Lifetime and Spectral Weight
A quasiparticle description has a validity window: a branch must remain identifiable on the energy and time scales being studied. Its weight depends on the probe. Long propagation is an additional requirement for a trajectory or transport description, not for the existence of every excitation; a stationary band-edge mode or a localized oscillator can still be sharply defined.
Three quantities are central:
None is sufficient alone. A high narrow peak can have tiny area. A finite residue can accompany a width comparable to the branch separation. A long population lifetime can coexist with rapid phase dephasing. A transport lifetime can be much longer than a single-particle lifetime.
A useful interpretation identifies the operator, the analytic singularity behind its spectral feature, and the physical process that broadens it. The comparisons below separate spectral width, population decay, coherence, and transport.
Helpful background. Spectral Functions defines normalized spectra and measured intensity; Green Functions supplies the Dyson equation. Time-Dependent Correlations explains the Fourier connection between spectra and dynamics.
Complex Poles and Spectral Widths
Section titled “Complex Poles and Spectral Widths”Energy variable
Section titled “Energy variable”The spectral variable is energy,
The page uses
for a diagonal single-particle spectral function. Its units are inverse energy.
Retarded sign
Section titled “Retarded sign”Write
For a passive normal fermionic channel,
Retarded poles lie on or below the real axis. A pole in the upper half-plane would represent exponential growth and signals an instability, a sign error, or a nonretarded convention.
Pole and width
Section titled “Pole and width”A weakly damped pole is written
The time-domain pole amplitude varies as
For the associated Lorentzian spectral peak:
This page reserves for the energy FWHM.
Population lifetime
Section titled “Population lifetime”The pole amplitude decays with time constant
Its squared magnitude decays as
so, if this amplitude is a survival amplitude with no separate pure-dephasing process, its population lifetime is
Squaring a general Green function or ensemble-averaged coherence does not give an occupation. With pure dephasing, the spectral FWHM is instead , and must be obtained from population kinetics. The following uses only in the decay-only benchmark.
Many authors call that decay-only simply the quasiparticle lifetime. Others quote an amplitude decay time or use for the HWHM. A numerical linewidth–lifetime statement is meaningless until these choices are explicit.
Residue
Section titled “Residue”For a canonical fermionic orbital,
If one coherent pole has area , then
for that normalized diagonal channel. This bound does not carry unchanged to every bosonic response, matrix element, or experimentally weighted spectrum.
Four Complementary Tests
Section titled “Four Complementary Tests”Spectral test
Section titled “Spectral test”A peak should be narrow compared with the energy scale on which its center, background, matrix element, and self-energy vary:
There is no universal choice of . It may be a gap, excitation energy, neighboring-branch separation, distance to a threshold, or curvature scale.
Temporal test
Section titled “Temporal test”For a decay-only oscillatory excitation, a useful comparison is
For a mode with positive frequency and damping rate in inverse-time units, an equivalent quality factor is
The excitation is sharply underdamped when .
Propagation test
Section titled “Propagation test”For a wave packet with group velocity
define
For a semiclassical propagation description, a packet should travel many characteristic wavelengths or packet widths:
The rough crossover is often called an Ioffe–Regel criterion. It is a diagnostic crossover, not a universal phase-transition theorem.
Identity and weight test
Section titled “Identity and weight test”A branch label is useful only if the associated eigenvector or pole projector varies smoothly and remains distinguishable from nearby structures. Useful diagnostics include
Small in one operator channel does not destroy the excitation. It says that this operator has little overlap with it. Width comparable to separation or failure of a controlled pole expansion can invalidate a scalar branch description. Rapid exchange of bare-state character at a resolved avoided crossing does not itself destroy the exact eigenmodes; it requires tracking their eigenvectors.
Pole Expansion from the Self-Energy
Section titled “Pole Expansion from the Self-Energy”Dyson denominator
Section titled “Dyson denominator”For one scalar channel,
A candidate real quasiparticle energy satisfies
This real-axis equation is only a starting point. It can have several roots, no isolated root, or a root in a region where is too large for a quasiparticle expansion.
Residue from the real part
Section titled “Residue from the real part”For a stable simple pole, or approximately for a narrow resonance with a predominantly real residue and slowly varying imaginary self-energy,
The derivative measures how strongly the medium’s dynamical response follows a shift of the excitation energy. Through causality, this real-part renormalization is linked to the frequency dependence of ; mass renormalization and decay are not unrelated fitting knobs.
Width from the imaginary part
Section titled “Width from the imaginary part”To leading order in weak damping,
Therefore
In the decay-only interpretation, the population rate is
Dropping is justified only when the chosen on-shell approximation and self-energy convention make it consistent.
Coherent and incoherent pieces
Section titled “Coherent and incoherent pieces”Near an isolated pole,
The coherent spectral contribution is
Its area is
while its peak height is
Height therefore mixes weight and width. A tall peak need not carry much spectral weight.
Matrix-valued channels
Section titled “Matrix-valued channels”For canonical fermionic orbitals or fermionic Nambu components, or a first-order mode problem with unit frequency metric,
The pole residue is a matrix or projector, not one scalar attached independently to every diagonal element. Near a simple non-Hermitian pole,
where
For bosonic Nambu correlators, the commutator metric must be retained in the inverse propagator and residue; the unit-metric form above is not automatically applicable. The same left/right derivative construction works after defining the correct inverse kernel. Left and right eigenvectors differ when damping makes the effective problem non-Hermitian. Tracking only the largest diagonal peak can swap branch identity near a hybridization.
From Decay Matrix Elements to Widths
Section titled “From Decay Matrix Elements to Widths”Exact eigenstates do not decay
Section titled “Exact eigenstates do not decay”An exact eigenstate of a closed, time-independent Hamiltonian evolves only by a phase. Decay language refers instead to
- a state prepared by a simple microscopic operator;
- a metastable resonance embedded in a continuum;
- an excitation of an effective Hamiltonian coupled to omitted degrees of freedom;
- a subsystem state after environmental degrees of freedom are traced out;
- a wave packet or mode amplitude whose overlap spreads among exact eigenstates.
This distinction prevents the phrase “the state decays” from hiding which projection or observable is losing weight.
Golden-rule benchmark
Section titled “Golden-rule benchmark”Let a weak interaction couple an initial prepared state to a dense set of final states . In the long-time weak-coupling regime,
With the population-lifetime convention,
The rate is not “matrix element squared” alone. It is the product of
The sum counts each distinct final state once; a sum over ordered labels for identical daughter particles needs the corresponding symmetry factor. The delta function is an ideal long-time limit. At short time, strong coupling, a sharp threshold, or a sparse final spectrum, a constant Markovian rate need not emerge.
Conservation and symmetry
Section titled “Conservation and symmetry”For a translationally invariant one-to-two decay,
the energy constraint is
On a lattice, momentum conservation permits a reciprocal vector:
Even when these equations have solutions, decay can be forbidden by spin, parity, point-group representation, charge, topological sector, or a vanishing matrix element.
A branch below the minimum allowed continuum,
is kinematically stable against that channel at zero temperature.
Bose enhancement and Pauli blocking
Section titled “Bose enhancement and Pauli blocking”For a bosonic decay channel, a schematic finite-temperature factor is
Existing bosons stimulate final-state occupation. For fermionic final states, the corresponding availability factor is
Occupied fermion states are Pauli blocked.
These products describe an out-scattering process, not automatically the net linearized relaxation or retarded damping rate. For with bosonic daughters held at equilibrium, the gain–loss combination is
Its derivative with respect to is , not . Inverse processes therefore matter even when only the parent population is perturbed.
A full collision integral also contains inverse processes. For example, absorption of a thermal boson carries a factor , while emission carries . Equilibrium detailed balance makes the gain and loss terms cancel for the equilibrium distribution even though individual scattering events continue.
Imaginary self-energy and unitarity
Section titled “Imaginary self-energy and unitarity”The imaginary part of a retarded self-energy summarizes the probability flux from the projected one-particle channel into allowed intermediate and final states. Perturbatively, cutting rules and the optical theorem connect
to sums of on-shell transition probabilities.
The relation is structural, but factors of , , , degeneracy, and normalization depend on whether one quotes
- an on-shell bare self-energy;
- a dressed pole width;
- an amplitude rate;
- a population rate;
- an energy HWHM or FWHM.
Under the decay-only assumptions, the dressed population result is
Threshold nonanalyticity
Section titled “Threshold nonanalyticity”Suppose a continuum begins at with weighted density
Golden-rule phase space then turns on nonanalytically at threshold. The real part of the self-energy develops a related cusp or singular derivative through dispersion relations.
Near the edge, treating and as constants across the peak can fail. Possible outcomes include
- a stable bound state below threshold;
- a narrow resonance above threshold;
- an asymmetric threshold enhancement;
- a virtual state;
- complete dissolution into continuum weight.
Common microscopic channels
Section titled “Common microscopic channels”Intrinsic many-body broadening can arise from
- quasiparticle–quasiparticle scattering;
- emission or absorption of phonons, magnons, photons, or other collective modes;
- decay of one collective quantum into two or more lower-energy quanta;
- Landau damping into particle–hole pairs;
- interband transitions;
- multipair production;
- Umklapp processes;
- coupling to a bath or lead retained in an open-system description.
Elastic disorder can broaden momentum-resolved single-particle spectra without transferring energy. Static inhomogeneity can broaden an ensemble spectrum without giving every microscopic realization the same decay rate.
Which Lifetime?
Section titled “Which Lifetime?”Single-particle spectral lifetime
Section titled “Single-particle spectral lifetime”A common spectral-time convention assigns the following time to the FWHM of an added- or removed-particle peak:
This is half the amplitude-decay time of the simple pole. It equals a population-loss time only when that microscopic interpretation is justified. Scattering, dephasing, and averaging can all affect the spectral feature.
Transport lifetime
Section titled “Transport lifetime”Transport asks how quickly a current or another flux relaxes. For isotropic elastic scattering with angular probability ,
whereas
Small-angle scattering changes momentum only slightly. It can strongly broaden a momentum-resolved spectral peak while relaxing electrical current inefficiently:
is therefore possible.
Population and phase coherence
Section titled “Population and phase coherence”For a two-level coherence in a simple Markovian benchmark,
Here is a population-relaxation time and is pure dephasing. The coherence time can be shorter than the population lifetime even when no extra population decay occurs.
A single-particle Green function, a density response, and an off-diagonal coherence probe different operators. Their widths need not yield the same or .
Energy-relaxation lifetime
Section titled “Energy-relaxation lifetime”Elastic scattering can destroy momentum or phase coherence while leaving energy unchanged. Energy relaxation weights processes by transferred energy and may require multiple collisions.
Thus
are distinct kinetic moments of a collision process.
Collective-mode attenuation time
Section titled “Collective-mode attenuation time”For a collective pole
the mode amplitude decays as
Its amplitude decay time is , while its quadratic energy or intensity decays on in the ideal exponential model.
In a propagating mode with group velocity , the temporal attenuation length is
Experiments may instead fix real frequency and measure a complex wave vector
Then amplitude decays spatially as . Converting between and requires the local dispersion and weak-damping approximation.
Escape and dwell time
Section titled “Escape and dwell time”In a finite device or open cavity, a linewidth can reflect escape into leads or radiation channels:
when independent Markovian channels add at the level of rates. The escape width is physical but is not an intrinsic lifetime of the isolated material.
Lifetime dictionary
Section titled “Lifetime dictionary”| Quantity | What is lost? | Typical weighting |
|---|---|---|
| spectral lifetime | overlap with one operator-resolved excitation | all scattering out of the channel |
| transport lifetime | current or flux | angular or vertex weight |
| population lifetime | occupation of a prepared level or mode | gain–loss kinetics |
| coherence time | relative phase | population loss plus pure dephasing |
| energy-relaxation time | excess energy | transferred-energy weight |
| attenuation length | propagating amplitude in space | complex wave vector |
| escape time | probability inside a finite region | boundary coupling |
Calling all of these “the scattering time” erases the observable being predicted.
Spectral Weight and Residue
Section titled “Spectral Weight and Residue”Lehmann overlap
Section titled “Lehmann overlap”At zero temperature, an addition spectrum for a canonical fermion contains
in one declared grand-canonical energy convention.
For an isolated stable exact addition state, the residue is the operator overlap:
The insertion state is generally not normalized: , so an addition-pole residue obeys . A metastable resonance is not a normalizable exact eigenstate of the closed Hamiltonian; its complex analytic residue or approximate peak area replaces this exact overlap formula.
Operator dependence
Section titled “Operator dependence”Let two operators create different linear combinations of the same exact states:
The same excitation has weights
It can be bright in one channel and dark in another without changing its existence or energy.
Coherent versus incoherent weight
Section titled “Coherent versus incoherent weight”For a normalized diagonal canonical-fermion spectrum,
when one coherent pole is isolated and all other weight is grouped as incoherent.
The incoherent part is not experimental noise. It can contain
- shake-up satellites;
- multiparticle continua;
- molecular or atomic branches;
- phonon sidebands;
- Hubbard bands;
- threshold singularities;
- additional coherent poles not selected into .
Calling everything outside the main peak “background” can discard most of the many-body physics.
Peak height is not weight
Section titled “Peak height is not weight”For a Lorentzian with fixed area ,
Narrowing the peak doubles its height when the FWHM is halved, even though the residue is unchanged. Conversely, a broad feature can carry substantial integrated weight while having a low maximum.
Experimental intensity adds matrix elements and occupation factors:
The resolution kernel and probe matrix element must be removed or modeled before an intensity area can be called a quasiparticle residue.
Weight transfer under hybridization
Section titled “Weight transfer under hybridization”Consider two lossless levels coupled by
For real (its phase can be absorbed into ), choose the angle branch continuously so that
If the probe creates only bare state , its weights in the two exact eigenmodes are
An expression that fixes the branch on both sides of the crossing is
Their sum is conserved:
Across the avoided crossing, the peaks exchange weight smoothly. Following only the brighter peak can produce an apparent jump between eigenbranches.
Fermi-surface discontinuity
Section titled “Fermi-surface discontinuity”In a conventional Fermi liquid at zero temperature, the jump in momentum occupation at the Fermi surface equals the quasiparticle residue:
This is a special relation tied to the single-particle Green function and Fermi-liquid structure. It is not a universal definition of residue in every phase.
Bosonic and collective residues
Section titled “Bosonic and collective residues”For bosonic Nambu Green functions, residues can involve , , and an indefinite metric. For a density or spin response, a pole coefficient has units set by the chosen operators and normalization.
Therefore statements such as
must be restricted to a normalized positive diagonal channel. A collective-mode oscillator strength, a dielectric pole residue, and a fermionic addition probability are not the same quantity merely because all are called spectral weight.
Sum rules and partial windows
Section titled “Sum rules and partial windows”An exact sum rule constrains the complete spectrum:
A finite experimental window measures only
Missing high-energy satellites or negative-energy weight can make an apparent residue change even when the complete sum rule is satisfied. Track both the pole area and the closure of the relevant total moment.
Broad Continua and Non-Lorentzian Response
Section titled “Broad Continua and Non-Lorentzian Response”Continuum does not mean noise
Section titled “Continuum does not mean noise”In the thermodynamic limit, multiparticle energies can become dense. The analytic Green function then develops a branch cut rather than isolated poles. Its spectral weight can be smooth, singular at a threshold, or divided among several overlapping continua.
A continuum can represent perfectly coherent exact eigenstates of the full closed Hamiltonian. The apparent decay of a simple prepared state comes from dephasing among those many frequencies.
Survival amplitude
Section titled “Survival amplitude”For a normalized spectral measure associated with a prepared state,
A pole approximation
gives
This exact exponential uses an ideal Lorentzian extending over the whole real axis. A physical Hamiltonian bounded below cannot preserve that form at arbitrarily short and long times.
Threshold tails
Section titled “Threshold tails”If
with , then the threshold contribution has long-time scaling
up to a complex coefficient and powers of .
If this edge dominates and no stable pole or other slower contribution persists, the late-time decay is a power law. Assigning one constant lifetime to a threshold-dominated spectrum loses the physically important exponent.
Short-time behavior
Section titled “Short-time behavior”For a state with finite energy variance,
The survival probability begins quadratically, whereas a pure exponential begins linearly. Golden-rule exponential decay is therefore an intermediate-time approximation, not an exact identity at .
Fano interference
Section titled “Fano interference”When a probe reaches the same final continuum through a direct path and through a resonant discrete state, the amplitudes interfere. A standard reduced line shape is
where
The result can be an asymmetric peak, a peak–dip structure, or a near-zero. Its maximum and apparent half-width do not obey the elementary isolated-Lorentzian dictionary.
Inhomogeneous and instrumental broadening
Section titled “Inhomogeneous and instrumental broadening”If each microscopic region has a narrow Lorentzian but their center energies have a Gaussian distribution, the ensemble line is a Voigt profile. Its width contains both homogeneous and inhomogeneous contributions.
Similarly, a finite observation window convolves the intrinsic spectrum with a sinc-like or chosen window transform. A numerical regulator
replaces exact delta functions by plotting kernels. Neither operation creates an intrinsic many-body decay rate.
Finite systems
Section titled “Finite systems”A finite-dimensional closed model, or a confined finite-volume model with discrete spectrum, has exact discrete lines. Apparent smoothness can result when
or when the observation time is too short to resolve the level spacing. A physical continuum requires a declared limit, reservoir, average, or experimental resolution.
The limits
need not commute.
Top: two exact Lorentzians share area over the full real line, but differ by a factor of four in HWHM and peak height; only part of each tail is shown. Bottom: the normalized threshold distribution has survival amplitude and probability , in units . Its quadratic initial loss and algebraic tail differ from the dashed exponential. The two panels illustrate separate models, not a claimed Fourier pair.
When Is the Excitation Well Defined?
Section titled “When Is the Excitation Well Defined?”Finite-energy narrowness
Section titled “Finite-energy narrowness”For a gapped or finite-energy branch measured relative to a physically relevant reference,
The pole is parametrically sharp when
The reference must be stated. For a particle excitation it may be the chemical potential; for a resonance it may be a threshold; for an optical mode it may be zero energy.
Gapless scaling
Section titled “Gapless scaling”For a gapless branch, both energy and width can vanish:
The decisive ratio is
If it tends to zero, the branch becomes asymptotically sharp. If it approaches a nonzero constant, the mode has only a finite quality factor. If it diverges, the would-be excitation is overdamped in the infrared.
Quoting only is insufficient: every low-energy scale may be vanishing at the same time.
Branch separation
Section titled “Branch separation”Let
A scalar assignment based on energy separation is controlled when
At an exact degeneracy, symmetry or another commuting observable may still distinguish channels even when this energy-separation test cannot. Near an avoided crossing or exceptional point, use the full matrix response. A fit to independent Lorentzians can fail even when two visible maxima remain.
Distance to continuum
Section titled “Distance to continuum”Define
for a branch below a continuum. If , the channel is closed at zero temperature. If the branch lies above threshold, the local separation no longer protects it and the imaginary self-energy must be evaluated.
Near
threshold curvature usually invalidates a constant-width Lorentzian.
Smooth-self-energy test
Section titled “Smooth-self-energy test”The pole expansion assumes the self-energy changes little across one width. Schematic requirements are
and
The second compares the quadratic term of the inverse propagator with its linear term and is dimensionless. These are local diagnostics, not exact inequalities with universal constants. A divergent derivative, nearby pole, or threshold singularity demands a non-Lorentzian treatment.
Propagation and Ioffe–Regel test
Section titled “Propagation and Ioffe–Regel test”For a nearly monochromatic packet,
The regime
supports many oscillations over a mean free path. When becomes order unity, momentum and trajectory cease to be sharply resolved in a semiclassical picture.
For a lattice excitation near a Brillouin-zone boundary, is not always the relevant size. Compare with the packet width, lattice spacing, and local wavelength measured relative to the band extremum.
Interpreting a Small Residue
Section titled “Interpreting a Small Residue”There is no universal threshold such as
for quasiparticle existence. A sharp eigenmode can have small weight in one microscopic operator. Conversely, a broad maximum can carry large integrated weight without yielding a long-lived particle.
Residue becomes decisive when combined with other failures:
For a proposed propagating branch, these combined failures indicate that a scalar particle description may no longer be useful. They are not necessary conditions for every localized or symmetry-resolved excitation.
Controlled-theory test
Section titled “Controlled-theory test”A narrow numerical peak is trustworthy only if its width is stable under
- frequency and momentum resolution;
- finite-size scaling;
- regulator removal;
- basis or bond-dimension enlargement;
- self-consistency and vertex choices;
- analytic-continuation priors;
- conservation-law and sum-rule checks.
An unresolved width is an upper bound or a resolution statement, not a measured lifetime.
Representative Regimes
Section titled “Representative Regimes”Fermi-liquid quasiparticles
Section titled “Fermi-liquid quasiparticles”For a conventional three-dimensional Fermi liquid near its Fermi surface, phase-space restriction and Pauli blocking give the schematic low-energy rate
times an interaction-dependent dimensionless coefficient. Here
At zero temperature,
The quasiparticle becomes asymptotically sharp even though its lifetime diverges only as the Fermi surface is approached. In two dimensions, logarithmic factors can modify the simple quadratic law.
The Fermi Liquid Theory Preview develops the Landau construction, effective mass, interaction function, and thermodynamic relations.
Electron–phonon threshold
Section titled “Electron–phonon threshold”At zero temperature, an electron can emit a dispersionless phonon of energy only if its initial energy and momentum permit a final electronic state plus that phonon:
Below the emission threshold, that channel contributes no real decay in the ideal clean model, though virtual phonons still renormalize the real self-energy and residue. At finite temperature, absorption appears with Bose factor
Thus an energy kink, residue change, and linewidth onset are causally related signatures of the same coupling, not independent effects.
Weak Bose-gas phonons
Section titled “Weak Bose-gas phonons”In a weakly interacting three-dimensional Bose condensate at zero temperature, a long-wavelength Bogoliubov phonon can decay by the Beliaev process into two lower-energy phonons. In the asymptotic regime,
Therefore
The mode becomes sharply defined in the infrared even though decay is kinematically allowed. Curvature, dimension, temperature, and interaction range can change the available phase space.
Magnons and crystal phonons
Section titled “Magnons and crystal phonons”Anharmonic phonons and interacting magnons can decay when one branch overlaps a symmetry-allowed multiparticle continuum. Their widths depend on cubic or quartic vertices, occupation factors, crystal momentum conservation, and density of states.
The relevant Hamiltonians are developed in:
A dispersion entering a continuum does not guarantee large damping if the matrix element vanishes. A branch outside a two-particle continuum can still decay through disorder, higher-particle channels, or coupling to another subsystem.
Plasmons
Section titled “Plasmons”A long-wavelength three-dimensional plasmon can lie above the one-pair particle–hole continuum and avoid ideal one-pair Landau damping. At larger momentum it can enter that continuum, lose pole weight, and broaden.
Plasmons Preview develops the dielectric zero, loss function, dimensional scaling, and -sum-rule analysis. The lesson here is diagnostic: frequency, FWHM, and pole weight must all be tracked through continuum entry.
Polarons
Section titled “Polarons”A polaron pole can remain sharp while its bare-particle residue becomes small because much of the state resides in its dressing cloud. Conversely, a repulsive polaron branch may retain visible residue while having a finite decay width into a lower branch and host excitations.
The pair
contains independent information. Polarons Preview develops the mobile-impurity construction and branch taxonomy.
One-dimensional continua
Section titled “One-dimensional continua”In a generic gapless interacting one-dimensional fermion liquid, a microscopic fermion excites collective sectors. Spinful liquids can have distinct spin and charge waves; a spinless liquid has no independent spin sector. The single-fermion spectral function may have threshold power laws but no finite-residue pole:
This is not merely a quasiparticle with a very short Lorentzian lifetime. The correct low-energy language is collective and critical. Luttinger Liquid Preview develops that construction.
Critical and strongly incoherent regimes
Section titled “Critical and strongly incoherent regimes”Near a quantum critical point, the only low-energy scale can be temperature or frequency itself. A response may obey scaling such as
or
without a small narrowness ratio. A broad universal scaling function can be physically precise even when quasiparticle language is not.
The absence of a sharp pole is not absence of theory. Hydrodynamic variables, critical operators, kinetic distributions, or fractionalized degrees of freedom may provide the controlled description.
Temperature, Disorder, and Multiple Channels
Section titled “Temperature, Disorder, and Multiple Channels”Thermal broadening
Section titled “Thermal broadening”Temperature opens absorption channels, changes Bose and Fermi occupation factors, and smears sharp occupation boundaries. The retarded self-energy itself can be temperature dependent:
Do not infer the intrinsic zero-temperature residue by fitting a temperature-broadened peak with a fixed background and fixed matrix element.
Elastic disorder
Section titled “Elastic disorder”For static weak disorder in a simple Born approximation,
Energy is conserved, but momentum-resolved overlap decays. The transport rate adds an angular current-relaxation factor.
Disorder averaging can restore translation invariance statistically while hiding localization, rare regions, or sample-to-sample variation. A disorder-averaged width is not automatically the lifetime of one realization.
Rate addition and its limits
Section titled “Rate addition and its limits”Independent weak Markovian channels often motivate Matthiessen-type addition:
This approximation can fail when channels interfere, share intermediate states, alter the spectrum self-consistently, or have strong energy dependence. Adding fitted FWHMs is especially unsafe for non-Lorentzian or inhomogeneous lines.
Vertex selectivity
Section titled “Vertex selectivity”Two probes can report different apparent widths because they couple to different momentum regions, orbitals, polarizations, or many-body channels. A probe-dependent intensity is
not the density of all states at that energy.
Agreement in peak energy does not require agreement in linewidth or residue.
Extracting Width and Weight
Section titled “Extracting Width and Weight”Begin with a forward model
Section titled “Begin with a forward model”An observed spectrum should be modeled schematically as
Here is a probe matrix element, an occupation or detailed-balance factor, a background, and the instrument response. The intrinsic spectrum may itself contain several poles and continua.
Deconvolution is often ill conditioned. It is safer to convolve a causal intrinsic model forward and fit the observed data than to divide noisy data by a resolution function.
Energy-distribution curves
Section titled “Energy-distribution curves”At fixed momentum, an energy-distribution curve samples
before convolution and backgrounds. A Lorentzian energy width can estimate only when
- the self-energy is smooth across the line;
- nearby bands and satellites are resolved or modeled;
- the occupation cutoff is treated;
- matrix elements and background vary slowly;
- instrumental and inhomogeneous widths are separated.
Near a threshold or Fano interference, the fitted Lorentzian center and width can be biased even at high signal-to-noise ratio.
Momentum-distribution curves
Section titled “Momentum-distribution curves”At fixed energy, suppose the bare dispersion is locally linear:
where has units of energy times length. If is nearly independent of momentum, the momentum-distribution curve is approximately Lorentzian with HWHM
Converting this to an energy FWHM by multiplying by a measured velocity requires care. Strong momentum dependence, band curvature, matrix-element variation, overlapping bands, and a momentum-dependent background invalidate the elementary relation.
Damped-oscillator modes
Section titled “Damped-oscillator modes”A common collective-response model is
Its poles are
For , the positive-frequency peak is locally Lorentzian with angular-frequency FWHM approximately
When damping is not weak, the peak maximum, real part of the pole, and undamped parameter differ appreciably. Quoting one of them as “the mode frequency” without the model is ambiguous.
Resolution and Voigt profiles
Section titled “Resolution and Voigt profiles”A Lorentzian intrinsic line convolved with a Gaussian resolution gives a Voigt profile. If their FWHMs are and , the Olivero–Longbothum approximation is
The observed FWHM is not the sum in quadrature of two arbitrary line shapes. Resolution parameters should be calibrated independently when possible.
Integrating weight
Section titled “Integrating weight”Define the weight of one resolved component over a declared window:
Systematic uncertainty in the baseline can dominate statistical fit uncertainty for broad peaks. Vary the window, baseline family, resolution, and number of components. Report how much of the exact or known sum rule lies outside the window.
Coupled peaks
Section titled “Coupled peaks”If two modes hybridize, fit a matrix response or a coupled-mode denominator. Independent peak fits do not enforce
- common poles across channels;
- causal real and imaginary parts;
- oscillator-strength conservation;
- shared damping pathways;
- eigenvector continuity.
A physically constrained fit can require fewer meaningful parameters than several unrelated Lorentzians.
Computational Methods and Checks
Section titled “Computational Methods and Checks”Perturbative self-energies
Section titled “Perturbative self-energies”At weak coupling, compute and solve either
- an on-shell approximation using the reference energy;
- a quasiparticle equation for the real part;
- the full complex pole equation.
State which was used. Self-consistent dressing can improve some regimes and violate others if vertices are not updated consistently.
Kinetic equations
Section titled “Kinetic equations”A Boltzmann or quantum kinetic equation resolves gain and loss rates for distribution functions. It is the natural tool for transport, energy relaxation, and nonequilibrium populations, but it may discard off-shell spectral structure and coherent memory. Boltzmann Transport derives collision operators and their electrical and thermal responses.
The collision integral must preserve the intended conserved quantities:
for number-conserving scattering, with analogous weighted identities for energy and momentum where appropriate.
Exact diagonalization and Krylov spectra
Section titled “Exact diagonalization and Krylov spectra”Finite-size exact spectra are sums of delta functions. Introduced broadening is a visualization and resolution scale:
Vary independently of system size. A stable physical width should not simply track the chosen regulator.
Real-time evolution
Section titled “Real-time evolution”Real-time methods can extract decay envelopes directly, but finite duration limits energy resolution:
Window choice changes spectral leakage and apparent FWHM. Entanglement growth, boundary reflections, and finite-size recurrences set additional time limits.
Fit exponential, stretched-exponential, Gaussian, and power-law forms only where the corresponding residuals and physical mechanisms support them.
Imaginary-time data
Section titled “Imaginary-time data”Imaginary-time correlators smooth real-frequency structure through an integral kernel. Several spectra with different narrow linewidths can agree within the same statistical errors.
A continued peak width is trustworthy only if synthetic-resolution tests, covariance, sum rules, positivity, prior variation, and alternative continuations show that the width is identifiable. Otherwise report a bound or resolution limit.
Causality and positivity
Section titled “Causality and positivity”A normal diagonal fermionic spectrum must obey
The retarded Green function must be analytic in the upper half-plane, and its real and imaginary parts must satisfy dispersion relations. Negative diagonal weight, an upper-half-plane pole, or a violated normalization is not a novel lifetime effect.
Conservation and vertex consistency
Section titled “Conservation and vertex consistency”A self-energy approximation can generate a plausible single-particle width while an inconsistent response vertex violates a Ward identity or sum rule. When using the same approximation to infer transport or density-mode lifetimes, check the associated conserved-current constraints.
Worked Checks
Section titled “Worked Checks”Self-energy factors of two
Section titled “Self-energy factors of two”Suppose a quasiparticle root occurs at
with
and
The residue is
The dressed HWHM is
so
Using
the decay-only population lifetime is
Using would instead give the amplitude decay time, twice as long.
Equal residue, unequal height
Section titled “Equal residue, unequal height”Take two Lorentzians with the same area
but HWHMs
Their peak-height ratio is
The first peak is four times taller, yet both carry the same coherent weight.
Forward scattering
Section titled “Forward scattering”Suppose elastic scattering is concentrated near a small angle . Then
If the angular distribution is narrow enough to replace by , then
For
one estimates
A broad single-particle line can therefore coexist with relatively efficient current flow.
Fermi-liquid scale estimate
Section titled “Fermi-liquid scale estimate”Use the schematic coefficient-one estimate
at zero temperature. With
one finds
The narrowness ratio is
and the corresponding illustrative lifetime is
The coefficient is interaction and dimension dependent; the robust statement is the asymptotic ratio .
Resolution-dominated line
Section titled “Resolution-dominated line”Let an intrinsic Lorentzian have
and let the Gaussian resolution have
The Voigt estimate gives
Using the observed width directly would give
whereas the intrinsic Lorentzian lifetime is
Resolution cannot be ignored merely because the observed line looks smooth.
Exercises
Section titled “Exercises”Exercise 1: Pole, line shape, and two decay times
Section titled “Exercise 1: Pole, line shape, and two decay times”Consider
Derive the spectral function, its area, HWHM, and FWHM. Fourier transform the pole for . Under a decay-only survival-amplitude interpretation, identify the amplitude and population decay times; explain why pure dephasing would invalidate the population inference.
Solution
The imaginary part is
Therefore
Using the normalized Lorentzian integral,
At the maximum,
Half maximum occurs when
Thus
Closing the retarded Fourier contour in the lower half-plane for gives, up to the transform normalization,
The amplitude decay time is
The squared magnitude decays as , so
With additional pure dephasing, the measured pole amplitude instead has coherence time . Its squared magnitude decays on , which is not the population time in general. Only when can the linewidth alone determine .
Exercise 2: Self-energy renormalization
Section titled “Exercise 2: Self-energy renormalization”Near a quasiparticle root, suppose
Assume a decay-only pole with no extra pure dephasing. Find the residue, dressed HWHM, FWHM, and population lifetime.
Solution
The residue is
The HWHM is
Therefore
Using ,
The undressed quantity meV would overestimate the dressed FWHM by a factor of four in this linearized example.
Exercise 3: Threshold phase space
Section titled “Exercise 3: Threshold phase space”A prepared level of energy couples with constant matrix element to a continuum labeled by in dimensions:
Use the golden rule to determine how the decay rate scales just above threshold.
Solution
Ignoring volume-normalization constants, the rate is
Let
There is no on-shell phase space for . For , spherical coordinates give
The on-shell momentum is
Since
the rate scales as
Thus the formal golden-rule onset diverges in one dimension, steps on in two dimensions, and grows as in three dimensions. The one-dimensional divergence signals failure of a uniform weak-coupling rate approximation arbitrarily close to threshold; it is not a controlled prediction of an infinite physical decay rate. A momentum-dependent matrix element can change these powers.
Exercise 4: Spectral versus transport lifetime
Section titled “Exercise 4: Spectral versus transport lifetime”Assume all elastic scattering occurs at one angle . Show that
Evaluate the ratio for forward scattering with and for backscattering with .
Solution
If the total scattering probability is , then
and
Dividing gives
For ,
so
For backscattering,
and therefore
One backscattering event relaxes current especially efficiently, while many forward-scattering events can be required.
Exercise 5: Weight exchange at an avoided crossing
Section titled “Exercise 5: Weight exchange at an avoided crossing”For
take and assume the probe creates only bare state . Show that the total probe weight in the two exact eigenstates is conserved. Find both weights exactly at resonance .
Solution
Choose normalized eigenvectors
The probe weights are
and
Therefore
At resonance the eigenvectors are equal symmetric and antisymmetric mixtures, so
Hence
The bare-state weight is redistributed, not destroyed.
Exercise 6: Threshold tail
Section titled “Exercise 6: Threshold tail”Let the threshold part of a spectral measure be
with and . Determine the leading large- power of its survival amplitude.
Solution
Set
Then
Combine the exponentials:
where
Thus
For ,
The corresponding survival probability scales as
if this threshold term dominates.
Exercise 7: Regulator or physical width?
Section titled “Exercise 7: Regulator or physical width?”A finite-size calculation produces a peak whose measured FWHM is
for every tested Lorentzian regulator , while increasing system size only adds more unresolved lines under the envelope. What can be concluded about the intrinsic lifetime?
Solution
The observed width tracks the imposed kernel:
It therefore does not establish a regulator-independent intrinsic width. At finite size the exact spectrum remains a sum of delta functions.
More system sizes and smaller are needed while comparing with the level spacing. One should examine whether a smooth envelope converges in a controlled thermodynamic limit and whether a complex pole or continuum calculation predicts a nonzero width after .
From these results, one may report only the broadened spectral envelope and a resolution bound. Assigning
as a physical lifetime would be unjustified.
Exercise 8: Asymptotic Fermi-liquid criterion
Section titled “Exercise 8: Asymptotic Fermi-liquid criterion”At zero temperature, suppose
with dimensionless. Show that the quasiparticle becomes asymptotically sharp relative to its excitation energy. Assuming decay-only broadening, determine how the population lifetime and number of oscillations scale as .
Solution
The narrowness ratio is
Therefore
as .
The population lifetime is
so it diverges as .
One complete oscillation period associated with the excitation energy is
Their ratio is
which diverges as . The excitation survives an increasing number of its own oscillation times.
References
Section titled “References”- A. A. Abrikosov, L. P. Gor’kov, and I. E. Dzyaloshinski, Methods of Quantum Field Theory in Statistical Physics (Dover, 1975). Analytic Green functions and quasiparticle methods in interacting systems.
- G. Baym and L. P. Kadanoff, “Conservation laws and correlation functions,” Physical Review 124, 287–299 (1961), doi:10.1103/PhysRev.124.287. Conserving approximations and consistent self-energy–vertex structure.
- G. Baym and C. Pethick, Landau Fermi-Liquid Theory: Concepts and Applications (Wiley, 1991), doi:10.1002/9783527617159. Systematic low-energy quasiparticle theory and collision scales.
- S. T. Beliaev, “Energy spectrum of a non-ideal Bose gas,” Soviet Physics JETP 7, 299–307 (1958), JETP archive. Quasiparticle corrections and low-momentum damping in a dilute Bose gas.
- A. Damascelli, Z. Hussain, and Z.-X. Shen, “Angle-resolved photoemission studies of the cuprate superconductors,” Reviews of Modern Physics 75, 473–541 (2003), doi:10.1103/RevModPhys.75.473. Experimental spectral functions, matrix elements, self-energy extraction, and resolution.
- P. A. M. Dirac, “The quantum theory of the emission and absorption of radiation,” Proceedings of the Royal Society A 114, 243–265 (1927), doi:10.1098/rspa.1927.0039. Transition amplitudes and the perturbative rate framework underlying the golden rule.
- U. Fano, “Effects of configuration interaction on intensities and phase shifts,” Physical Review 124, 1866–1878 (1961), doi:10.1103/PhysRev.124.1866. Interference between a discrete resonance and continuum.
- A. L. Fetter and J. D. Walecka, Quantum Theory of Many-Particle Systems (McGraw–Hill, 1971). Green functions, self-energies, spectral representations, damping, and response.
- G. F. Giuliani and G. Vignale, Quantum Theory of the Electron Liquid (Cambridge University Press, 2005), doi:10.1017/CBO9780511619915. Electron-liquid quasiparticles, response, damping, and sum rules.
- F. Giustino, “Electron–phonon interactions from first principles,” Reviews of Modern Physics 89, 015003 (2017), doi:10.1103/RevModPhys.89.015003. Modern electron–phonon self-energies, spectral renormalization, relaxation rates, and transport.
- L. Hedin and S. O. Lundqvist, “Effects of electron–electron and electron–phonon interactions on the one-electron states of solids,” Solid State Physics 23, 1–181 (1969), doi:10.1016/S0081-1947(08)60615-3. Self-energy, quasiparticle renormalization, lifetimes, and one-electron spectra.
- L. D. Landau, “The theory of a Fermi liquid,” Soviet Physics JETP 3, 920–925 (1957). Foundational quasiparticle and Fermi-liquid construction.
- H. Lehmann, “Über Eigenschaften von Ausbreitungsfunktionen und Renormierungskonstanten quantisierter Felder,” Il Nuovo Cimento 11, 342–357 (1954), doi:10.1007/BF02783624. Spectral representation, propagator singularities, and field-strength residues.
- G. D. Mahan, Many-Particle Physics, 3rd ed. (Springer, 2000), doi:10.1007/978-1-4757-5714-9. Self-energy, spectral weight, electron–boson coupling, transport, and response.
- A. A. Maradudin and A. E. Fein, “Scattering of neutrons by an anharmonic crystal,” Physical Review 128, 2589–2608 (1962), doi:10.1103/PhysRev.128.2589. Anharmonic phonon shifts, decay, and scattering line shapes.
- P. Nozières, Theory of Interacting Fermi Systems (W. A. Benjamin, 1964). Quasiparticle poles, response, and Fermi-liquid validity.
- J. J. Olivero and R. L. Longbothum, “Empirical fits to the Voigt line width: A brief review,” Journal of Quantitative Spectroscopy and Radiative Transfer 17, 233–236 (1977). doi:10.1016/0022-4073(77)90161-3.
- J. J. Quinn and R. A. Ferrell, “Electron self-energy approach to correlation in a degenerate electron gas,” Physical Review 112, 812–827 (1958), doi:10.1103/PhysRev.112.812. Imaginary self-energy and low-energy electron damping.
Cross-Links
Section titled “Cross-Links”- Quasiparticles Overview
- Spectral Functions
- Green Functions in Many-Body QM
- Time-Dependent Correlations
- Collective Modes
- Particle–Hole Excitations
- Fermi Liquid Theory Preview
- Non-Fermi Liquids
- Luttinger Liquid Preview
- Phonons as Many-Body Excitations
- Magnons
- Bogoliubov Quasiparticles
- Polarons Preview
- Plasmons Preview
- Sum Rules
- Transport Coefficients Preview
- Diagrammatic Methods Preview
- Analytic Continuation
- Fermi’s Golden Rule
- Energy–Time Uncertainty
- Spectroscopy gives the complementary measurement-level dictionary for centers, areas, widths, line shapes, and instrument response.