Heisenberg Equations of Motion
The Heisenberg equation of motion gives the time derivative of an operator in the Heisenberg picture:
It is the operator analogue of Hamiltonian time evolution. The dynamics-side discussion of commutators as generators is Commutator Dynamics.
The Core expectation-value consequence, including the conservation-law test, is Conservation Laws. For a practical symmetry-oriented checklist, see Constants of Motion.
Differentiating the Heisenberg operator
Section titled “Differentiating the Heisenberg operator”Assume a differentiable unitary propagator. For unbounded operators, use states in an invariant domain on which the products and derivatives below exist. Write . For an operator with no explicit time dependence,
Using
and its adjoint, differentiation gives
If has explicit time dependence, the extra term must be included.
Free Particle
Section titled “Free Particle”For
the canonical commutator gives
Thus
Particle in a Potential
Section titled “Particle in a Potential”For
one obtains
These are operator equations on the appropriate domain. Their expectation values give Ehrenfest theorem, where cannot generally be replaced by .
Harmonic Oscillator
Section titled “Harmonic Oscillator”For
the ladder operator obeys
so
Spin in a Magnetic Field
Section titled “Spin in a Magnetic Field”With the magnetic-moment convention ,
The sign of the gyromagnetic ratio sets the sense of precession. For , and .
The spin-specific derivation is Larmor Precession.
Common Mistakes
Section titled “Common Mistakes”- Forgetting the explicit time-derivative term.
- Reversing the commutator sign.
- Treating operator equations as ordinary commuting equations.
- Assuming Heisenberg equations automatically solve the whole classical-limit problem.
- Dropping domain and boundary-condition issues for unbounded operators.
References
Section titled “References”- D. J. Griffiths and D. F. Schroeter, Introduction to Quantum Mechanics, 3rd ed., Cambridge University Press, 2018.
- J. J. Sakurai and J. Napolitano, Modern Quantum Mechanics, 3rd ed., Cambridge University Press, 2020.
- R. Shankar, Principles of Quantum Mechanics, 2nd ed., Springer, 1994.
Exercises
Section titled “Exercises”- Use to derive for the free particle.
Solution
For ,
Using gives