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This page is the rapid lookup and translation layer for notation in many-body and statistical quantum mechanics. It answers questions such as “Is NN a number or an operator?”, “Does k\mathbf k mean momentum or wave number?”, and “Which factors of NsN_s, 2π2\pi, ℏ\hbar, and kBk_{\mathrm B} are in this formula?”

Required background. Conventions explains the general bra–ket and unit conventions.

A specialized article may override any default below when another convention is standard for that subject. The override must be stated near the first affected formula and used consistently.

Particle number, sites, and operator labels

Section titled “Particle number, sites, and operator labels”

A symbol’s index, units, and definition determine how to use it. In particular, NN particles, NsN_s sites, and the number operator N^\hat N are different objects. For a spin-1/21/2 fermion lattice with one spatial orbital per site, half filling means N/Ns=1N/N_s=1, because there are two spin modes per site.

Object Default notation Interpretation
scalar parameter TT, μ\mu, tt, JJ a number with stated units
spatial vector r\mathbf r, k\mathbf k, q\mathbf q boldface marks a spatial vector
operator HH, AA, SiαS_i^\alpha hats are omitted when operator status is unambiguous
ambiguous number operator N^\hat N the hat distinguishes it from NN or ⟨N^⟩\langle\hat N\rangle
pure state ∣Ψ⟩\lvert\Psi\rangle normalized unless stated otherwise
density operator ρ\rho positive and trace one for a normalized state
identity II or IHI_{\mathcal H} subscript names the space when needed
complex conjugate z∗z^* scalar conjugation
adjoint A†A^\dagger Hilbert-space adjoint
transpose ATA^{\mathsf T} basis-dependent transpose
expectation value ⟨A⟩\langle A\rangle state or ensemble must be recoverable

Bold symbols are reserved for geometric vectors, not merely for collections of components. An arrow notation such as k⃗\vec k may appear in cited literature, but a page should not alternate between k⃗\vec k and k\mathbf k without reason.

These are defaults, not universal laws:

Index Usual domain Common role
i,j,ℓi,j,\ell lattice sites local operators and hopping links
a,ba,b orbitals, bands, species, or Cartesian components must be declared locally
σ,σ′\sigma,\sigma' ↑,↓\uparrow,\downarrow or an internal set spin or pseudospin component
α,β\alpha,\beta internal or Cartesian components flavor, spin component, or tensor index
n,mn,m integers or eigenstate labels energy level, occupation, or Matsubara integer
k,q\mathbf k,\mathbf q reciprocal-space grid or continuum wave vector and transferred wave vector
p,qp,q generic one-particle modes not necessarily momentum
A,BA,B subsystems or observables distinguish by typography and context
ss spin projection, species, or contour branch define before use

Repeated indices are not summed automatically unless an article declares an Einstein convention. Lattice and mode sums are normally written explicitly. Cartesian tensor formulas may use implicit summation after saying so.

Composite labels compress several indices. For example,

1≡(r1,σ1,t1)1 \equiv (\mathbf r_1,\sigma_1,t_1)

is acceptable in a Green-function derivation only after the measure associated with ∫d1\int d1 has also been defined.

Symbol Default meaning
NN number of particles or a fixed particle-number eigenvalue
N^\hat N total particle-number operator
NsN_s number of lattice sites
MM number of retained one-particle modes or orbitals
NfN_f number of flavors or field components
VV physical volume
LL linear system size
dd spatial dimension
aa lattice spacing
nn particle density N/VN/V
ν\nu filling N/NsN/N_s

For an isotropic hypercubic lattice with compatible periodic counting,

Ns=(La)d.N_s = \left( \frac{L}{a} \right)^d.

Density and filling answer different questions:

n=NV,ν=NNs.\begin{aligned} n &= \frac{N}{V}, \\ \nu &= \frac{N}{N_s}. \end{aligned}

The filling is dimensionless. The density has units of inverse volume. A continuum limit usually changes aa, NsN_s, and the couplings together; it is not obtained by replacing NsN_s with VV in a lattice formula.

For anisotropic boxes, use L1,…,LdL_1,\ldots,L_d and state

V=∏a=1dLaV = \prod_{a=1}^{d}L_a

rather than concealing the shape in one length LL.

A pure-state and density-operator expectation are

⟨A⟩Ψ=⟨Ψ∣A∣Ψ⟩,⟨A⟩ρ=Tr⁡(ρA).\begin{aligned} \langle A\rangle_\Psi &= \langle\Psi|A|\Psi\rangle, \\ \langle A\rangle_\rho &= \operatorname{Tr}(\rho A). \end{aligned}

The subscript may be omitted only when the state or ensemble remains unambiguous. A change from a ground-state expectation to a thermal or disorder-averaged expectation must be visible.

The principal equilibrium symbols are:

Symbol Meaning
β\beta inverse temperature 1/(kBT)1/(k_{\mathrm B}T)
ZZ canonical partition function
Ξ\Xi grand partition function
ρβ\rho_\beta canonical Gibbs state
ρβ,μ\rho_{\beta,\mu} grand-canonical Gibbs state
KK grand Hamiltonian H−μN^H-\mu\hat N when declared
X‾\overline{X} or [X]dis[X]_{\mathrm{dis}} disorder average, never a thermal average by default

For the canonical state, the trace and HH are restricted to the fixed-NN Hilbert space; the grand-canonical trace runs over Fock space. Their normalized states are

ρβ=e−βHZ,Z=Tr⁡e−βH,ρβ,μ=e−βKΞ,K=H−μN^.\begin{aligned} \rho_\beta &= \frac{e^{-\beta H}}{Z}, & Z &= \operatorname{Tr}e^{-\beta H}, \\ \rho_{\beta,\mu} &= \frac{e^{-\beta K}}{\Xi}, & K &= H-\mu\hat N. \end{aligned}

Here βH\beta H and βμN^\beta\mu\hat N are dimensionless. If KK is called a Hamiltonian, remember that physical real-time evolution is generated by HH, not automatically by KK. The Ensemble Formula Sheet collects the thermodynamic derivative identities and their assumptions.

Use distinct notation for nested averages. In a disordered thermal system, for example,

⟨A⟩J‾\overline{ \langle A\rangle_J }

means: compute the thermal or quantum expectation for one realization JJ, then average over realizations. Reversing those operations generally defines a different object.

Symbol Default role Required declaration
bi,bi†b_i,b_i^\dagger bosonic mode operators the mode or site indexed by ii
ci,ci†c_i,c_i^\dagger fermionic mode operators the mode, site, spin, and ordering convention
ai,ai†a_i,a_i^\dagger statistics-neutral placeholder the algebra must be stated first
nin_i mode or site occupation operator species sums and allowed eigenvalues
N^\hat N total number operator which species it counts
ψσ(r)\psi_\sigma(\mathbf r) continuum field operator statistics, normalization, and components
SiαS_i^\alpha spin operator spin representation and units
σiα\sigma_i^\alpha Pauli operator dimensionless; not the same as SiαS_i^\alpha
HH physical Hamiltonian degrees of freedom, parameters, and sector

Bosonic and fermionic mode algebras are, respectively,

[bi,bj†]=δij,[bi,bj]=0,{ci,cj†}=δij,{ci,cj}=0.\begin{aligned} [b_i,b_j^\dagger] &= \delta_{ij}, & [b_i,b_j] &= 0, \\ \{c_i,c_j^\dagger\} &= \delta_{ij}, & \{c_i,c_j\} &= 0. \end{aligned}

For either statistics,

ni=ai†ai,N^=∑ini,n_i = a_i^\dagger a_i, \qquad \hat N = \sum_i n_i,

but the occupation spectrum depends on the algebra. An occupation number is an eigenvalue of nin_i, not the probability that the mode exists.

Continuum fields obey a delta-normalized algebra. The nonvanishing equal-time bracket is

[ψσ(r),ψσ′†(r′)]∓=δσσ′δ(d)(r−r′),\big[ \psi_\sigma(\mathbf r), \psi_{\sigma'}^\dagger(\mathbf r') \big]_{\mp} = \delta_{\sigma\sigma'} \delta^{(d)}(\mathbf r-\mathbf r'),

where the upper commutator choice applies to bosons and the lower anticommutator choice to fermions. Because fields are operator-valued distributions, products at the same point may require a regulator or lattice definition.

For an interaction symmetric under exchanging the particles, let Vij;kl=⟨i,j∣V∣k,l⟩V_{ij;kl}=\langle i,j|V|k,l\rangle denote an unsymmetrized matrix element. Its number-conserving second-quantized form is

V^=12∑ijklVij;kl ai†aj†alak.\widehat V=\frac12\sum_{ijkl}V_{ij;kl}\,a_i^\dagger a_j^\dagger a_l a_k.

For fermions, the antisymmetrized element V‾ij;kl=Vij;kl−Vij;lk\overline V_{ij;kl}=V_{ij;kl}-V_{ij;lk} gives the same operator with a different prefactor:

V^=14∑ijklV‾ij;kl ci†cj†clck.\widehat V=\frac14\sum_{ijkl}\overline V_{ij;kl}\,c_i^\dagger c_j^\dagger c_l c_k.

Keep the annihilation order clckc_lc_k when comparing these formulas. The factor changes because the exchange contribution is already included in V‾\overline V; it is not an additional interaction. Two-Body Operators derives both conventions and checks their equivalence.

In this translation table S\mathbf S denotes angular momentum with units of ℏ\hbar. For spin 1/21/2,

Siα=ℏ2σiα,α∈{x,y,z}.S_i^\alpha = \frac{\hbar}{2} \sigma_i^\alpha, \qquad \alpha\in\{x,y,z\}.

Consequently,

Si⋅Sj=ℏ24σi⋅σj.\mathbf S_i\cdot\mathbf S_j = \frac{\hbar^2}{4} \boldsymbol\sigma_i\cdot\boldsymbol\sigma_j.

Many lattice pages instead use dimensionless spin s=S/ℏ=σ/2\mathbf s=\mathbf S/\hbar=\boldsymbol\sigma/2, sometimes labeling it S\mathbf S after explicitly declaring the convention. Their exchange coefficient then has energy units. Translate the operator and the coupling together. Do not replace SαS^\alpha by σα\sigma^\alpha while leaving all numerical coefficients unchanged.

Raising and lowering operators are

Si±=Six±iSiy.S_i^\pm = S_i^x \pm iS_i^y.

Some sources instead define σ±=(σx±iσy)/2\sigma^\pm=(\sigma^x\pm i\sigma^y)/2. The factor of 1/21/2 is part of the definition, not a cosmetic choice.

For NsN_s sites at positions rj\mathbf r_j, the default symmetric discrete transform is

ckσ=1Ns∑je−ik⋅rjcjσ,cjσ=1Ns∑keik⋅rjckσ.\begin{aligned} c_{\mathbf k\sigma} &= \frac{1}{\sqrt{N_s}} \sum_j e^{-i\mathbf k\cdot\mathbf r_j} c_{j\sigma}, \\ c_{j\sigma} &= \frac{1}{\sqrt{N_s}} \sum_{\mathbf k} e^{i\mathbf k\cdot\mathbf r_j} c_{\mathbf k\sigma}. \end{aligned}

This preserves the canonical mode algebra without an extra volume factor. The allowed k\mathbf k grid is fixed by the lattice vectors and boundary conditions.

For continuum fields in dd dimensions,

ψσ(r)=∫ddk(2π)d/2eik⋅rakσ,akσ=∫ddr(2π)d/2e−ik⋅rψσ(r).\begin{aligned} \psi_\sigma(\mathbf r) &= \int \frac{d^dk}{(2\pi)^{d/2}} e^{i\mathbf k\cdot\mathbf r} a_{\mathbf k\sigma}, \\ a_{\mathbf k\sigma} &= \int \frac{d^dr}{(2\pi)^{d/2}} e^{-i\mathbf k\cdot\mathbf r} \psi_\sigma(\mathbf r). \end{aligned}

Here k\mathbf k is wave number and

p=ℏk\mathbf p = \hbar\mathbf k

is physical momentum. A source using ddp/(2πℏ)dd^dp/(2\pi\hbar)^d has made a different but equivalent choice. Translate the integration measure, delta function, and operator normalization together.

For a periodic box, the continuum replacement is

1V∑k⟶∫ddk(2π)d.\frac{1}{V} \sum_{\mathbf k} \longrightarrow \int \frac{d^dk}{(2\pi)^d}.

The arrow describes a limit under stated regularity assumptions. It is not an exact identity for a finite box.

For real time, the default transform pair for an ordinary function is

A(ω)=∫−∞∞dt eiωtA(t),A(t)=∫−∞∞dω2πe−iωtA(ω).\begin{aligned} A(\omega) &= \int_{-\infty}^{\infty} dt\, e^{i\omega t} A(t), \\ A(t) &= \int_{-\infty}^{\infty} \frac{d\omega}{2\pi} e^{-i\omega t} A(\omega). \end{aligned}

The Heisenberg operator, independently of the Fourier convention, is

A(t)=eiHt/ℏAe−iHt/ℏ.A(t) = e^{iHt/\hbar} A e^{-iHt/\hbar}.

A source may reverse both exponential signs. Translate the transform pair before comparing pole locations or response conventions.

For grand-canonical fields use K=H−μN^K=H-\mu\hat N as the imaginary-time generator. The two common unit conventions are:

Convention Interval Evolved observable Matsubara quantity
time-valued τ\tau 0≤τ<βℏ0\le\tau<\beta\hbar eτK/ℏAe−τK/ℏe^{\tau K/\hbar}Ae^{-\tau K/\hbar} angular frequency in inverse time
inverse-energy τ\tau 0≤τ<β0\le\tau<\beta eτKAe−τKe^{\tau K}Ae^{-\tau K} energy-valued frequency, usually with ℏ=1\hbar=1

For time-valued τ\tau, the angular frequencies are

ωnB=2πnβℏ,ωnF=(2n+1)πβℏ.\begin{aligned} \omega_n^{\mathrm B} &= \frac{2\pi n}{\beta\hbar}, \\ \omega_n^{\mathrm F} &= \frac{(2n+1)\pi}{\beta\hbar}. \end{aligned}

The grid follows the correlator’s thermal boundary condition: an even density operator built from fermions has a bosonic grid. The usual odd-field antiperiodicity assumes the full grand-canonical trace. A finite fixed-NN projection cannot be cycled through a number-changing field as though it were the identity; use the Matsubara derivation for that distinction.

Correlation, Response, and Ordering Symbols

Section titled “Correlation, Response, and Ordering Symbols”
Symbol Usual role What still must be stated
CAB(t)C_{AB}(t) generic correlation ordering, state, and connectedness
CABcC_{AB}^{\mathrm c} connected correlation subtraction convention
GG Green function fields, sign, factor of ii or ℏ\hbar, and ordering
GR,GAG^{\mathrm R},G^{\mathrm A} retarded and advanced Green functions Fourier sign and bracket convention
G>,G<G^>,G^< greater and lesser Green functions operator order and statistics sign
GTG^{\mathsf T} or GTG^{\mathrm T} time-ordered Green function avoid confusing superscript with transpose
χABR\chi_{AB}^{\mathrm R} retarded response or susceptibility perturbation sign and normalization
S(q,ω)S(\mathbf q,\omega) dynamic structure factor Fourier and volume normalization
T\mathcal T real-time ordering equal-time prescription
Tτ\mathcal T_\tau imaginary-time ordering bosonic or fermionic exchange sign
θ(t)\theta(t) step function value at t=0t=0 if it matters

A generic unordered correlator and its connected part are

CAB(t)=⟨A(t)B(0)⟩,CABc(t)=CAB(t)−⟨A(t)⟩⟨B(0)⟩.\begin{aligned} C_{AB}(t) &= \langle A(t)B(0)\rangle, \\ C_{AB}^{\mathrm c}(t) &= C_{AB}(t) - \langle A(t)\rangle \langle B(0)\rangle. \end{aligned}

For a physical source H′(t)=−f(t)BH'(t)=-f(t)B, define δ⟨A(t)⟩=∫dt′ χABR(t−t′)f(t′)\delta\langle A(t)\rangle=\int dt'\,\chi^R_{AB}(t-t')f(t'). Then

χABR(t)=+iℏθ(t)⟨[A(t),B(0)]⟩.\chi_{AB}^{\mathrm R}(t) = +\frac{i}{\hbar} \theta(t) \langle[A(t),B(0)]\rangle.

For the source H′(t)=+f(t)BH'(t)=+f(t)B, the response kernel has the opposite sign. The commonly defined retarded commutator Green function also uses −i/ℏ-i/\hbar; do not identify it with the susceptibility above without the minus sign.

Symbol Quantity Standard relation or warning
UU or EE internal energy ⟨H⟩\langle H\rangle
SthS_{\mathrm{th}} thermodynamic entropy carries units of kBk_{\mathrm B}
SvNS_{\mathrm{vN}} von Neumann entropy dimensionless with natural logarithm
SAS_A subsystem entropy partition and logarithm base must be stated
FF Helmholtz free energy natural variables T,V,NT,V,N
Ω\Omega grand potential natural variables T,V,μT,V,\mu
μ\mu chemical potential energy per particle added at fixed entropy and volume
PP pressure do not confuse with parity or a projector
CVC_V heat capacity specify fixed variables and whether total or specific
κT\kappa_T isothermal compressibility normalization varies with density convention

For an equilibrium Gibbs state with dimensionless von Neumann entropy,

Sth=kBSvN,S_{\mathrm{th}} = k_{\mathrm B} S_{\mathrm{vN}},

but thermodynamic entropy and entanglement entropy answer different physical questions. A lowercase density such as f=F/Vf=F/V or a per-site quantity such as F/NsF/N_s should be introduced explicitly; lowercase is not an automatic “per particle” instruction.

Partial derivatives must display their held-fixed variables when more than one thermodynamic interpretation is possible. For example,

P=−(∂F∂V)T,N.P = -\left( \frac{\partial F}{\partial V} \right)_{T,N}.
Notation Meaning
f∼gf\sim g asymptotic equivalence: f/g→1f/g\to1 in the stated limit
f∝gf\propto g equality up to an unspecified multiplicative constant
f≃gf\simeq g approximate equality in a declared regime
f=O(g)f=O(g) asymptotic upper-order statement
f=o(g)f=o(g) f/g→0f/g\to0
x≪yx\ll y a controlled or physically stated scale separation
x→x0x\to x_0 a limit, not an ordinary assignment

The thermodynamic limit for a continuum fluid is

N,V→∞,NV=nfixed,N,V\to\infty, \qquad \frac{N}{V}=n \quad\text{fixed},

while a lattice limit takes Ns→∞N_s\to\infty with filling, shape, and coupling scaling specified.

Orders of limits may be physical data. When the indicated limits exist, they need not agree:

lim⁡t→∞lim⁡Ns→∞CNs(t)≠lim⁡Ns→∞lim⁡t→∞CNs(t).\lim_{t\to\infty} \lim_{N_s\to\infty} C_{N_s}(t) \neq \lim_{N_s\to\infty} \lim_{t\to\infty} C_{N_s}(t).

The first may describe relaxation after a continuum spectrum emerges. A finite isolated system often has no pointwise long-time limit at all because of recurrences; a time average is a different, explicitly defined operation.

Abbreviation Meaning Typical consequence
OBC open boundary conditions edges and standing-wave modes
PBC periodic boundary conditions discrete momenta; translation symmetry if the Hamiltonian also preserves it
APBC antiperiodic boundary conditions shifted momentum grid
TBC twisted boundary conditions flux or stiffness probe through a phase θ\theta

For a one-dimensional lattice,

cj+Ns=cj(PBC),cj+Ns=eiθcj(twist).\begin{aligned} c_{j+N_s} &= c_j &&\text{(PBC)}, \\ c_{j+N_s} &= e^{i\theta}c_j &&\text{(twist)}. \end{aligned}

Boundary conditions affect the allowed momentum grid, symmetry sectors, finite-size degeneracies, and sometimes fermion-parity bookkeeping. They are not a numerical afterthought.

Orientation and derivation pages keep ℏ\hbar and kBk_{\mathrm B} explicit unless suppressing them materially clarifies an advanced calculation. The declarations

ℏ=1,kB=1,a=1\hbar=1, \qquad k_{\mathrm B}=1, \qquad a=1

are three independent choices.

  • ℏ=1\hbar=1 identifies energy with angular frequency and momentum with wave number.
  • kB=1k_{\mathrm B}=1 gives temperature energy units.
  • a=1a=1 measures lengths in lattice spacings and wave numbers in inverse lattice spacings.

To restore constants, first use dimensions and then verify the generating equation. Typical replacements include

e−iHt⟶e−iHt/ℏ,e−βH⟶e−H/(kBT),k⟶pℏ.\begin{aligned} e^{-iHt} &\longrightarrow e^{-iHt/\hbar}, \\ e^{-\beta H} &\longrightarrow e^{-H/(k_{\mathrm B}T)}, \\ \mathbf k &\longrightarrow \frac{\mathbf p}{\hbar}. \end{aligned}

Dimensional analysis alone may not recover every Fourier normalization or coupling convention. Check the canonical commutator, anticommutator, or partition-function exponent after translating.

Symbol Frequent meanings Preferred repair on one page
NN particles, sites, flavors, large-NN rank use NsN_s, NfN_f, or a descriptive subscript
LL length, site count, Liouvillian use NsN_s and L\mathcal L for the latter two
SS entropy, spin, action, structure factor use SthS_{\mathrm{th}}, S\mathbf S, S\mathcal S, and S(q)S(\mathbf q)
Ω\Omega grand potential, volume, angular frequency use VV for volume and ω\omega for frequency
Δ\Delta gap, order parameter, detuning, finite difference add Δgap\Delta_{\mathrm{gap}}, Δsc\Delta_{\mathrm{sc}}, or prose
Γ\Gamma rate, linewidth, hybridization, vertex attach arguments or a descriptive subscript
GG Green function, Gibbs free energy, conductance use GRG^{\mathrm R}, GGibbsG_{\mathrm{Gibbs}}, or context-specific notation
χ\chi susceptibility, field, spinor expose arguments and indices
TT temperature, ordering, transpose use T\mathcal T and T\mathsf T for the latter two
PP pressure, parity, projector, probability use Π\Pi for a projector or a descriptive subscript
σ\sigma spin index, Pauli matrix, conductivity distinguish index position, σ\boldsymbol\sigma, and σ(ω)\sigma(\omega)
JJ exchange, hopping, current, disorder realization use tt for hopping and label currents explicitly

Overloading across separate pages is manageable. Overloading inside one derivation is a source of false identities. The sitewide Notation Collisions page gives a broader repair guide.

Consider the finite-lattice density structure factor

S(q,ω)=12πNs∫−∞∞dt eiωt×∑jℓe−iq⋅(rj−rℓ)×⟨δnj(t)δnℓ(0)⟩,δnj=nj−⟨nj⟩.\begin{aligned} S(\mathbf q,\omega) &= \frac{1}{2\pi N_s} \int_{-\infty}^{\infty} dt\, e^{i\omega t} \times \sum_{j\ell} e^{-i\mathbf q\cdot(\mathbf r_j-\mathbf r_\ell)} \times \langle \delta n_j(t) \delta n_\ell(0) \rangle, \\ \delta n_j &= n_j-\langle n_j\rangle. \end{aligned}

The formula is interpretable because its convention data are visible:

  1. jj and ℓ\ell are site indices, while NsN_s is the site count.
  2. q\mathbf q is a reciprocal-space wave vector fixed by the boundary conditions.
  3. The 1/Ns1/N_s normalization is intensive when the connected spatial correlation is summable; critical correlations can still produce size dependence.
  4. The 1/(2π)1/(2\pi) factor belongs to the chosen forward time transform.
  5. The correlator is unordered and built from connected density fluctuations.
  6. The expectation brackets still require a declared state or ensemble.
  7. njn_j may include one species or a species sum; the model must say which.

Another source may omit 1/(2π)1/(2\pi), normalize by particle number NN, or use e−iωte^{-i\omega t}. None of those choices is automatically wrong. A comparison must translate all three choices before applying a sum rule or comparing spectral weights.

A paper writes “take N→∞N\to\infty at half filling” for a spin-1/21/2 fermion lattice with one orbital per site. Rewrite the statement so that particle number, site count, and filling cannot be confused. State what half filling means in this model.

Solution

Write the lattice thermodynamic limit as

Ns→∞,ν=NNs=1fixed.N_s\to\infty, \qquad \nu = \frac{N}{N_s} = 1 \quad\text{fixed}.

There are two spin orbitals per site, so the maximum filling is ν=2\nu=2. Half filling therefore means one fermion per site on average, N=NsN=N_s, not N=Ns/2N=N_s/2.

Translate

H=JS∑⟨ij⟩Si⋅SjH = J_S \sum_{\langle ij\rangle} \mathbf S_i\cdot\mathbf S_j

for spin 1/21/2 into Pauli-operator notation. Give the relation between the coefficient JσJ_\sigma multiplying σi⋅σj\boldsymbol\sigma_i\cdot\boldsymbol\sigma_j and JSJ_S.

Solution

Using Si=(ℏ/2)σi\mathbf S_i=(\hbar/2)\boldsymbol\sigma_i,

H=JSℏ24∑⟨ij⟩σi⋅σj.H = \frac{J_S\hbar^2}{4} \sum_{\langle ij\rangle} \boldsymbol\sigma_i\cdot\boldsymbol\sigma_j.

Therefore

Jσ=ℏ24JS.J_\sigma = \frac{\hbar^2}{4} J_S.

If a source defines dimensionless spin operators s=σ/2\mathbf s=\boldsymbol\sigma/2, then its coefficient convention differs again. The operator definition and coupling must be translated as one unit.

An advanced calculation sets ℏ=kB=1\hbar=k_{\mathrm B}=1 and writes

ρ=e−(H−μN^)/TΞ,A(t)=eiHtAe−iHt.\begin{aligned} \rho &= \frac{e^{-(H-\mu\hat N)/T}}{\Xi}, \\ A(t) &= e^{iHt}Ae^{-iHt}. \end{aligned}

Restore ℏ\hbar and kBk_{\mathrm B}.

Solution

The thermal exponent must be dimensionless, so

ρ=exp⁡ ⁣[−(H−μN^)/(kBT)]Ξ.\rho = \frac{ \exp\!\left[-(H-\mu\hat N)/(k_{\mathrm B}T)\right] }{\Xi}.

Real-time evolution requires an action divided by ℏ\hbar:

A(t)=eiHt/ℏAe−iHt/ℏ.A(t) = e^{iHt/\hbar} A e^{-iHt/\hbar}.

No factor of ℏ\hbar belongs in the equilibrium Gibbs exponent because kBTk_{\mathrm B}T already has energy units.

  • A. Altland and B. Simons, Condensed Matter Field Theory, 2nd ed., Cambridge University Press (2010) — continuum, lattice, and field-theory translations.
  • P. Coleman, Introduction to Many-Body Physics, Cambridge University Press (2015) — lattice models, spin notation, and many-body scales.
  • A. L. Fetter and J. D. Walecka, Quantum Theory of Many-Particle Systems, Dover (2003) — operator, Green-function, and many-particle notation.
  • G. D. Mahan, Many-Particle Physics, 3rd ed., Springer (2000) — real- and imaginary-time Green functions and response conventions.
  • J. W. Negele and H. Orland, Quantum Many-Particle Systems, Westview Press (1998) — fields, thermal traces, and imaginary-time methods.
  • R. K. Pathria and P. D. Beale, Statistical Mechanics, 3rd ed., Elsevier (2011) — ensemble and thermodynamic notation.