Time-Independent Hamiltonians
A Hamiltonian is time independent when it has no explicit dependence on the time parameter. In that case the time-evolution operator is the ordinary exponential
This is the simplest and most important exact solution of closed-system quantum dynamics.
Time-independent unitary evolution
Section titled “Time-independent unitary evolution”The formula applies when the same self-adjoint Hamiltonian , with a fixed domain, generates evolution throughout the interval from to . It does not require to be diagonal in the basis being used, but it does require not to change with time.
For unbounded Hamiltonians, the exponential is defined through spectral theory. In finite dimensions, it is the usual matrix exponential.
Spectral Decomposition
Section titled “Spectral Decomposition”If has a discrete spectral decomposition
then
For nondegenerate eigenstates, , so
This makes energy-basis evolution especially transparent: each energy component acquires a phase. Stationary states and phases explains why a superposition of different energies can still have time-dependent probabilities.
Degeneracy
Section titled “Degeneracy”If an energy level is degenerate, every state inside that eigenspace gets the same phase under alone. Under alone the ray of every vector in that eigenspace is fixed. A basis change does not create dynamics. An added perturbation can split or mix the subspace, and a measurement can change the state through a separate state-update operation.
Continuous Spectra
Section titled “Continuous Spectra”For continuous spectra, sums are replaced by spectral integrals. The free particle is the standard example: momentum components evolve by phases determined by .
The formal lesson is unchanged. Diagonalize the Hamiltonian, attach phases to spectral components, then transform back if needed.
Finite-Dimensional Matrix Exponentials
Section titled “Finite-Dimensional Matrix Exponentials”In a finite-dimensional basis, is a Hermitian matrix. If it is diagonalized as
then
This is often the stable way to compute exact finite-dimensional time evolution.
Examples
Section titled “Examples”For a diagonal two-level Hamiltonian
the evolution is
For the harmonic oscillator,
number states evolve as
Common Mistakes
Section titled “Common Mistakes”- Substituting an instantaneous into this formula. Even if all commute, the exponent uses , not generally .
- Thinking a time-independent Hamiltonian means all observables are time independent.
- Forgetting relative phases between different energy eigenstates.
- Treating degeneracy as if it automatically fixes a preferred basis inside the degenerate subspace.
- Ignoring domain issues for unbounded Hamiltonians in rigorous arguments.
References
Section titled “References”- M. Reed and B. Simon, Methods of Modern Mathematical Physics I: Functional Analysis, revised and enlarged ed., Academic Press, 1980.
- J. J. Sakurai and J. Napolitano, Modern Quantum Mechanics, 3rd ed., Cambridge University Press, 2020.
- R. Shankar, Principles of Quantum Mechanics, 2nd ed., Springer, 1994.
Exercises
Section titled “Exercises”- Suppose . Show that satisfies the operator Schrödinger equation.
Solution
Differentiate the spectral expression:
Since , the right-hand side is .