* and an approximate charge Q~\widetilde Q over the observation window. Maximize

S=−Tr⁡(ρln⁡ρ)S = -\operatorname{Tr}(\rho\ln\rho)

subject to normalization and fixed expectations of H∗H_* and Q~\widetilde Q.

Solution

Introduce multipliers α\alpha, β∗\beta_*, and λ\lambda and vary

L=S−α(Tr⁡ρ−1)−β∗(Tr⁡ρH∗−E∗)−λ(Tr⁡ρQ~−q∗).\mathcal L = S -\alpha( \operatorname{Tr}\rho-1 ) - \beta_* \left( \operatorname{Tr}\rho H_*-E_* \right) - \lambda \left( \operatorname{Tr}\rho\widetilde Q-q_* \right).

Stationarity gives

ln⁡ρ=−1−α−β∗H∗−λQ~,\ln\rho = -1-\alpha-\beta_*H_*-\lambda\widetilde Q,

so

ρpre=1Zexp⁡ ⁣(−β∗H∗−λQ~).\rho_{\mathrm{pre}} = \frac{1}{Z} \exp\!\left( -\beta_*H_*-\lambda\widetilde Q \right).

For a full-rank optimum with compatible interior constraints, this is the maximum-entropy state; boundary constraints may require restricting its support or taking infinite multipliers. Noncommuting constraints still permit the exponential variational form. Approximate stationarity additionally requires their commutators with the effective Hamiltonian to be small, and a dynamical prediction requires local equilibration.

For

x˙=−γf(x−aq),q˙=−γs(q−qeq),\dot x = -\gamma_f(x-aq), \qquad \dot q = -\gamma_s(q-q_{\mathrm{eq}}),

derive the exact x(t)x(t) for γf≠γs\gamma_f\neq\gamma_s.

Solution

First,

q(t)=qeq+Δq e−γst,Δq=q(0)−qeq.\begin{aligned} q(t) &= q_{\mathrm{eq}} + \Delta q\,e^{-\gamma_st}, \\ \Delta q &= q(0)-q_{\mathrm{eq}}. \end{aligned}

Using an integrating factor for xx,

x(t)=aqeq+[x(0)−aqeq]e−γft+aγfΔqγf−γs(e−γst−e−γft).x(t) = aq_{\mathrm{eq}} + \left[ x(0)-aq_{\mathrm{eq}} \right] e^{-\gamma_ft} + \frac{a\gamma_f\Delta q} {\gamma_f-\gamma_s} \left( e^{-\gamma_st} - e^{-\gamma_ft} \right).

For γs≪γf\gamma_s\ll\gamma_f and γf−1≪t≪γs−1\gamma_f^{-1}\ll t\ll\gamma_s^{-1},

x(t)−aq(0)=O(aΔq γst)+O(aΔq γs/γf)+O ⁣([∣x(0)∣+∣aq(0)∣+∣aqeq∣]e−γft).x(t)-aq(0) ={}O(a\Delta q\,\gamma_st) +O(a\Delta q\,\gamma_s/\gamma_f) +O\!\left([|x(0)|+|aq(0)|+|aq_{\mathrm{eq}}|]e^{-\gamma_ft}\right).

Suppose changing an approximate charge requires kk applications of a perturbation gVgV. Estimate the leading transition amplitude and golden-rule rate.

Solution

If all lower orders vanish by a selection rule, the first nonzero effective matrix element is schematically

Meff∼gk∏j=1k−11Δj,M_{\mathrm{eff}} \sim g^k \prod_{j=1}^{k-1} \frac{1}{\Delta_j},

where Δj\Delta_j are intermediate-state detunings. A golden-rule rate is quadratic in the matrix element:

Γ∼2πℏ∣Meff∣2ρf.\Gamma \sim \frac{2\pi}{\hbar} |M_{\mathrm{eff}}|^2 \rho_f.

If the detunings remain of microscopic order and the final density of states ρf\rho_f is nonsingular,

Γ∝g2k,τ∗∝g−2k.\Gamma \propto g^{2k}, \qquad \tau_* \propto g^{-2k}.

Resonant denominators, vanishing phase space, or coherent dynamics can invalidate this estimate.

Verify that

S1=T+1−T−1US_1 = \frac{T_{+1}-T_{-1}}{U}

cancels T+1+T−1T_{+1}+T_{-1} to first order in eS1He−S1e^{S_1}He^{-S_1}.

Solution

Use

[Nd,Tm]=mTm.[N_d,T_m] = mT_m.

Therefore

[T+1,Nd]=−T+1,[T−1,Nd]=T−1.[T_{+1},N_d] = -T_{+1}, \qquad [T_{-1},N_d] = T_{-1}.

It follows that

[S1,UNd]=−T+1−T−1.[S_1,UN_d] = -T_{+1} -T_{-1}.

The Baker–Campbell–Hausdorff expansion begins

eS1He−S1=H+[S1,H]+⋯ .e^{S_1}He^{-S_1} = H+[S_1,H]+\cdots.

Hence the commutator with UNdUN_d cancels the charge-changing hopping at order JJ, leaving UNd+T0UN_d+T_0 plus terms of order J2/UJ^2/U.

7. Stroboscopic versus intracycle plateaus

Section titled “7. Stroboscopic versus intracycle plateaus”

Suppose

U(t)≃P(t)e−iH∗t/ℏP†(0),P(t+T)=P(t).\begin{aligned} U(t) &\simeq P(t)e^{-iH_*t/\hbar}P^\dagger(0), \\ P(t+T) &= P(t). \end{aligned}

Show how the expectation of a laboratory observable differs from that of its dressed representative.

Solution

For an initial state ρ0\rho_0,

⟨O⟩t=Tr⁡[ρ0U†(t)OU(t)].\langle O\rangle_t = \operatorname{Tr} \left[ \rho_0 U^\dagger(t)OU(t) \right].

Substituting the factorization gives evolution under H∗H_* of

O∗(t)=P†(t)OP(t),O_*(t) = P^\dagger(t)OP(t),

with the initial state dressed by P†(0)P^\dagger(0). At t=nTt=nT, periodicity gives P(nT)=P(0)P(nT)=P(0), so the same dressed observable is sampled each cycle. At intermediate phases, P(t)P(t) changes and can produce substantial micromotion even when the stroboscopic sequence is flat.

A local magnetization remains nearly constant for all measured times as a weak perturbation gg is varied. List a minimal set of additional measurements needed to distinguish prethermalization from exact conservation, finite-size freezing, localization, and technical decoherence.

Solution

A useful test set is:

  1. compute or measure the commutator of the proposed bare or dressed charge with the full Hamiltonian;
  2. measure several local observables and correlations, not only the magnetization;
  3. vary gg over a range sufficient to test a lifetime law;
  4. increase size so that level spacing and recurrence effects change;
  5. measure transport or spatial spreading to test localization;
  6. perturb disorder and integrability independently;
  7. monitor particle loss, control noise, and bath coherence times;
  8. extend the window until drift appears or report only a lower bound on τ∗\tau_*;
  9. compare the plateau values with a predicted H∗H_*, Gibbs state, or GGE;
  10. state the order of thermodynamic, long-time, and weak-coupling limits.

Together these measurements test the mechanism, local-state prediction, scaling, alternatives, and endpoint.

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